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Preparation of chemically uniform and monodisperse microparticles as highly efficient solid acid catalysts for aldol condensation

Chemical engineering science, v.175, 2018년, pp.168 - 174  

Kim, Jongmin (Department of Chemical Engineering and Applied Chemistry, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Republic of Korea) ,  Jin, Si Hyung (Department of Chemical Engineering and Applied Chemistry, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Republic of Korea) ,  Kang, Kyoung-Ku (Department of Chemical Engineering and Applied Chemistry, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Republic of Korea) ,  Chung, Young-Min (Department of Nano & Chemical Engineering, Kunsan National University, 558 Daehak-ro, Kunsan, Jeollabuk-Do 54150, Republic of Korea) ,  Lee, Chang-Soo (Department of Chemical Engineering and Applied Chemistry, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Republic of Korea)

Abstract AI-Helper 아이콘AI-Helper

Highly active heterogeneous catalysts are in high demand, but realizing an efficient heterogeneous catalyst with uniform active sites remains challenging. In this study, we present a facile preparation of carboxylic acid-incorporated monodisperse microparticles (COOH-MPs) with uniform active sites a...

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참고문헌 (35)

  1. Catal. Sci. Technol. Tayade 3 1288 2013 10.1039/c3cy20613k A study on factors influencing cross and self product selectivity in aldol condensation over propylsulfonic acid functionalized silica 

  2. Micropor. Mesopor. Mater. Prabhu 168 126 2013 10.1016/j.micromeso.2012.09.020 Mesoporous cubic Ia3d materials for the preparation of fine chemicals: synthesis of jasminaldehyde 

  3. J. Mol. Catal. A: Chem. Sharma 280 61 2008 10.1016/j.molcata.2007.10.013 Synthesis of jasminaldehyde using magnesium organo silicate as a solid base catalyst 

  4. J. Catal. Climent 175 70 1998 10.1006/jcat.1998.1970 Use of mesoporous MCM-41 aluminosilicates as catalysts in the preparation of fine chemicals - a new route for the preparation of Jasminaldehyde with high selectivity 

  5. Adv. Synth. Catal. Yadav 346 389 2004 10.1002/adsc.200303212 Preparation of the novel mesoporous solid acid catalyst UDCaT-4 via synergism of persulfated alumina and zirconia into hexagonal mesoporous silica for alkylation reactions 

  6. Korean J. Chem. Eng. Hu 33 1232 2016 10.1007/s11814-015-0267-8 Efficient hydrolysis of cellulose over a magnetic lignin-derived solid acid catalyst in 1-butyl-3-methylimidazolium chloride 

  7. Korean J. Chem. Eng. Sun 28 99 2011 10.1007/s11814-010-0324-2 H3PW12O40/SiO2 for sorbitol dehydration to isosorbide: high efficient and reusable solid acid catalyst 

  8. Chem. Soc. Rev. Margelefsky 37 1118 2008 10.1039/b710334b Cooperative catalysis by silica-supported organic functional groups 

  9. Angew. Chem. Int. Ed. Shiju 50 9615 2011 10.1002/anie.201101449 Mesoporous silica with site-isolated amine and phosphotungstic acid groups: a solid catalyst with tunable antagonistic functions for one-pot tandem reactions 

  10. J. Mol. Catal. A: Chem. Ganga 420 264 2016 10.1016/j.molcata.2016.04.030 P-Toluene sulfonic acid (PTSA)-MCM-41 as a green, efficient and reusable heterogeneous catalyst for the synthesis of jasminaldehyde under solvent-free condition 

  11. Korean J. Chem. Eng. Zhu 34 110 2017 10.1007/s11814-016-0220-5 Synthesis and characteristics of lignin-derived solid acid catalysts for microcrystalline cellulose hydrolysis 

  12. Korean J. Chem. Eng. Wang 34 664 2017 10.1007/s11814-016-0299-8 Effect of acid sites on catalytic destruction of trichloroethylene over solid acid catalysts 

  13. J. Am. Chem. Soc. Manabe 123 10101 2001 10.1021/ja016338q Dehydration reactions in water. Surfactant-type Bronsted acid-catalyzed direct esterification of carboxylic acids with alcohols in an emulsion system 

  14. Angew. Chem. Int. Ed. Kunishima 44 7254 2005 10.1002/anie.200502594 Unusual rate enhancement of bimolecular dehydrocondensation to form amides at the interface of micelles of fatty acid salts 

  15. Proc. Natl. Acad. Sci. U.S.A. Wang 97 9861 2000 10.1073/pnas.180192597 Gel catalysts that switch on and off 

  16. J. Org. Chem. Wang 74 1923 2009 10.1021/jo802427k Pd-catalyzed C-C cross-coupling reactions within a thermoresponsive and pH-responsive and chelating polymeric hydrogel 

  17. Chem. Soc. Rev. Diaz 40 427 2011 10.1039/C005401C Stimuli-responsive gels as reaction vessels and reusable catalysts 

  18. Chem. Sci. Yue 6 6112 2015 10.1039/C5SC01978H Design rationale of thermally responsive microgel particle films that reversibly absorb large amounts of CO2: fine tuning the pK(a) of ammonium ions in the particles 

  19. Polym. J. (Tokyo, Jpn.) Seto 48 897 2016 10.1038/pj.2016.44 Polymer microgel particles as basic catalysts for Knoevenagel condensation in water 

  20. Micropor. Mesopor. Mater. Jaenicke 35-6 143 2000 10.1016/S1387-1811(99)00215-2 Organic-inorganic hybrid catalysts for acid- and base-catalyzed reactions 

  21. J. Catal. Climent 197 385 2001 10.1006/jcat.2000.3086 Acid-base bifunctional catalysts for the preparation of fine chemicals: synthesis of jasminaldehyde 

  22. Catal. Lett. Yu 77 165 2001 10.1023/A:1012735011521 Al-MCM-41 supported magnesium oxide as catalysts for synthesis of alpha-pentylcinnamaldehyde 

  23. React. Kinet. Catal. Lett. Yu 72 365 2001 10.1023/A:1010571703071 Cross aldolization between benzaldehyde and n-heptaldehyde to alpha-pentylcinnamaldehyde over calcined Mg-Al hydrotalcites 

  24. Adv. Synth. Catal. Climent 344 1090 2002 10.1002/1615-4169(200212)344:10<1090::AID-ADSC1090>3.0.CO;2-X Aldol condensations on solid catalysts: a cooperative effect between weak acid and base sites 

  25. J. Mol. Catal. A: Chem. Sudheesh 321 77 2010 10.1016/j.molcata.2010.02.005 Chitosan as an eco-friendly solid base catalyst for the solvent-free synthesis of jasminaldehyde 

  26. Catal. Sci. Technol. Perez-Sanchez 3 2732 2013 10.1039/c3cy00313b Synthesis of natural fragrance jasminaldehyde using silica-immobilized piperazine as organocatalyst 

  27. Clean Technol. Chung 20 116 2014 10.7464/ksct.2014.20.2.116 Aldol condensation over acid-base bifunctional metal-organic framework catalysts 

  28. J. Chem. Soc., Chem. Commun. Kloetstra 1005 1995 10.1039/c39950001005 Base and acid catalysis by the alkali-Containing MCM-41 mesoporous molecular sieve 

  29. Angew. Chem. Int. Ed. Choi 49 7748 2010 10.1002/anie.201002764 Surface-tension-induced synthesis of complex particles using confined polymeric fluids 

  30. Polymer (Korea) Yeom 40 457 2016 10.7317/pk.2016.40.3.457 Fabrication of multicompartment particles via sequential micromolding method 

  31. Anal. Chem. Lewis 82 5851 2010 10.1021/ac101032r Fabrication of uniform DNA-conjugated hydrogel microparticles via replica molding for facile nucleic acid hybridization assays 

  32. Chem. Eng. J. (Amsterdam, Neth.) Kim 321 384 2017 Reversible self-bending soft hydrogel microstructures with mechanically optimized designs 

  33. ACS Appl. Mater. Interfaces Oh 8 8782 2016 10.1021/acsami.5b12704 Control of reversible self-bending behavior in responsive janus microstrips 

  34. ACS Appl. Mater. Interfaces Choi 7 11393 2015 10.1021/acsami.5b01955 Controlled fabrication of microparticles with complex 3D geometries by tunable interfacial deformation of confined polymeric fluids in 2D micromolds 

  35. Polymer (Korea) Lee 39 814 2015 10.7317/pk.2015.39.5.814 Fabrication of microparticles with anisotropic patchy based on sequential micromolding technique 

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