[논문]A New Fe (III)-Selective Membrane Electrode Based on Fe (II) Phthalocyanine

Ozer, Tugba; Isildak, Ibrahim

doi:10.33961/jecst.2019.00038

A New Fe (III)-Selective Membrane Electrode Based on Fe (II) Phthalocyanine 원문보기

Journal of electrochemical science and technology, v.10 no.3, 2019년, pp.321 - 328

Ozer, Tugba (Faculty of Chemistry-Metallurgy, Department of Bioengineering, Yildiz Technical University) , Isildak, Ibrahim (Faculty of Chemistry-Metallurgy, Department of Bioengineering, Yildiz Technical University)

Abstract ▼ AI-Helper

A new miniaturized all solid-state contact Fe (III)-selective PVC membrane electrode based on Fe (II) phthalocyanine as a neutral carrier was described. The effects of the membrane composition and foreign ions on the electrode performance was investigated. The best performance was obtained with a membrane containing 32% poly (vinyl chloride), 64% dioctylsebacate, 3% Fe (II) phthalocyanine, and 1% potassium tetrakis (p-chlorophenyl) borate. The electrode showed near Nernstian response of $26.04{\pm}0.95mV/decade$ over the wide linear concentration range $1.0{\times}10^{-6}$ to $1.0{\times}10^{-1}M$, and a very low limit of detection $1.8{\pm}0.5{\times}10^{-7}M$. The potentiometric response of the developed electrode was independent at pH 3.5-5.7. The lifetime of the electrode was approximately 3 months and the response time was very short (< 7 s). It exhibited excellent selectivity towards Fe (III) over various cations. The miniaturized all solid-state contact Fe (III)-selective membrane electrode was successfully applied as an indicator electrode for the potentiometric titration of $1.0{\times}10^{-3}M$ Fe (III) ions with a $1.0{\times}10^{-2}M$ EDTA and the direct determination of Fe (III) ions in real water samples.

주제어

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제안 방법

Then, calibration graphs were plotted by using the recorded potentials versus log [Fe (III) ion]. The obtained graphs were evaluated in order to identify the response of the proposed electrode.
The potentiometric measurements was performed by using a computer-controlled high-input impedance multi-channel potentiometric measurement system (sensitivity ± 0.1 mV) with a custom-made software program (Medisen Ar-Ge, Turkey).
The proposed electrode was applied to determine Fe (III) ion in tap water (Yildiz Technical University), mineral water (Kizilay mineral water, marketed in Turkey) and river water (Istanbul, Turkey) in order to investigate the applicability of the electrode. The Fe (III) concentrations in the samples were assessed by standard addition method.

대상 데이터

Tetrahydrofuran (THF), potassium tetrakis (p-chlorophenyl) borate (KTpClPB), graphite, Fe (II) phthalocyanine, high molecular weight poly(vinyl chloride) (PVC) and plasticizers, o-nitrophenyl octyl ether (NPOE), dioctylsebacate (DOS), dibutyl phthalate (DBP), dioctyl phthalate (DOP) were purchased from Fluka(Bucks, Switzerland). Epoxy (Macroplast Su 2227) and hardener (Desmodur RFE) were obtained from Henkel (Istanbul, Turkey) and Bayer AG (Darmstadt, Germany) respectively. All of the cationic solutions were prepared from their nitrate and chloride salt in doubly distilled water and, used without any further purification except for vacuum drying over P₂O₅.
Four different electrodes with the same optimized compositions were used in order to examine the reproducibility of the proposed electrode. The relative standard deviation (RSD) for five measurements was attained as 3.
All chemicals and reagents were of analytical grade quality and were used as received. Tetrahydrofuran (THF), potassium tetrakis (p-chlorophenyl) borate (KTpClPB), graphite, Fe (II) phthalocyanine, high molecular weight poly(vinyl chloride) (PVC) and plasticizers, o-nitrophenyl octyl ether (NPOE), dioctylsebacate (DOS), dibutyl phthalate (DBP), dioctyl phthalate (DOP) were purchased from Fluka(Bucks, Switzerland). Epoxy (Macroplast Su 2227) and hardener (Desmodur RFE) were obtained from Henkel (Istanbul, Turkey) and Bayer AG (Darmstadt, Germany) respectively.

이론/모형

The proposed electrode was applied to determine Fe (III) ion in tap water (Yildiz Technical University), mineral water (Kizilay mineral water, marketed in Turkey) and river water (Istanbul, Turkey) in order to investigate the applicability of the electrode. The Fe (III) concentrations in the samples were assessed by standard addition method.

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