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Unveiling a Masked Polymer of Dewar Benzene Reveals trans-Poly(acetylene)

Macromolecules, v.52 no.8, 2019년, pp.2923 - 2931  

Seo, Jinwon (Center for Multidimensional Carbon Materials (CMCM) , Institute for Basic Science (IBS) , Ulsan 44919 , Republic of Korea) ,  Lee, Stanfield Y. (Center for Multidimensional Carbon Materials (CMCM) , Institute for Basic Science (IBS) , Ulsan 44919 , Republic of Korea) ,  Bielawski, Christopher W.

Abstract AI-Helper 아이콘AI-Helper

A dibromo derivative of Dewar benzene, trans-5,6-dibromobicyclo[2.2.0]hex-1-ene, was polymerized using ring-opening metathesis polymerization (ROMP). The reaction proceeded in a controlled manner as changing the initial monomer-to-catalyst ratio afforded monodispersed polymers with tunable molecular...

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