[논문]고성능 탄화수소계 고분자 전해질막의 합성 전략

이소영; 김형준; 남상용; 박치훈

doi:10.14579/membrane_journal.2016.26.1.1

고성능 탄화수소계 고분자 전해질막의 합성 전략
Synthetic Strategies for High Performance Hydrocarbon Polymer Electrolyte Membranes (PEMs) for Fuel Cells 원문보기

멤브레인 = Membrane Journal, v.26 no.1, 2016년, pp.1 - 13

이소영 (한국과학기술연구원 연료전지센터) , 김형준 (한국과학기술연구원 연료전지센터) , 남상용 (경상대학교나노신소재융합공학과, 공학연구원) , 박치훈 (경남과학기술대학교 에너지공학과)

초록
AI-Helper

연료전지는 화석연료, 특히 내연기관을 대체할 수 있는 가장 대표전인 에너지 기술이다. 가장 중요한 핵심 재료 중 하나로서 연료기체의 장벽 역할을 함과 동시에 수소이온전달 역할을 하는 고분자 전해질 막(PEM)이 있다. PEM 내부에서 수화 채널은 수소이온의 전달통로 역할을 하기 때문에, 많은 연구자들은 높은 함수율을 저가습 상태에서도 유지하여 우수한 수소이온 전달 능력을 보유할 수 있는 상분리현상을 통한 친수성 채널 형성에 대하여 초점을 맞추어 왔다. 본 총설에서는 이러한 낮은 가습조건에서도 높은 수소이온전도도를 갖는 술폰화 PEM들의 합성 전략에 대하여 논의 하여보고, 다른 연구자들의 고성능 탄화수소계 PEM의 설계에 도움을 주고자 하였다.

Abstract ▼ AI-Helper

Fuel cells are regarded as a representative energy source expected to replace fossil fuels particularly used in internal combustion engines. One of the most important components is polymer electrolyte membranes (PEMs) acting as a proton conducting barrier to prevent fuel gas crossover. Since water channels act as proton pathways through PEMs, many researchers have been focused on the 'good phase-separation of hydrophilic moiety' which ensures high water retention under low humidity enough to keep the water channel for good proton conduction. Here, we summarized the strategies which have been adopted to synthesize sulfonated PEMs having high proton conductivities even under low humidified conditions, and hope this review will be helpful to design high performance hydrocarbon PEMs.

주제어

AI 본문요약
AI-Helper

* AI 자동 식별 결과로 적합하지 않은 문장이 있을 수 있으니, 이용에 유의하시기 바랍니다.

제안 방법

[32]. studied the effect of molecular weights of poly(p-phenylene) on their properties for PEMs, and concluded that high molecular weight poly(p-phenylene) could retain high IEC values and high proton conductivities without loss of mechanical properties and dimensional stability.
[40]. studied the properties of an alternating sulfonated poly(arylene ether ketone), a random sulfonated poly(arylene ether sulfone), and a multiblock copolymer of sulfonated poly(arylene ether sulfone) and polyimide. The multiblock copolymer outperformed both the others in proton conductivity and fuel cell performance, as it showed a well-defined structure with continuous hydrophilic and hydrophobic pathways responsible for fast proton transport.

참고문헌 (55)

L. Maugeri, "Understanding oil price behavior through an analysis of a crisis", Rev. Environ. Econ. Policy, 3, 147 (2009).

상세보기
J. A. Cook, C. R. Ramsay, and P. Fayers, "Using the literature to quantify the learning curve: A case study", Int. J. Technol. Assess. Health Care, 24, 131 (2008).

상세보기
R. Wycisk and P. Pintauro, "Fuel cells II", pp.157-183, Springer, Heidelberg (2008).
H. R. Allcock, "Recent developments in polyphosphazene materials science", Curr. Opin. Solid State Mater. Sci., 10, 231 (2006).

상세보기
M. A. Hickner, H. Ghassemi, Y. S. Kim, B. R. Einsla, and J. E. McGrath, "Alternative polymer systems for proton exchange membranes (PEMs)", Chem. Rev., 104, 4587 (2004).

상세보기
M. Kim, Y. Lee, J. Kim, H. Kim, T. Lim, and I. Moon, "Multiscale modeling and simulation of direct methanol fuel cell", Membr. J., 20, 29 (2010).
K.-D. Kreuer, A. Rabenau, and W. Weppner, "Vehicle mechanism, A new model for the interpretation of the conductivity of fast proton conductors", Angew. Chem. Int. Edit., 21, 208 (1982).
K.-D. Kreuer, S. J. Paddison, E. Spohr, and M. Schuster, "Transport in proton conductors for fuel-cell applications: Simulations, elementary reactions, and phenomenology", Chem. Rev., 104, 4637 (2004).

상세보기
K. A. Mauritz and R. B. Moore, "State of understanding of nafion", Chem. Rev., 104, 4535 (2004).

상세보기
N. Li, C. Wang, S. Y. Lee, C. H. Park, Y. M. Lee, and M. D. Guiver, "Enhancement of proton transport by nanochannels in comb-shaped copoly(arylene ether sulfone)s", Angew. Chem. Int. Edit., 50, 9158 (2011).

상세보기
K. Yoon, J. H. Choi, J. K. Choi, S. K. Hong, Y. T. Hong, and H. Byun, "Fabrication and characterization of partially covalent-crosslinked poly(arylene ether sulfone)s for use in a fuel cell", Membr. J., 18, 274 (2008).
D. J. Kim, H. Y. Hwang, and S. Y. Nam, "Characterization of composite membranes made from sulfonated poly(arylene ether sulfone) and vermiculite with high cation exchange capacity for DMFC applications", Membr. J., 21, 389 (2011).
C. H. Park, H. S. Kim, and Y. M. Lee, "Surface modification of proton exchange membrane by introduction of excessive amount of nanosized silica", Membr. J., 24, 301 (2014).

원문보기 상세보기
K.-K. Lee, T.-H. Kim, T.-S. Hwang, and Y. T. Hong, "Novel sulfonated poly(arylene ether sulfone) composite membranes containing tetraethyl orthosilicate (TEOS) for PEMFC applications", Membr. J., 20, 278 (2010).
D. J. Kim, H. Y. Hwang, and S. Y. Nam, "Characterization of composite membranes made from sulfonated poly(arylene ether sulfone) and vermiculite with high cation exchange capacity for DMFC applications", Membr. J., 21, 389 (2011).
D. J. Kim and S. Y. Nam, "Research trend of organic/ inorganic composite membrane for polymer electrolyte membrane fuel cell", Membr. J., 22, 155 (2012).
G. Maier and J. Meier-Haack, "Fuel cells II", pp.1-62, Springer, Heidelberg (2008).
J. Meier-Haack, A. Taeger, C. Vogel, K. Schlenstedt, W. Lenk, and D. Lehmann, "Membranes from sulfonated block copolymers for use in fuel cells", Sep. Purif. Technol., 41, 207 (2005).

상세보기
M. Rikukawa and K. Sanui, "Proton-conducting polymer electrolyte membranes based on hydrocarbon polymers", Prog. Polym. Sci., 25, 1463 (2000).

상세보기
K. D. Kreuer, "Hydrocarbon membranes", Handbook of Fuel Cells, 3, 420 (2003).
J. Roziere and D. J. Jones, "Non-fluorinated polymer materials for proton exchange membrane fuel cells", Annu. Rev. Mater. Res., 33, 503 (2003).

상세보기
R. Y. M. Huang, P. Shao, C. M. Burns, and X. Feng, "Sulfonation of poly(ether ether ketone)(PEEK): Kinetic study and characterization", J. Appl. Polym. Sci., 82, 2651 (2001).

상세보기
B. Yang and A. Manthiram, "Sulfonated poly(ether ether ketone) membranes for direct methanol fuel cells", Electrochem. Solid-State Lett., 6, A229 (2003).

상세보기
K. Miyatake, T. Yasuda, and M. Watanabe, "Substituents effect on the properties of sulfonated polyimide copolymers", J. Polym. Sci., Part A: Polym. Chem., 46, 4469 (2008).

상세보기
S. Matsumura, A. R. Hlil, C. Lepiller, J. Gaudet, D. Guay, and A. S. Hay, "Ionomers for proton exchange membrane fuel cells with sulfonic acid groups on the end groups: Novel linear aromatic poly(sulfide-ketone)s", Macromolecules, 41, 277 (2007).
S. Matsumura, A. R. Hlil, N. Du, C. Lepiller, J. Gaudet, D. Guay, Z. Shi, S. Holdcroft, and A. S. Hay, "Ionomers for proton exchange membrane fuel cells with sulfonic acid groups on the end-groups: Novel branched poly(ether-ketone)s with 3,6-ditrityl-9H-carbazole end-groups", J. Polym. Sci., Part A: Polym. Chem., 46, 3860 (2008).

상세보기
M. A. Abu-Saied, A. A. Elzatahry, K. M. El-Khatib, E. A. Hassan, M. M. El-Sabbah, E. Drioli, and M. S. M. Eldin, "Preparation and characterization of novel grafted cellophane-phosphoric acid-doped membranes for proton exchange membrane fuel-cell applications", J. Appl. Polym. Sci., 123, 3710 (2012).

상세보기
J. Ding, C. Chuy, and S. Holdcroft, "Solid polymer electrolytes based on ionic graft polymers: Effect of graft chain length on nano-structured, ionic networks", Adv. Funct. Mater., 12, 389 (2002).

상세보기
J. Parvole and P. Jannasch, "Polysulfones grafted with poly(vinylphosphonic acid) for highly proton conducting fuel cell membranes in the hydrated and nominally dry state", Macromolecules, 41, 3893 (2008).

상세보기
S. Seesukphronrarak and A. Ohira, "Novel highly proton conductive sulfonated poly(p-phenylene) from 2,5-dichloro-4-(phenoxypropyl)benzophenone as proton exchange membranes for fuel cell applications", Chem. Commun., 4744 (2009).
S. Seesukphronrarak, K. Ohira, K. Kidena, N. Takimoto, C. S. Kuroda, and A. Ohira, "Synthesis and properties of sulfonated copoly(p-phenylene)s containing aliphatic alkyl pendant for fuel cell applications", Polymer, 51, 623 (2010).

상세보기
I. Tonozuka, M. Yoshida, K. Kaneko, Y. Takeoka, and M. Rikukawa, "Considerations of polymerization method and molecular weight for proton-conducting poly(p-phenylene) derivatives", Polymer, 52, 6020 (2011).

상세보기
D. S. Kim, G. P. Robertson, Y. S. Kim, and M. D. Guiver, "Copoly(arylene ether)s containing pendant sulfonic acid groups as proton exchange membranes", Macromolecules, 42, 957 (2009).

상세보기
T. B. Norsten, M. D. Guiver, J. Murphy, T. Astill, T. Navessin, S. Holdcroft, B. L. Frankamp, V. M. Rotello, and J. Ding, "Highly fluorinated comb-shaped copolymers as proton exchange membranes (PEMs): Improving PEM properties through rational design", Adv. Funct. Mater., 16, 1814 (2006).

상세보기
B. Lafitte, M. Puchner, and P. Jannasch, "Proton conducting polysulfone ionomers carrying sulfoaryloxybenzoyl side chains", Macromol. Rapid Commun., 26, 1464 (2005).

상세보기
N. Li, D. W. Shin, D. S. Hwang, Y. M. Lee, and M. D. Guiver, "Polymer electrolyte membranes derived from new sulfone monomers with pendent sulfonic acid $groups^{\dagger}$ ", Macromolecules, 43, 9810 (2010).

상세보기
C. Wang, N. Li, D. W. Shin, S. Y. Lee, N. R. Kang, Y. M. Lee, and M. D. Guiver, "Fluorene-based poly(arylene ether sulfone)s containing clustered flexible pendant sulfonic acids as proton exchange membranes", Macromolecules, 44, 7296 (2011).

상세보기
Y. A. Elabd, E. Napadensky, C. W. Walker, and K. I. Winey, "Transport properties of sulfonated poly(styrene-b-isobutylene-b-styrene) triblock copolymers at high ion-exchange capacities", Macromolecules, 39, 399 (2005).
J.-H. Choi, C. L. Willis, and K. I. Winey, "Structure-property relationship in sulfonated pentablock copolymers", J. Membr. Sci., 394-395, 169 (2012).
M. L. Einsla, Y. S. Kim, M. Hawley, H.-S. Lee, J. E. McGrath, B. Liu, M. D. Guiver, and B. S. Pivovar, "Toward improved conductivity of sulfonated aromatic proton exchange membranes at low relative humidity", Chem. Mater., 20, 5636 (2008).

상세보기
H. Ghassemi, J. E. McGrath, and T. A. Zawodzinski Jr, "Multiblock sulfonated-fluorinated poly(arylene ether)s for a proton exchange membrane fuel cell", Polymer, 47, 4132 (2006).

상세보기
K. Matsumoto, T. Higashihara, and M. Ueda, "Star-shaped sulfonated block copoly(ether ketone)s as proton exchange membranes", Macromolecules, 41, 7560 (2008).

상세보기
X. Yu, A. Roy, S. Dunn, J. Yang, and J. E. McGrath, "Synthesis and characterization of sulfonated-fluorinated, hydrophilic-hydrophobic multiblock copolymers for proton exchange membranes", Macromol. Symp., 245-246, 439 (2006).

상세보기
H.-Y. Lee, I. Bae, and K.-H. Min, "Solvent effect on sulfur ylide mediated epoxidation reaction", Bull. Korean Chem. Soc., 28, 2051 (2007).

원문보기 상세보기
A. Roy, M. A. Hickner, X. Yu, Y. Li, T. E. Glass, and J. E. McGrath, "Influence of chemical composition and sequence length on the transport properties of proton exchange membranes", J. Polym. Sci., Part B: Polym. Phys., 44, 2226 (2006).
H.-S. Lee, A. S. Badami, A. Roy, and J. E. McGrath, "Segmented sulfonated poly(arylene ether sulfone)-b-polyimide copolymers for proton exchange membrane fuel cells. I. Copolymer synthesis and fundamental properties", J. Polym. Sci., Part A: Polym. Chem., 45, 4879 (2007).

상세보기
H.-S. Lee, A. Roy, O. Lane, S. Dunn, and J. E. McGrath, "Hydrophilic-hydrophobic multiblock copolymers based on poly(arylene ether sulfone) via low-temperature coupling reactions for proton exchange membrane fuel cells", Polymer, 49, 715 (2008).

상세보기
B. Bae, K. Miyatake, and M. Watanabe, "Synthesis and properties of sulfonated block copolymers having fluorenyl groups for fuel-cell applications", ACS Appl. Mater. Interfaces, 1, 1279 (2009).

상세보기
B. Bae, T. Yoda, K. Miyatake, H. Uchida, and M. Watanabe, "Proton-conductive aromatic ionomers containing highly sulfonated blocks for high-temperature-operable fuel cells", Angew. Chem. Int. Ed., 49, 317 (2010).

상세보기
K. Nakabayashi, T. Higashihara, and M. Ueda, "Polymer electrolyte membranes based on cross-linked highly sulfonated multiblock copoly(ether sulfone)s", Macromolecules, 43, 5756 (2010).

상세보기
S. Takamuku and P. Jannasch, "Fully aromatic block copolymers for fuel cell membranes with densely sulfonated nanophase domains", Macromol. Rapid Commun., 32, 474 (2011).

상세보기
S. Matsumura, A. R. Hlil, C. Lepiller, J. Gaudet, D. Guay, Z. Shi, S. Holdcroft, and A. S. Hay, "Ionomers for proton exchange membrane fuel cells with sulfonic acid groups on the end groups: Novel branched poly(ether-ketone)s", Macromolecules, 41, 281 (2007).

상세보기
S. Tian, Y. Meng, and A. S. Hay, "Membranes from poly(aryl ether)-based ionomers containing randomly distributed nanoclusters of 6 or 12 sulfonic acid groups", Macromolecules, 42, 1153 (2009).

상세보기
K. Matsumoto, T. Higashihara, and M. Ueda, "Locally and densely sulfonated poly(ether sulfone)s as proton exchange membrane", Macromolecules, 42, 1161 (2009).

상세보기
K. Matsumoto, T. Higashihara, and M. Ueda, "Locally sulfonated poly(ether sulfone)s with highly sulfonated units as proton exchange membrane", J. Polym. Sci., Part A: Polym. Chem., 47, 3444 (2009).

상세보기

저자의 다른 논문 :

LOADING...

표제어: PCR

동의어: Packet Collision Rate

용어 설명 출처 목록 (6)

용어 설명: PCR은 세균 특이성이 있는 primer를 이용하여 적은 수의 세균이 있을지라도 쉽게 검출할 수 있는 유용한 방법이며, 이를 이용하여 구강 내 치면세균막이나 타액에서 직접 세균을 검출할 수 있게 되었다[8].

내보내기 구분	파일저장 인쇄 메일전송
구성항목	기본정보 상세정보 관리번호, 논문명, 저널/프로시딩명, 저자 , 발행년, 권, 호, 시작페이지, 끝페이지, 발행기관 관리번호, 논문명, 대등논문명, 저자 , 저널/프로시딩명, 발행기관, 발행년, 발행언어, 권, 호, 시작페이지, 끝페이지, ISBN, ISSN, 주제분야, 키워드, 초록(한글), 초록(영문), 저자(소속기관)
저장형식	Text(ASCII format) Excel format RefWorks Direct Export RIS format (for Reference Manager, ProCite, EndNote), Scholar's Aids, Mendeley
메일정보	받는사람 (필수) @ 보내는사람 (선택) @ 제목 내용 KISTI 검색결과 이메일 서비스
안내	총 건의 자료가 검색되었습니다. 다운받으실 자료의 인덱스를 입력하세요. (1-10,000) 검색결과의 순서대로 최대 10,000건 까지 다운로드가 가능합니다. 데이타가 많을 경우 속도가 느려질 수 있습니다.(최대 2~3분 소요) 다운로드 파일은 UTF-8 형태로 저장됩니다. 파일의 내용이 제대로 보이지 않을실 때는 웹브라우저 상단의 보기 -> 인코딩 -> 자동선택 여부를 확인하십시오. ~ Text(ASCII format) Excel format

연합인증