초록 ▼

Oxygen and water impurities are cleaned from hydrogen, which is to be stored in tanks containing a hydride-forming metallic alloy, using a novel, self-cleaning filter system. The impurity-containing hydrogen gas is first passed through a catalyst bed comprising a catalyst which is adapted to convert

Oxygen and water impurities are cleaned from hydrogen, which is to be stored in tanks containing a hydride-forming metallic alloy, using a novel, self-cleaning filter system. The impurity-containing hydrogen gas is first passed through a catalyst bed comprising a catalyst which is adapted to convert oxygen in the presence of hydrogen to water. The gas then passes through an adsorbent capable of adsorbing water from the gas stream, thereby substantially removing water impurities from the hydrogen gas. The purified hydrogen gas is charged into a storage tank containing a hydride-forming metallic alloy which absorbs the hydrogen by reacting therewith to form hydrogen-loaded metallic hydride. When the storage tank is to be discharged, the hydrogen-loaded metallic hydride in the tank is treated to release hydrogen gas therefrom. The released gas is passed back through the adsorbent, thereby cleaning the adsorbent of water impurities deposited therein when the tank was being charged with hydrogen. The hydrogen gas containing water impurities is then forwarded to a hydrogen utilization unit for further use of the hydrogen.

대표청구항 ▼

A hydrogen storage system having a self-cleaning filter means for removing oxygen and water from hydrogen which is being charged to storage tanks containing a hydride-forming, metallic alloy, said system comprising: (a) a composite filter means comprising a catalyst section containing a catalyst ada

A hydrogen storage system having a self-cleaning filter means for removing oxygen and water from hydrogen which is being charged to storage tanks containing a hydride-forming, metallic alloy, said system comprising: (a) a composite filter means comprising a catalyst section containing a catalyst adapted to convert oxygen in the presence of hydrogen to water and an adsorption section containing an adsorbent adapted to adsorb water from hydrogen gas, said catalyst section and adsorption section being in flow communication with each other, (b) a storage tank containing a hydride-forming metallic reactant which absorbs hydrogen by reacting therewith to form hydrogen-loaded metallic hydride, (c) flow communicating means connecting the adsorption section of the filter means with the storage tank for flow of hydrogen gas between the filter means and the storage tank, and (d) manifold means connected in flow communication with the catalyst section of the filter means, said manifold means adapted to deliver hydrogen gas to the catalyst section of the filter means when the storage tank is being filled and to accept hydrogen gas from the catalyst section of the filter means during discharge of the tank, whereby oxygen and water impurities are removed from the hydrogen gas being charged to the storage tank, oxygen being converted to water as the hydrogen passes through the catalyst section of the filter means and water being adsorbed by the adsorbent as the hydrogen passes through the adsorption section of the filter means, and whereby the water is cleaned from the filter as hydrogen is discharged from the storage tank, the catalyst and the adsorbent in step (a) being contained in an enclosed chamber having top, bottom and side walls, with the adsorbent and the catalyst occupying the lower and the upper portions of the chamber, respectively, and the flow communicating means consisting of: (1) a dip-tube extending through the top wall of the chamber, through the catalyst section, and at least through the major portion of the adsorption section so that the open, lower end of the dip-tube is positioned within the chamber and the upper end of the dip-tube is open to the outside of the chamber, and (2) coupling means connecting the upper end of said dip-tube to said storage tank for flow of hydrogen gas between the dip-tube and the storage tank, and manifold means being connected to the top of said chamber to be in flow communication with the top of the catalyst section of the filter means.