초록 ▼

A composition for coating paper, films and fiber materials, comprising A. 4 PARTS BY WEIGHT OF A LINEAR POLYORGANOSILOXANE WITH ENDS STOPPED BY VINYL GROUPS AND HAVING A VISCOSITY OF UP TO ABOUT 500 CP (20°C) and B. ABOUT 0.5 TO 1.5 PARTS BY WEIGHT OF A CROSSLINKING AGENT CONTAINING Si-vinyl units a

A composition for coating paper, films and fiber materials, comprising A. 4 PARTS BY WEIGHT OF A LINEAR POLYORGANOSILOXANE WITH ENDS STOPPED BY VINYL GROUPS AND HAVING A VISCOSITY OF UP TO ABOUT 500 CP (20°C) and B. ABOUT 0.5 TO 1.5 PARTS BY WEIGHT OF A CROSSLINKING AGENT CONTAINING Si-vinyl units and SiH units and comprising molecules with a maximum of about 10 Si atoms bonded to one another via oxygen, and wherein the two reactive groups are present in adjacent positions in one and the same molecule and the remaining valencies of the Si atom are saturated by methyl groups and the SiH groups are present in a ratio of about 1:1 to 2.5:1 to the total amount of all Si-vinyl units present in the composition, C. A PLATINUM METAL COMPLEX, THE AMOUNT OF METAL BEING UP TO ABOUT 0.01 PART BY WEIGHT －BASED ON 100 PARTS BY WEIGHT OF TOTAL COMPOSITION, AND D. A DIAZIRIDINE, THE AMOUNT OF DIAZIRIDINE BEING ABOUT 75 TO 250 TIMES THE WEIGHT OF METAL. The compositon has a viscosity of about 150 cP －the increase of the initial viscosity over a period to of at least 24 hours being less than 1 cP －easy application from existing equipment. The present invention relates to a coating agent based on polyorganosiloxanes which is suitable for the manufacture on non-stick films or coatings on paper, films, fabric tapes and similar materials, without the use of solvents. The application of non-stick polysiloxane coatings from water or organic solvents onto paper or similar materials has in itself been known for a long time (compare, for example, Noll, Chemie und Technologie der Silicone (Chemistry and Technology of the Silicones), 2nd edition, 1968, Verlag Chemie, Weinheim, page 520) and is extensively carried out in industry. The apparatuses suitable for the application of such coatings are in general designed to apply a coating material which contains solvent and are therefore adjusted to deal with viscosities of less than 150 cP or even of less than 100 cP. Such low viscosities have the advantage that they can be adjusted very precisely by means of the solvent. In addition, dilute solutions can be processed better, and the substrate is generally wetted better. In spite of these advantages, such coating systems containing solvents still suffer from considerable shortcomings. The main disadvantage is that about 92-97% of the mixture applied must again be removed. This requires high expenditure of energy. Furthermore, for reasons of protection of the environment and reasons of profitability, it is necessary either to recover the solvent removed in this way or, if recovery is not possible, to destroy the solvent, for example by combustion. However, this requires considerable expenditure on energy or apparatuses in every case. For these reasons there has been a constantly increasing demand for a coating without solvents, but of course it is a prerequisite that with a solvent-free coating system the advantage must not be achieved at the expense of a series of other disadvantages. Admittedly, some processes have already been disclosed (compare, for example, DT-OS (German Published Specification) No. 2,210,380 and DT-OS (German Published Specification No.) 2,321,879), in which the atteMpt to manage without solvents has been made. However, these systems in every case still suffer from a series of disadvantages so that they are unable satisfactorily to fulfil the demands made of them. Above all, it is in respect of their viscosity behavior －such systems are required to have a high degree of constancy of the viscosity －that the previously known systems have only been partially satisfactory. A further aspect of the viscosity problem which also still awaits a satisfactory solution in spite of the previously known processes and compositions is the initial viscosity. As is known to those skilled in the art, a mixture of a siloxane polymer with a crosslinking agent cannot directly be brought to a lower viscosity by shortening the siloxane chains of the polymer. Short-chain rubber molecules give a hard, crumbly film of low suppleness and poor mechanical properties. Applied to paper coating, this means that the film is not abrasion-resistant, and the inadequate abrasion resistance does not necessarily relate to the breaking of the bond between the substrate and the film but to the film itself breaking. Hence it is not surprising that all examples in the known publications relate to polymers of which the viscosity is in part many times higher than 150 cP. Accordingly, it is the object of the present invention to provide a coating system or coating process which makes it posible to achieve, by means of the applicator units of the state of the art, thin, commercially acceptable films of which the uniformity and mechanical properties are such as to give constant release properties and migration properties which meet practical requirements. In detail, this means that such a process must resort to compositions which in spite of the low initial viscosities are able to give films which withstand mechanical strain and repel adhesives, while the original viscosity must remain constant for at least 24 hours under conditions resembling those encountered in practice. This object is realized in accordance with the present invention pursuant to which there is provided a composition for coating paper, films and fiber materials, comprising a. 4 parts by weight of a linear polyorganosiloxane with ends stopped by vinyl groups and having a viscosity of up to about 500 cP (20°C), b. about 0.5 to 1.5 parts by weight of a crosslinking agent containing Si-vinyl units and SiH units, comprising molecules with a maximum of about 10 Si atoms bonded to one another via oxygen, and wherein the two reactive groups are present in adjacent positions in one and the same molecule and the remaining valencies of the Si atom are saturated by methyl groups and the SiH groups are present in a ratio of 2.5:1 to the total amount of all Si-vinyl units present in the composition, c. a platinum metal complex, the amount of metal being up to about 0.01 part by weight - based on 100 parts by weight of the composition, and d. a diaziridine, the amount of diaziridine being about 75 to 250 times the weight of metal. Accordingly, it was possible to achieve the present object by making 4 parts by polyorganosiloxane with ends stopped by vinyl groups and having a viscosity of at most 500 cP/20°C with 0.5 to 1.5 parts of a crosslinking agent carrying Si-vinyl groups and SiH groups; the molecular size of the crosslinking agent should not exceed 10 Si atoms which are bonded via oxygen and of which the remaining valencies are saturated by methyl groups, where they are not occupied by the above reactive groups, and the viscosity of the polyorganosiloxane is so chosen that it is more than 50 cP and that the viscosity of the total mixture does not exceed 150 cP. The SiH:Si-vinyl ratio in the mixture may vary between the ratios of 1:1 and 2.5:1. The crosslinking Agent used is such that it consists of one type of molecule and carries, in addition to SiH groups, a sufficient number of Si-vinyl groups that the above conditional ratios are observed. While the linear polyorganosiloxane has a viscosity which may be as high as 500 cP/20°C, it is blended with such an amount of crosslinking agent that the overall composition has a viscosity from about 50 to 150 cP/20°C. In the sense of the invention, polyorganosiloxanes with ends stopped by vinyl groups are polydiorganosiloxanes which terminate in CH2〓CH-Si(CH3)2O½units and of which the organo groups consist to the extent of at least about 70 % of methyl groups, the remainder

대표청구항 ▼

A composition for coating paper, films and fiber materials, comprising a. 4 parts by weight of a linear polyorgano siloxane with ends stopped by vinyl groups and having a viscosity of up to about 500 cP (20°C) and b. about 0.5 to 1.5 parts by weight of a crosslinking agent containing Si-vinyl units

A composition for coating paper, films and fiber materials, comprising a. 4 parts by weight of a linear polyorgano siloxane with ends stopped by vinyl groups and having a viscosity of up to about 500 cP (20°C) and b. about 0.5 to 1.5 parts by weight of a crosslinking agent containing Si-vinyl units and SiH units and comprising molecules with a miximum of about 10 Si atoms bonded to one another via oxygen, and wherein the two reactive groups are present in adjacent positions in one and the same molecule and the remaining valencies of the Si atom are saturated by methyl groups and the SiH groups are present in a ratio of about 1:1 to 2.5:1 to the total amount of all Si-vinyl units present in the composition, c. a platinum metal complex, the amount of metal being up to about 0.01 part by weight - based on 100 parts by weight of total composition, and d. a diaziridine of the formula [Figure] wherein R1 and R2 each individually is an alkyl radical containing up to 6 carbon atoms or R1 +R2 are pentamethylene or hexamethylene, the amount of diaziridine being about 75 to 250 times the weight of said metal.