Cationic hydrogels based on heterocyclic N-vinyl monomers
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C08F-220/20
C08F-026/00
출원번호
US-0549097
(1975-02-11)
발명자
/ 주소
Steckler Robert (San Diego CA)
출원인 / 주소
Plastomedical Sciences, Inc. (Briarcliff Manor NY 02)
인용정보
피인용 횟수 :
28인용 특허 :
0
초록▼
Novel cationic hydrogels, containing basic (cationic) groups in their molecular structure, and processes for their preparation are described. These novel hydrogels are stable, three-dimensional polymer networks, having good water permeability and mechanical properties. They are obtained by simultane
Novel cationic hydrogels, containing basic (cationic) groups in their molecular structure, and processes for their preparation are described. These novel hydrogels are stable, three-dimensional polymer networks, having good water permeability and mechanical properties. They are obtained by simultaneous polymerization and cross-linking in the presence of a polymerization catalyst, such as an organic peroxide, azobisisobutyronitrile or other free radical polymerization catalyst, of a mixture of (a) a heterocyclic monomer preferably an N-vinyl lactam, (b) a cationic monomer -usually an ester of acrylic or methacrylic acid with an amino alcohol, the terminal amino group of which may be quaternized, such as dimethylaminoethyl methacrylate or acrylate and the quaternized derivatives thereof, and (c) a cross-linking agent, such as a glycol or polyglycol diacrylate or dimethacrylate and also, preferably, (d) at least one acrylic monomer capable of polymerizing to a very high molecular weight, such as hydroxyethyl- or hydroxypropyl-acrylate or methacrylate, or a lower alkyl acrylate or methacrylate; if desired there may also be present in the monomer mixture (e) other polymerizable ethylenically unsaturated monomers, which are copolymerizable with components (a), (b), (c) and (d). The thus obtained cationic hydrogels are useful for combining by reaction or complexing, with water soluble or dispersible materials having an opposite charge; such as acidic or anionic agricultural chemicals (insecticides, herbicides, fungicides, plant growth regulators, etc.), germicides, pharmaceuticals, cosmetics, hormones, enzymes, flavors, fragrances, antiperspirants, metals and the like, both to recover such acidic or anionic materials from an aqueous medium and for purifying water containing them, and also for the preparation of a complex or other combination of the cationic hydrogel with such anionic materials which may be useful per se or from which the complexed or combined acidic or anionic material may be slowly or controllably released.
대표청구항▼
The cationic, polymeric hydrogel produced by simultaneus polymerization and cross-linking in the presence of a free radical polymerization catalyst in an amount of from about 0.05 to about 4 weight percent, based on the total weight of monomers, and at a temperature of from about 20°C. to about 125°
The cationic, polymeric hydrogel produced by simultaneus polymerization and cross-linking in the presence of a free radical polymerization catalyst in an amount of from about 0.05 to about 4 weight percent, based on the total weight of monomers, and at a temperature of from about 20°C. to about 125°C., of a mixture consisting essentially of the following monomers: a. about 20 to about 95 weight percent, based on the total weight of monomers, of a heterocyclic N-vinyl monomer selected from the group consisting of N-vinyl lactams, N-vinyl succinimide, N-vinyl diglycoylimide, N-vinyl glutarimide, N-vinyl-3-morpholinone, N-vinyl-5-methyl-3-morpholinone and N-vinyl imidazole; b. about 50 to about 0.05 weight percent, based on the total weight of monomers, of a cationic monoethylenically unsaturated quaternary ammonium monomer, capable of copolymerizing with (a) and having the formula: [Figure] wherein: R represents hydrogen, methyl or aryl; R1 represents hydrogen or alkyl of 1 to about 18 carbons; A and A1, each of which may be the same or different, each represents an alkylene group of from about 2 to about 8 carbons or an arylene group; R2, R3 and R4, each of which may be the same or different, each represents alkyl, aryl or alkaryl or the R2 and R3 on the same nitrogen atom, taken together represent a divalent aliphatic group of 4 to 5 atoms which jointly with the amino nitrogen forms a 5 or 6 membered heterocyclic amino group; X and Y, each of which may be the same or different, each represents an anion forming the anionic portion of a quaternary ammonium group; n represents an integer, including 0, of from 0 to about 10; and m represents an integer, including 0, of from 0 to about 5. c. about 0.2 to about 12 weight percent, based on the total weight of monomers, of a polymerizable cross-linking agent capable of copolymerizing with (a) and (b); and having the formula: [Figure] wherein R represents a member of the group consisting of hydrogen and alkyl of from 1 to about 4 carbon atoms; A represents alkylene of from 2 to about 10 carbons or a polyglycol ether group of the formula: [Figure] R′represents a member of the group consisting of hydrogen and alkyl of 1 to 2 carbon atoms; and n represents an integer of from 1 to about 20; and d. from 0 to about 50 weight percent, based on the total weight of monomers, of a monoethylenically unsaturated acrylic monomer capable of copolymerizing with (a), (b) and (c) and capable of polymerizing to a high molecular weight, in excess of 100,000 and selected from the group consisting of acrylamides, methacrylamides, acrylonitrile, methacrylonitrile, alkyl acrylates and methacrylates, hydroxyalkyl acrylates and methacrylates, and monohydroxy and monoalkoxy polyalkylene glycol acrylates and methacrylates; and provided that (a) ≥(d) and (a)+(d) =about 40 to about 95 weight percent.
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