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An alkali metal carbonate substantially free of alkali metal chloride is efficiently produced by electrolyzing an alkali metal chloride in an electrolytic cell having anolyte and catholyte compartments separated by a cation-exchange hydraulically impermeable membrane comprised of a thin film of a fl

An alkali metal carbonate substantially free of alkali metal chloride is efficiently produced by electrolyzing an alkali metal chloride in an electrolytic cell having anolyte and catholyte compartments separated by a cation-exchange hydraulically impermeable membrane comprised of a thin film of a fluorinated polymer having pendant carboxylic acid or alkali metal carboxylate groups and a cathode spaced apart from the membrane, injecting into the catholyte compartment of the cell carbon dioxide in a quantity sufficient to convert substantially all the alkali metal hydroxide forming therein to the alkali metal carbonate salt, and utilizing a magnitude of electrolyzing current that reduces alkali metal chloride in the catholyte solids to less than 400 ppm.

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In a method for producing an alkali metal carbonate wherein: A. an alkali metal chloride is electrolyzed in an electrolytic cell having an anode and cathode in anolyte and catholyte compartments separated by a permselective cation-exchange membrane that is impervious to hydraulic flow and is spaced

In a method for producing an alkali metal carbonate wherein: A. an alkali metal chloride is electrolyzed in an electrolytic cell having an anode and cathode in anolyte and catholyte compartments separated by a permselective cation-exchange membrane that is impervious to hydraulic flow and is spaced apart from the cathode; B. carbon dioxide is injected into the catholyte compartment to give catholyte solids wherein substantially all of the alkali metal hydroxide formed therein is converted to alkali metal carbonate; and C. catholyte containing the alkali metal carbonate is removed from the catholyte compartment; the improvement which comprises: D. utilizing a membrane which: 1. consists essentially of a film having a thickness not exceeding 8 mils of a copolymer having recurring structural units of the formula: [Figure] (I) and (II) －CXX′－CF2－ wherein R represents the group －OCF2－CFY－mO－CF2－(G)e－ in which Y is fluorine or trifluoromethyl, G is －CF2－or [Figure] m is 1, 2 or 3, e is 0 or 1, and a is an integer from 1 to 10; n is 0 or 1; A is H, Na, or K; X is fluorine, chlorine, or trifluoromethyl; X′is X or CF3－CF2－z wherein z is 0 or an integer from 1 to 5; the units of formula (I) being present in an amount to provide a copolymer having in the acid form an －CO2H equivalent weight of about 800 to 1400; and 2. is capable when immersed in 100°C. water of absorbing at least 15% by weight water; and E. utilizing an electrolyzing current density in excess of one ampere per square inch of membrane area of sufficient magnitude to reduce alkali metal chloride in the catholyte solids to less than 400 parts per million.