초록 ▼

A process is disclosed for gasifying solid carbonaceous material at elevated temperature and pressure to produce a gas consisting of carbon monoxide and hydrogen, which comprises forming a slurry at atmospheric pressure of the carbonaceous material with a liquid having a specific gravity of from 1.1

A process is disclosed for gasifying solid carbonaceous material at elevated temperature and pressure to produce a gas consisting of carbon monoxide and hydrogen, which comprises forming a slurry at atmospheric pressure of the carbonaceous material with a liquid having a specific gravity of from 1.1 to 1.9, a boiling temperature of at least 70°F., a latent heat of vaporization less than about 200 BTU per pound, a critical temperature which is less than the incipient coking temperature of the carbonaceous material, a stability at temperatures up to 600°F., an essentially inert chemical reaction with the carbonaceous material at temperatures less than about 600°F., an immiscibility with water or solubility in water at no more than 5%, and a dissolving ability for hydrogen sulfide at temperatures of from -40 to 250°F., and raising the formed slurry to a pressure of at least the gasification pressure and vaporizing said liquid and gasifying said carbonaceous material, either in the same or in separate steps. Examples of suitable slurrying liquids are: carbon tetrachloride, carbon disulfide, trichloroethylene, bromoethane, chlorobenzene, methane dichloride, chloroform, or mixtures thereof.

대표청구항 ▼

In a process for gasifying solid carbonaceous material at elevated temperature and pressure to produce a gas containing carbon monoxide and hydrogen, the improvement which comprises forming a slurry at atmospheric pressure of the carbonaceous material with carbon disulfide and raising said formed sl

In a process for gasifying solid carbonaceous material at elevated temperature and pressure to produce a gas containing carbon monoxide and hydrogen, the improvement which comprises forming a slurry at atmospheric pressure of the carbonaceous material with carbon disulfide and raising said formed slurry to a pressure of at least the gasification pressure and simultaneously vaporizing the carbon disulfide and gasifying said carbonaceous material. A process for the superatmospheric gasification of a solid carbonaceous material which comprises: (a) forming a slurry of said carbonaceous material at atmospheric pressure with a recycle fluid consisting of carbon disulfide, carbon tetrachloride, trichloroethylene, bromoethane, chlorobenzene, methane dichloride or chloroform, or mixture of these compounds; (b) pumping said slurry to a pressure of at least the gasification pressure; (c) gasifying the carbonaceous material and simultaneously evaporating said recycle slurrying fluid within a gasifier; (d) scrubbing the resultant product gas with a chilled solution of scrubbing fluid which is essentially the same as said recycle fluid, thereby condensing said evaporated recycle fluid while simultaneously condensing water vapor from said product gas, absorbing sulfur compounds and other soluble compounds from said product gas, and physically removing particulates from said product gas; (e) treating said scrubbing fluid to remove accumulated particulates and sulfur compounds; (f) separating said scrubbing fluid from said condensed water; (g) forming a recycle fluid from a portion of the scrubbing fluid; and (h) recycling the recycle fluid to step (a), whereby substantially no reaction of recycle fluid occurs when gasifying the carbonaceous material.