초록 ▼

Ammonia synthesis processes are disclosed which provide enhanced conversion of hydrogen values to ammonia. In the processes, a purge stream from an ammonia synthesis loop, which purge stream contains ammonia, is contacted at a superatmospheric pressure with the feed side of a separation membrane whi

Ammonia synthesis processes are disclosed which provide enhanced conversion of hydrogen values to ammonia. In the processes, a purge stream from an ammonia synthesis loop, which purge stream contains ammonia, is contacted at a superatmospheric pressure with the feed side of a separation membrane which exhibits selective permeation of each of hydrogen and ammonia as compared to the permeation of each of methane and argon. A total pressure differential across the membrane is maintained to provide a driving force for the permeation of hydrogen and ammonia through the membrane. A hydrogen-rich permeating gas which contains ammonia is obtained on the permeate exit side of the membrane. The permeating gas is combined with the gas in the ammonia synthesis loop and passed to the ammonia synthesis reaction zone for conversion to ammonia. Ammonia which permeates the membrane can be recovered by the means to remove product ammonia from the gas in the synthesis loop. A non-permeating gas is removed from the feed side of the separation membrane at substantially the same pressure at which the purge stream is contacted with the separation membrane.

대표청구항 ▼

A process for synthesizing ammonia from hydrogen and nitrogen comprising: a. introducing to and reacting in an ammonia synthesis reaction zone a nitrogen and hydrogen containing reactor feed gas at a superatmospheric synthesis pressure to produce ammonia said reactor feed gas comprising inert contam

A process for synthesizing ammonia from hydrogen and nitrogen comprising: a. introducing to and reacting in an ammonia synthesis reaction zone a nitrogen and hydrogen containing reactor feed gas at a superatmospheric synthesis pressure to produce ammonia said reactor feed gas comprising inert contaminants; b. withdrawing an ammonia-containing reaction effluent from said ammonia synthesis reaction zone and recycling said reaction effluent to said ammonia synthesis reaction zone in an ammonia synthesis loop; c. introducing a synthesis feed gas into said ammonia synthesis loop, said synthesis feed gas being at substantially said superatmospheric synthesis pressure and comprising nitrogen, hydrogen, and at least one of methane and argon; d. removing ammonia from the reaction effluent in said ammonia synthesis loop; e. removing a purge stream containing ammonia from said ammonia synthesis loop in an amount sufficient to maintain the concentration of inert contaminants in the reactor feed gas less than about 25 volume percent and being at substantially said superatmospheric synthesis pressure; f. contacting said purge stream containing at least about 0.5% volume percent ammonia with a separation membrane, said purge stream when contacted with the separation membrane being at a superatmospheric pressure, said separation membrane having a feed side and a permeate exit side at a lower total pressure and exhibiting selective permeation of each of hydrogen and ammonia as compared to the permeation of each of methane and argon; g. permeating through and recovering from the permeate exit side of said separation membrane a permeating gas comprising at least about 20 percent of the hydrogen and at least about 20 percent of the ammonia in the purge stream containing the separation membrane; h. removing from the feed side of said separation membrane a non-permeating gas containing a lesser amount by weight of ammonia than the amount of ammonia in the purge stream contacting the separation membrane; and i. recycling said permeating gas to said ammonia synthesis reaction zone.