초록 ▼

A method of synthesizing ammonia by reacting a synthesis gas comprising nitrogen and hydrogen at superatmospheric pressure in a synthesis reaction zone with recycling of unreacting gas to the reacting zone is disclosed in which a purge gas stream is withdrawn at superatmospheric pressure and subject

A method of synthesizing ammonia by reacting a synthesis gas comprising nitrogen and hydrogen at superatmospheric pressure in a synthesis reaction zone with recycling of unreacting gas to the reacting zone is disclosed in which a purge gas stream is withdrawn at superatmospheric pressure and subjected to the steps of: (a) work expansion, (b) separation of methane and argon to form a gaseous product stream comprising nitrogen and hydrogen, (c) recompression of at least a portion of the gaseous product stream from step (b) using work generated in step (a), and (d) recycling of at least a portion of the recompressed product from step (c) to the reaction zone. Apparatus for effecting said process is also claimed.

대표청구항 ▼

A method of synthesising ammonia by reacting a synthesis gas comprising nitrogen and hydrogen at superatmospheric pressure in a synthesis reaction zone with recycling of unreacting gas to said synthesis reaction zone, wherein fresh synthesis gas is introduced as a feed stream to a synthesis loop com

A method of synthesising ammonia by reacting a synthesis gas comprising nitrogen and hydrogen at superatmospheric pressure in a synthesis reaction zone with recycling of unreacting gas to said synthesis reaction zone, wherein fresh synthesis gas is introduced as a feed stream to a synthesis loop comprising said synthesis reaction zone and a recycle path leading from an exit of the synthesis reaction zone to an inlet thereto, and wherein a purge gas stream comprising unreacted hydrogen and nitrogen and impurities including methane and argon is withdrawn at superatmospheric pressure from said synthesis loop and subjected to the following steps (a) to (d) carried out in the sequence stated: (a) first work expanding said withdrawn purge gas stream to a second superatmospheric pressure lower than the pressure in said synthesis loop, (b) separating methane and argon from the work expanded purge gas stream to form a gaseous product stream comprising nitrogen and hydrogen, (c) recompressing at least a portion of said gaseous product stream from step (b) using work generated in step (a) and (d) recycling at least a portion of the recompressed product from step (c) to said synthesis reaction zone, whereby to recycle hydrogen and nitrogen values thereto. Apparatus for synthesising ammonia from a synthesis gas comprising nitrogen and hydrogen, said apparatus comprising a synthesis loop including a synthesis reaction zone and recycle conduit means leading from an exit of the synthesis reaction zone to an inlet thereto, first conduit means for introducing fresh synthesis gas to said synthesis loop, outlet means leading from said synthesis loop for withdrawal of a purge gas stream and means for treatment of said purge gas stream comprising expansion means in which purge gas at high pressure directly from said synthesis loop may be expanded with the performance of work and including an outlet for delivery of said purge gas stream after expansion, separation means for separating methane and argon contained in the expanded purge gas stream to form a stream enriched in hydrogen and nitrogen, second conduit means extending from the outlet of said expansion means to said separation means for transferring the expanded purge gas stream to said separation means, third conduit means extending from the outlet of said separation means to said compression means and fourth conduit means extending from an outlet of said compression means and connected to enable hydrogen and nitrogen values of said enriched stream to be recycled to the synthesis reaction zone, said compression means and said expansion means being coupled so that work generated in said expansion means is utilised in said compression means to compress the enriched stream.