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Effects of Electric Current and Potential on the Electrokinetic Removal of Heavy Metals from an Abandoned Mine Tailings 원문보기

한국환경과학회지 = Journal of the environmental sciences, v.13 no.2, 2004년, pp.149 - 159  

Shin, Hyun-Moo (Department of Civil and Environmental Engineering, Kyungsung University) ,  Lee, Chang-Eun (Department of Civil and Environmental Engineering)

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In the removal of heavy metals from the mine deposit using electrokinetic processes, the effects of operation under both constant current and constant potential conditions were estimated. The results of soil pH distributions for DDW-20 V and DDW-100 mA cases after the electrokinetic remediation test...

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제안 방법

  • At the end of each test, metal concentrations in anolyte, cath이yte, outflow, and filter paper were also analyzed. Soil pHs were recorded for each section before drying them in an oven fbr chemical analysis and water content evaluation.
  • At the constant current mode, the output current was regulated to the selected value, while output voltage was varied with the load requirements. Constant current mode was selected in this experiments to sustain a constant rate of production of electrolysis products at the electrodes and simplify analysis of the chemistry at the boundaries.'이 Copper wires were used as voltage probes to measure the electric potential distribution of the soil specimen in a horizontal direction.
  • In order to estimate the effects of operation conditions of electrokinetic processes in the removal of heavy metals from the mine tailings, electrokinetic reactors just saturated with water in which any other electrolyte was not contained, were run under constant current and constant potential conditions. In the operation of the process, changes in pH, electric current, electric potential, osmotic flow, and contaminant distribution were investigated.
  • According to the these differences, chaises of procedure conditions were expected in electrokinetic remediation at the real site. Therefore, the studies were carried out to estimate the applicability of electrokinetic technique in the metal mining deposit, same real contaminated soils which have been aged for longer periods of time. For those experiments, a mine deposit soil containing high concentration of heavy metals especially, Cu, Cd, Pb, and Zn were selected.

대상 데이터

  • The soil specimen fbr the electrokinetic experiments were prepared with metal mine tailings, which were collected from the "I" mine located at the North Eastern suburban area in Busan Metropolitan City. The main mining metals were gold, silver, copper, and tungsten.
  • Therefore, the studies were carried out to estimate the applicability of electrokinetic technique in the metal mining deposit, same real contaminated soils which have been aged for longer periods of time. For those experiments, a mine deposit soil containing high concentration of heavy metals especially, Cu, Cd, Pb, and Zn were selected.
  • The reactor was made of acrylic material with 5 mm thickness for electrical insulation and also to resist the lateral compaction pressure. The dimension of the reactor was 10 cm in width, 15 cm in hight, and 29 cm in length. The selected electrode spacing was about 16 cm.
  • The equipment fbr this study was composed of a electrokinetic remediation set, graduated cylinders, electric circuit, power supply, pH meter, and multitester. Fig.
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참고문헌 (19)

  1. Zelina, J. P and J. F. Rusling, 1998, Electrochemical remediation of soils. in Environmental Analysis and Remediation, John Wiley & Sons, New York, NY, 1567-1583pp. 

  2. Jeong, H. I., 1996, Removal of heavy metals from contaminated ground by electrokinetic remediation, Ph. D. Dissertation of the In-Ha University, 3-4pp. 

  3. Jeong, B. M., 1999, Electrokinetic technique application to kaolinite contaminated by heavy metal, Master Thesis of the Chung-ang University, 39-114pp. 

  4. Han, S. J., 2000, Characteristics of electro-osmosis and heavy metal migration in contminated soil by electrokinetic technique, Ph. D. Dissertation of the Chung-ang University, 75pp. 

  5. Rodsand, T. and Y. B. Acar, 1995, Electrokinetic extraction of lead from spiked Norwegian marine clay, 2000 Environment and Geotechnical special Publication, 2-2(46), 1518-1534. 

  6. Pamukcu, S. and J. K. Wittle, 1992, Electrokinetic removal of selected heavy metals from soil., Environmental Progress, 11(3), 241-250. 

  7. Shapiro, A. P. and R. F. Probstein, 1993, Removal of contaminants from saturated clay by electro-osmosis, Environ. Sci. Technol., 27(2), 283-291. 

  8. Delfino, J. J. and R. E. Enderson, 1978, Comparative study outlines methods of analysis of total metal in sludge, Water & Sewage works, 125(RN), R32-R48. 

  9. Acar, Y. B., A. N. Alshawabkeh and R. A. Parker, 1997, Theoretical and experimental modeling of multi-species transport in soils under electric fields, EPA/600/R-97/054. 

  10. Acar, Y. B., R. J. Gale, G. Putnam and J. Hamed, 1989, Electrochemical processing of soils: Its potential use in environmental geotechnology and significance of pH gradients, 2nd International symposium on environmental geotechnology; Shanghai, China, Envo Publishing, Bethlehem, PA, 1, 25-38. 

  11. Acar, Y. B., R. J. Gale, J. Hamed and G. Putnam, 1990, Electrochemical processing of soils: Theory of pH gradient development by diffusion and linear convection, J. of environmental science and health, part(a), Environ. Sci. and Eng., 25(6), 687-714. 

  12. Hamed, J., Y. B. Acar and R. J. Gale, 1991, Pb(II) removal from kaolinite by electrokinetics, J. of Geotech. Eng., ASCE, 117(2), 240-271. 

  13. Alshawabkeh, A. N. and Y. B. Acar, 1996, Electrokinetic remediation. II: Theoretical model, J. of Geotech. Eng., 122(3), 286-196. 

  14. Acar, Y. B. and A. N. A. Ishawabkeh, 1993, Principles of electrokinetic remediation, J. of Environ. Sci. Technol., 27(13), 2638-2647. 

  15. Acar, Y. B. and A. N. Alshawabkeh, 1996, Electrokinetic remediation. I: Pilot-Scale tests with lead-spiked kaolinite, J. of Geotech. Eng., 122(3), 173-185. 

  16. Acar, Y. B., R. J. Gale, A. N. Alshawabkeh, R. E. Marks, S. Puppala, M. Bricka and R. Parker, 1995, Electrokinetic remediation; Basics and technology status, J. of Hazardous Material, 40, 117-137. 

  17. Acar, Y. B. and A. N. Alshawabkeh, 1993, Principles of electrokinetic remediation., J. of Environ. Sci. Technol., 27(13), 2638-2647. 

  18. Sparks, D. L., 1989, Kinetics of soil chemical processes, Academic press, Inc., New York, NY, 119-122pp. 

  19. Sparks, D. L., 1995 Environmental soil chemistry, Academic Press, New York, NY, 130-131pp. 

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