초록 ▼

Partially devitrified porcelain compositions are provided which are comprised of a mixture, based on its oxide content, of barium oxide (BaO), magnesium oxide (McO) or a mixture of magnesium oxide with certain other oxides, boron trioxide (B2O3) and silicon dioxide (SiO2). In accordance with this in

Partially devitrified porcelain compositions are provided which are comprised of a mixture, based on its oxide content, of barium oxide (BaO), magnesium oxide (McO) or a mixture of magnesium oxide with certain other oxides, boron trioxide (B2O3) and silicon dioxide (SiO2). In accordance with this invention the porcelain compositions are applied to the metal core and fired to provide a partially devitrified porcelain coating on the metal core. The coating has a very low viscosity at its initial fusion point and then almost instantaneous high viscosity due to partial devitrification. The fired coating has a deformation temperature of at least 700°C. and a high coefficient of thermal expansion of at least about 110×10-7/°C.

대표청구항 ▼

A porcelain coated circuit board having a metal core and having applied to the surface of the metal core a coating of a devitrified porcelain which is free to substantially free of alkaline metal oxide, said porcelain consisting essentially, on an oxide basis, of: (a) from about 6 to about 25 mole p

A porcelain coated circuit board having a metal core and having applied to the surface of the metal core a coating of a devitrified porcelain which is free to substantially free of alkaline metal oxide, said porcelain consisting essentially, on an oxide basis, of: (a) from about 6 to about 25 mole percent of barium oxide; (b) from about 30 to about 60 mole percent of MO wherein MO is a member selected from the group consisting of magnesium oxide and mixtures of magnesium oxide with at least one member selected from the group consisting of zinc oxide and calcium oxide; (c) from about 13 to about 35 mole percent of boron trioxide; and (d) from about 10 to about 25 mole percent of silicon dioxide; said coating having a deformation temperature of at least 700°C. and said coating of porcelain having defined thereon an electrical circuit.