IPC분류정보
국가/구분 |
United States(US) Patent
등록
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국제특허분류(IPC7판) |
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출원번호 |
US-0039561
(1979-05-16)
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발명자
/ 주소 |
- Lorenz Donald H. (Basking Ridge NJ) Gruber Bruce A. (Bloomingdale NJ)
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출원인 / 주소 |
- GAF Corporation (New York NY 02)
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인용정보 |
피인용 횟수 :
18 인용 특허 :
1 |
초록
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This invention relates to a method of making in high yield light absorber compounds which are (2-cyano-3,3-diphenylacryloxy) alkylene acrylic acid esters having the formula: [Figure] where (Ar)1 and (Ar)2 are aromatic carbocyclic nuclei of the benzene and naphthalene series and are independently sel
This invention relates to a method of making in high yield light absorber compounds which are (2-cyano-3,3-diphenylacryloxy) alkylene acrylic acid esters having the formula: [Figure] where (Ar)1 and (Ar)2 are aromatic carbocyclic nuclei of the benzene and naphthalene series and are independently selected from phenyl or phenyl substituted with alkyl, halo, alkoxy, carboxy, carbalkoxy, cyano, acetyl, benzoyl, phenyl, alkyl phenyl, phenoxy phenyl, alkyl substituted phenoxy, or alkoxy phenyl substituted phenyl and naphthyl; X is alkylene, C2-C17, unsubstituted or substituted with halo, cyano, alkyl C1-C6 alkoxy C1-C6, alkoxyalkyl C1-C6, or alkoxyalkyleneoxy C1-C6; and Y is copolymerizable radical selected from acryloyl C3-C12 alkylacryloyl C3-C12, acryloxyalkyl C3-C12, acryloxyhydroxyalkyl and alkylacryloxyhydroxyalkyl C3-C12. The method comprises: (a) esterifying a hydroxyalkylene cyanoacetate with an acryloylhalide or acrylic acid to form a (2-acryloxyalkyl) 2-cyanoacetate intermediate, and, (b) condensing the intermediate directly with a benzophenone to provide the desired product.
대표청구항
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A method of making copolymerizable ultraviolet light absorber (2-cyano-3,3-diphenylacryloxy) alkylene acrylic acid esters in high yield having the formula: [Figure] where (Ar)1 and (Ar)2 are aromatic carbocyclic nuclei of the benzene and naphthalene series and are independently selected from phenyl
A method of making copolymerizable ultraviolet light absorber (2-cyano-3,3-diphenylacryloxy) alkylene acrylic acid esters in high yield having the formula: [Figure] where (Ar)1 and (Ar)2 are aromatic carbocyclic nuclei of the benzene and naphthalene series and are independently selected from phenyl or phenyl substituted with alkyl, halo, alkoxy, carboxy, carbalkoxy, cyano, acetyl, benzoyl, phenyl, alkyl phenyl, phenoxy phenyl, alkyl substituted phenoxy, or alkoxy phenyl substituted phenyl, and naphthyl; X is alkylene, C2-C17, unsubstituted or substituted with halo, cyano, alkyl C1-C6, alkoxy C1-C6, alkoxyalkyl C1-C6, or alkoxyalkyleneoxy C1-C6; and, Y is copolymerizable radical selected from acryloyl C3-C12, alkylacryloyl C3-C12, acryloxyalkyl C3-C12, acryloxyhydroxyalkyl and alkylacryloxyhydroxyalkyl C3-C12, which comprises the steps of: (a) esterifying a hydroxyalkylene cyanoacetate having the formula: [Figure] where X is as defined above, with an acryloyl halide or acrylic acid having the formula YZ, where Y is as defined above and Z is a halide or hydroxyl group to form a (2-acryloxyalkyl) 2-cyanoacetate intermediate, and, (b) condensing the intermediate with a benzophenone having the formula: [Figure] where (Ar)1 and (Ar)2 are as defined above, to form the desired compound.
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