$\require{mediawiki-texvc}$
  • 검색어에 아래의 연산자를 사용하시면 더 정확한 검색결과를 얻을 수 있습니다.
  • 검색연산자
검색연산자 기능 검색시 예
() 우선순위가 가장 높은 연산자 예1) (나노 (기계 | machine))
공백 두 개의 검색어(식)을 모두 포함하고 있는 문서 검색 예1) (나노 기계)
예2) 나노 장영실
| 두 개의 검색어(식) 중 하나 이상 포함하고 있는 문서 검색 예1) (줄기세포 | 면역)
예2) 줄기세포 | 장영실
! NOT 이후에 있는 검색어가 포함된 문서는 제외 예1) (황금 !백금)
예2) !image
* 검색어의 *란에 0개 이상의 임의의 문자가 포함된 문서 검색 예) semi*
"" 따옴표 내의 구문과 완전히 일치하는 문서만 검색 예) "Transform and Quantization"
쳇봇 이모티콘
안녕하세요!
ScienceON 챗봇입니다.
궁금한 것은 저에게 물어봐주세요.

논문 상세정보

Sol-Gel법을 이용한 (0.8PPV+0.2DMPPV)/Silica Glass, Borosilicate Glass 복합체의 합성과 그 특성

Synthesis and Their Properties of (0.8PPV+0.2DMPPV)/Silica Glass, Borosilicate Glass Composites by Sol-Gel Process

Abstract

The (0.8PPV+0.2DMPPV) copolymer and silica/borosilicate composites were synthesized by sol-gel process. The organic-inorganic hybrid solution was prepared by using of (0.8PPV+0.2DMPPV) copolymer precursor solution as a raw material for organic components and TEOS and TMB for glass components. Then by drying the solution in vacuum at 5$0^{\circ}C$ for 7days and subsequent heat treatment in vacuum at 15$0^{\circ}C$~30$0^{\circ}C$ for 2h~72h with heating rate of 0.2$^{\circ}C$/min and 1.8$^{\circ}C$/min, the organic-inorganic composites were synthesized. Microstructural evolution of the composites was characterized by DSC, IR spectrocopy, UV/VIS spectroscopy, and TEM. Elimination of the polymer precursor and degradation of the polymer were observed by DSC and Si-O and trans C=C absorption peaks were identified by IR spectra. The polymer was found to be successfully incorporated into the glass matrix and it was confirmed by the absorption peaks from the polymer in the UV/VIS spectra and the TEM results. The absorption peak of the composites was found to shift toward short wavelength side compared to that of the pure polymer and the amount of the blue shift increased with increasing the heat treatment temperature and heat treatment time and with decreasing the heating rate.

저자의 다른 논문

참고문헌 (22)

  1. H Schmidt;M. Popall , SPIE; Sol-Gel Optics / v.1328,pp.249, 1990
  2. Sol-Gel Processing of SiO₂-B₂O₃Glasses , B. Kumar , Mat. Res. Bull. / v.19,pp.331, 1984
  3. Coating Film of SiO₂-B₂O₃by the Sol-Gel Method , N. Tohge;A. Matsuda;T. Minami , J. Am. Ceram. Soc. / v.70,pp.C.13-C.15, 1987
  4. Synthesis, Doping and Electrical Conductivity of High Molecular Weight Poly(P-Phenylene Vinylene) , D.R. Gagnon;J.D. Capistran;F.E. Karasz;R.w Lenz;S. Antoun , Polymer / v.28,pp.567, 1987
  5. Structure and Morphology of Sol-Gel Prepared Polymer-Ceramic Composite Thin Films , F.W. Embs;E.L. Thomas , Polymer / v.34,pp.4608, 1993
  6. Structure Property Behavior of Hybrid Materials Incorporating Tetrathoxysilane with Multifunctional Poly(Tetra-methyleneoxide) , H. Huang;G. L. Wilkes;J. G. Carlson , Polymer / v.30,pp.2001, 1989
  7. Effect of Phase Separation on Precipitation Characteristics of CuCl Quantum Dots in the Borosilicate Glass System , Y. K. Yoon;W. -T. Han;S. J. Chung , J. Non-Cryst. Solids / v.203,pp.195-201, 1996
  8. J.L. Bredas;R. Silbey(eds) , Conjugated Polymers / v.,pp., 1991
  9. 이광섭 , Private Communication / v.,pp., 0000
  10. Applications of Nonlinear Optical Materials to Optical Communication Devices , S. Sudo , Nonlinear Optics / v.1,pp.213, 1990
  11. Materials for All-Optical Devices , P. W. E. Smith;S. D. Benjamin , Opt. Eng. / v.34,pp.189, 1995
  12. Poly(p-Phenylene Vinylene)-Silica Composite:A Novel Sol-Gel Processed Non-linear Optical Material for Optical Waveguides , C. J. Wung;Y. Pang;P. N. Prasad , Polymer / v.32,pp.605, 1991
  13. Observation of two Z₃excition resonances in CuCl-doped non-linear optical glass , W. T. Han;Y. K. Yoon , J. Non-Cryst Solids / v.196,pp.84-89, 1996
  14. Temperature Dependent Optical Resonances of Quantum Confined CuCl Nano-crystals in Borosilicate Glasses , Y. K Yoon;W.-T. Han , J. Appl. Phys. / v.82,pp.2584, 1997
  15. Homogeneity of Gels and Gel-Derived Glasses , S. P. Mukherjee , J. Non-Cryst. Solids / v.63,pp.35-43, 1984
  16. Synthesis and Electrical Conductivity of Poly(1,4-Phenylenevinylene-co-2-nn-Butoxy-5-Methoxy-1,4-Phenylenevinylene)s and Poly(1,4-Phenylenevinylene-co-2-n-Dodecyloxy-5-Methoxy-1,4-Phenylenevinylene)s , Jung-Il Jin;Chi-Kyun Park , Polymer / v.35,pp.480, 1994
  17. Nonlinear Optics, Principles, Materials, Phenomena, and Devices , T. Kobayashi , Nonlinear Optics / v.1,pp.91, 1991
  18. Nonlinear Optical Properties of Lead-Tin Fluorophosphate Glass Containing Acridine Dyes , W. R. Tompkin;R. W. Boyd;D. W. Hall;P. A. Tick , J. Opt. Soc. Am. / v.B4,pp.1030, 1987
  19. F. W. Embs;E.L.Thomas;C.J. Wung;P.N. Prasad , Polymer / v.34,pp.4607, 1993
  20. C. Li;J. Y. Tseng;K. Morita;C. Lechner;Y. Hu;J. D. Mackenzie , Proceedings SPIE-The International Society for Optical Engineering;Sol-Gel Optical Ⅱ / v.1758,pp.410, 1992
  21. New Type Non-Crystalline Solids between Inorganic and Organic Materials , H. Schmidt , J. Non-Cryst Solids / v.73,pp.681, 1985
  22. Research on Nonlinear Optical Materialsian assessment , D. H. Auston(et al) , Appl Optics / v.26,pp.221, 1987

이 논문을 인용한 문헌 (0)

  1. 이 논문을 인용한 문헌 없음

원문보기

원문 PDF 다운로드

  • ScienceON :

원문 URL 링크

원문 PDF 파일 및 링크정보가 존재하지 않을 경우 KISTI DDS 시스템에서 제공하는 원문복사서비스를 사용할 수 있습니다. (원문복사서비스 안내 바로 가기)

상세조회 0건 원문조회 0건

DOI 인용 스타일