$\require{mediawiki-texvc}$
  • 검색어에 아래의 연산자를 사용하시면 더 정확한 검색결과를 얻을 수 있습니다.
  • 검색연산자
검색연산자 기능 검색시 예
() 우선순위가 가장 높은 연산자 예1) (나노 (기계 | machine))
공백 두 개의 검색어(식)을 모두 포함하고 있는 문서 검색 예1) (나노 기계)
예2) 나노 장영실
| 두 개의 검색어(식) 중 하나 이상 포함하고 있는 문서 검색 예1) (줄기세포 | 면역)
예2) 줄기세포 | 장영실
! NOT 이후에 있는 검색어가 포함된 문서는 제외 예1) (황금 !백금)
예2) !image
* 검색어의 *란에 0개 이상의 임의의 문자가 포함된 문서 검색 예) semi*
"" 따옴표 내의 구문과 완전히 일치하는 문서만 검색 예) "Transform and Quantization"
쳇봇 이모티콘
안녕하세요!
ScienceON 챗봇입니다.
궁금한 것은 저에게 물어봐주세요.

논문 상세정보

치환기를 가진 다섯 자리 질소-산소 (N2O3)계 리간드의 합성 및 전이금속(II) 이온과의 착물 안정도상수 결정

Synthesis of Pentadentate Nitrogen-Oxygen(N2O3) Ligands with Substituting Groups and Determination of Stability Constants of Their Transition Metal(II) Complexes

Abstract

Hydrochloric acid salt of a new $N_2O_3$ pentadentate ligand, N,N'-Bis(2-Hydroxybenzyl)-1,3-diamino-2-propanol(H-BHDP 2HCl) was synthesized. Br-BHDP 2HCl, CI-BHDP 2HCl, $CH_3-BHDP$ 2HCl and $CH_3O$-BHDP 2HCl having Br, Cl, $CH_3$ and $CH_3O$ substituents at 5-position of the phenol group of H-BHDP 2HCl were also synthesized. The potentiometry study in aqueous solution revealed that the proton dissociations of the synthesized ligands occurred in four steps and their order of the calculated overall proton dissociation constants($log{\beta}_p$) was Br-BHDP < Cl-BHDP < H-BHDP < $CH_3O-BHDP$ < $CH_3-BHDP$. The order showed a similar trend to that of Hammett substituent constants(${\delta}_p$). The order of the stability constants($logK_{ML}$) was Co(II) < Ni(II) < Cu(II) < Zn(II) < Cd(II) < Pb(II). The order in their stability constants ($logK_{ML}$) of each transition metal complex agreed with that of the overall proton dissociation constants ($log{\beta}_p$).

참고문헌 (34)

  1. Kim E. J., Kim Y. S., Choi J. M., 2008, Studies on Solvent Extraction Using Salphen for Separative Determination of Trace Fe(II) and Fe(III) in Water Sample, Bull. Korean Chern. Soc., 29(1), 99-103 
  2. Agett J., Khoo A. W., 1981, Richardson R. A., Solvent Extraction of Cu(II) by Schiff Base-Il , J. Inorg. Chem., 43, 1867-1882 
  3. Agett J., Richardson R. A., 1970, Solvent Extraction of Cu(II) by Schiff Bases, Analytical Chimica Acta, 50, 269-273 
  4. 이대운, 이항, 유의경, 1979, 킬레이트 시약으로 처리한 음이온 교환수지에 의한 금속이온의 선택적 흡착에 관한 연구, 대한화학회지, 23(3), 141-151 
  5. 지상현, 고석오, 2008, 킬레이트제를 이용한 토양에서의 중금속 용출제거 평가, 한국폐기물학회지, 25(4), 287-294 
  6. 김영근, 김정래, 이우근, 2006, 산화-용매추출을 이용한 소각비산재로부터 Cu와 Zn의 회수, 23(7), 623-628 
  7. Kim Y. S., In G., Kim M. H., Choi J. M., 2006, Fundamental Study on Solvent Sublation Using Salphen and Its Application for Separative Detemination of Trace Ni(II), Co(II) and Cu(II) in Water Samples, Bull. Korean Chem. Soc., 27(11), 1757-1762 
  8. Joshaghani M., Gholivand M. B., Ahmadi F., 2008, Spectrophotometric and conductometric study of complexation of salophen and some transition metal ions in nonaqueous polar solvents, Spec. Acta. Part A., 70, 1073-1078 
  9. Rabie U. M., Assran A. S. A., Abou-El-Wafa M. H. M., 2008, Unsymmetrical Schiff base functionalize as bibasic tetradentate(ONNO) and monobasic tridentate(NNO) ligands complexation with some transition metal ions, J. Mole. stru., 872, 113-122 
  10. Tao R. J., Li F. A., Cheng Y. X., Zang S. Q., Wang Q. L., Niu J. Y., Liao D. Z., 2006, Synthesis, crystal structure and magnetic properties of a chain coordination polymer [[Cu_4L_2(H_2O)]{\cdot}H_2O]_n , Inorg. Chim. Acta., 359, 2053-2058 
  11. Pradeep C. P., Zacharias P. S., Das S. K., 2006, Synthesis and structural characterization of a carboxylate bridged tetranuclear copper complex derived from reduced Sciff base asymmetric compartmental ligand containing an amino acid side arm, Inorg. Chem. Com., 9, 1071-1074 
  12. Jancso A., Paksi Z., Mikkola S. A., Rockenbauer A., Gajda T., 2005, Iron(III) and copper(II) complexes of an asymmetric, pentadentate salen-like ligand bearing a pendant carboxylate group, J. lnorg. Biochem., 99, 1480-1489 
  13. Biava H., Palopoli C, Shova S., Gaudio M. D., Daier V. M., Gonazlez-Sierra M., Tuchagues J. P., Signorella S., 2006, New dimanganese(III) complexes of pentadentate ($N_2O_3$) Schiff base ligands with the $[Mn_2(\mu-OAc)(\mu-OR)_2]^{3+}$ core: Synthesis, characterization and mechanistic studies of $H_2O_2$ disproportionation, J. Inorg. Biochem., 100, 1660-1671 
  14. Plass W., 1996, Synthesis and characterization of a $VO^{3+}$ complex of a pentadentate amine alcohol ligand: towards hydrolytically stable ligands forming medel complexes for vanadium-dependent haloperoxidases, Inorg. Chim. Acta., 244, 221-229 
  15. Gupta K. C., Sutar A. K., 2008, Catalytic activity of polymer anchored N,$N^{\prime}$-bis(o-hydroxyacetophenone) ethylene diamine Schiff base complexes of Fe(III), Cu(III) and Zn(III) ions in oxidation of phenol, Rea & Fun. Poly., 68, 12-26 
  16. Gupta K. C., Sutar A. K., 2008, Catalytic activities of Schiff base transition metal complexes, Coor. Chem. Rev., 252, 1420-1450 
  17. Kureshy R. I., Khan N. H., Abdi S. H. R., Iyer P., 1997, Synthesis of catalytically active polymer-bound Mn(III) salen complexes for enantioseiective epoxidation of styrene derivatives, Rea. & Fun. Poly., 34, 153-160 
  18. Naeimi H., Salimi F. K., Rabiei K., 2006, Mild and convenient one pot synthesis of Schiff bases in the presence of $P_2O_5/AlO_3$ as new catalyst under solvent- free conditions, J. Mole. Cata. A: Chem., 260, 100-104 
  19. 김선덕, 이도협, 2006, 새로운 N,N,O계 세 자리 리간드의 합성과 전위차적정 법에 의한 전이금속 착물의 안정도상수의 결정, 한국환경과학회지, 15(8), 799-809 
  20. Kim S. D., Jin G. R., 2006, Synthesis of new $N_2O_2$ tetradentate ligands and the substituent effect on the stability constants of the transition metal complexes, Analytical Science & Technology, 19(2), 131-141 
  21. 김선덕, 김준광, 이경호, 2007, 중금속이온 분리를 위한 새로운 네 자리 $N_2O_2$계 리간드의 합성 및 착화합물의 안정도상수 결정, 한국환경과학회지, 16(8), 913-920 
  22. Martell A. E., Motekaitis R. J., 1992, Detemination and Use of Stability Constants. 2nd ed. VCH, N. Y 
  23. Motekaitis R. J., Martell A. E., 1992, Stabilities of Metal Complexes of the Meso and SS Isomers of Oxydisuccinic Acid. Inorg. Chem., 31, 11-15 
  24. Parsons G. H., Rochester C H., 1975, Acid Ionization Constants of 4-Substitutes Phenols in Methanol+Water Mixtures. J. Chem. Soc. Faraday, 71, 1058-1068 
  25. Koseoglu F., Kilic E., Uysal D., 1995, Protonation constants of some substituted 2-hydroxy-I-naphthalideneanilines in dioxan-water mixtures, Talanta., 42, 1875-1882 
  26. Kilic F., Canel E., Yilmaz E., 1994, Protonation constants of some substituted salicylidineanilines in ethanol-water mixtures, Analytica Chimica Acta., 293, 87-94 
  27. Jaffe H. H., 1953, A Reexamination of the Hammett Equation, Chem. Rev., 53, 191-261 
  28. Hoefnagel A. J., Hoefnagel M. A., Wepster B. M., 1978, J. Org. Chem., 43(25), 4720-4745 
  29. Walkwiak W., Stewart L. E., Lee H. K., Szech B. P., Bartsch R. A., Anal. Cheme., 1986, Compectitive Solvent Extrction of Alkaline-Earth Cations into Chloroform by Lipophilic Acyclic Diionzable Polyethcrs, Anal. Chem., 58, 188-191 
  30. Kang S. I., Czech A., Czech B. P., Stewart L. E., Bartsch R. A., 1985, Compectitive Solvent Extrction of Alkaline-Earth Cations into Chloroform by Lipophilic Acyclic Polyether Dicarboxylic Acids, Anal. Chem., 57, 1713-1717 
  31. Ercorani, G., Mandolini. L., Masci, B., 1981, Template Effects. 3. The Quantitative Determination of the Catalytic of Alkali and Alkaline Earth Cations in the Formation of Benzo-18-crown-6 in Methanol Solution, J. Am. Chem. Soc., 103, 2780 
  32. Hall E. A., Amma E. L., 1969, Macrocyc1ic Effect on the Stability of Copper(II) Tetraamine Complexes, J. Am. Chem. Soc., 5, 6540-6541 
  33. Juan A. A., Antonio B., Enrique G. E., Santoago V. L., Jose M. L., Jose A. R., Conxa S., 1994, Synthesis, Protonation and Co-ordina tion Abilities of the Open-chain Polyamine 4,8,11,15-Tetraazaocta decane- 1,18-diamine, J. Chem. Soc., Dalton Trans, 637-634 
  34. Coleman W. M., 1981, Relationships between Ligand Carbon-13 Chemical Shifts and Reduction Potentials of Mn(Ill) Complex, Inorg. Chim. Acta., 53, 191-193 

이 논문을 인용한 문헌 (1)

  1. Kim, Sun-Deuk ; Lee, Hye-Won ; Seol, Jong-Min 2010. "Synthesis of New Nitrogen-Oxygen(N3O2) Pentadentate Ligands and the Substituent Effect on the Stability Constants of the Heavy(II) Metal Complexes" 한국환경과학회지 = Journal of the environmental sciences, 19(7): 849~860 

원문보기

원문 PDF 다운로드

  • ScienceON :
  • KCI :

원문 URL 링크

원문 PDF 파일 및 링크정보가 존재하지 않을 경우 KISTI DDS 시스템에서 제공하는 원문복사서비스를 사용할 수 있습니다. (원문복사서비스 안내 바로 가기)

상세조회 0건 원문조회 0건

DOI 인용 스타일