[논문]Anticorrosion Coatings Obtained by Plasma Electrolytic Oxidation on Implant Metals and Alloys

Sinebryukhov, S.L.; Gnedenkov, S.V.; Khrisanfova, O.A.; Puz', A.V.; Egorkin, V.S.; Zavidnaya, A.G.

doi:10.14773/cst.2018.17.3.91

Anticorrosion Coatings Obtained by Plasma Electrolytic Oxidation on Implant Metals and Alloys 원문보기

Corrosion science and technology, v.17 no.3, 2018년, pp.91 - 100

Sinebryukhov, S.L. (Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences) , Gnedenkov, S.V. (Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences) , Khrisanfova, O.A. (Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences) , Puz', A.V. (Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences) , Egorkin, V.S. (Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences) , Zavidnaya, A.G. (Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences)

Abstract ▼ AI-Helper

Development of biodegradable implants for treatment of complex bone fractures has recently become one of the priority areas in biomedical materials research. Multifunctional corrosion resistant and bioactive coatings containing hydroxyapatite $Ca_{10}(PO_4)_6(OH)_2$ and magnesium oxide MgO were obtained on Mg-Mn-Ce magnesium alloy by plasma electrolytic oxidation. The phase and elemental composition, morphology, and anticorrosion properties of the coatings were investigated by scanning electron microscopy, energy dispersive spectroscopy, potentiodynamic polarization, and electrochemical impedance spectroscopy. The PEO-layers were post-treated using superdispersed polytetrafluoroethylene powder. The duplex treatment considerably reduced the corrosion rate (>4 orders of magnitude) of the magnesium alloy. The use of composite coatings in inducing bioactivity and controlling the corrosion degradation of resorbable Mg implants are considered promising. We also applied the plasma electrolytic oxidation method for the formation of the composite bioinert coatings on the titanium nickelide surface in order to improve its electrochemical properties and to change the morphological structure. It was shown that formed coatings significantly reduced the quantity of nickel ions released into the organism.

주제어

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문제 정의

The corrosion resistant layers formed using plasma electrolytic oxidation with subsequent SPTFE-treatment on the surface of titanium nickelide have been developed. The results of the comprehensive study show improvement of the protective characteristics and significant reduction of the nickel ions diffusion.

제안 방법

The measurements were carried out in three electrode cells at room temperature in an artificial physiological solution (NaCl – 8.4 g/l; NaHCO3 – 0.35 g/l; Na2HPO4·2H2O – 0.06 g/l; NaH2PO4·2H2O – 0.06 g/l).
This work has experimentally demonstrated that hydroxyapatite-containing protective coatings with the Ca/P ratio close to that of the bone tissue can be fabricated on the surface of Mg-Mn-Ce alloy by the pulsed bipolar PEO process in the electrolyte containing calcium glycerophosphate and sodium fluoride. The coatings have a convoluted porous morphology, which is favourable for osteoblast adhesion, and, at the same time, significantly reduces the corrosion rate of the magnesium alloy, which allows them to be considered promising for biodegradable Mg mplant applications.

이론/모형

The corrosion current density, I_C, and polarization resistance, R_p, were calculated using the Stern-Geary equation. When impedance measurements were carried out, perturbing sinusoidal signals with an amplitude of 10 mV and a frequency varying from 0.

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Anticorrosion Coatings Obtained by Plasma Electrolytic Oxidation on Implant Metals and Alloys 원문보기

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Anticorrosion Coatings Obtained by Plasma Electrolytic Oxidation on Implant Metals and Alloys 원문보기

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