The stereoselectivity of glycosylation … … reactions can depend critically on the reactivity of the acceptor glycoside (the nucleophile in the reaction). In their Communication on page 8240 ff., J. D. Codée et al. report a facile system that maps the relationship between glycosyl acceptor reactivity and glycosylation stereoselectivity. Tuning the reactivity of the nucleophile through the judicious choice of protecting groups can provide stereoselective 1,2‐cis‐glycosylations.
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