초록 ▼

Method of treating biomass material wherein it is subjected to two stage hydrolysis in which in first stage, the more easily hydrolyzed polysaccharides, such as hemicelluloses, are depolymerized and in second stage the more difficultly depolymerizable material, e.g., cellulose, is depolymerized. The

Method of treating biomass material wherein it is subjected to two stage hydrolysis in which in first stage, the more easily hydrolyzed polysaccharides, such as hemicelluloses, are depolymerized and in second stage the more difficultly depolymerizable material, e.g., cellulose, is depolymerized. The biomass material is preferably subjected to a sensitization step between the first and second hydrolyzing stages by contact with molecular oxygen. The resulting hydrolysate and remaining solids are variously treated, including recycling of hydrolysate to first stage hydrolysis; countercurrent or co-current flow of recycled hydrolysate is carried out according to the nature of solids; acid is added at appropriate points, preferably nitric acid to provide nutrients for fermentation or to inhibit corrrosion of equipment; bases such as calcium carbonate or hydroxide are added to neutralize hydolysate for fermentation; wet oxidation and methanation are carried out to solubilize refractory solids (wet oxidation) and to produce methane (methanation); and ferric and/or aluminum ions are added to flocculate solids in the hydrolysate and such ions are recovered and resolubilized by wet oxidation and are routed to the hydrolysis stages to function as catalysts.

대표청구항 ▼

1. In the hydrolysis of biomass material in stages including a first stage hydrolysis in a first hydrolysis zone having an inlet and an outlet and under relatively mild hydrolytic conditions to hydrolyze primarily the more readily hydrolyzable polysaccharides and resulting in an aqueous solution of

1. In the hydrolysis of biomass material in stages including a first stage hydrolysis in a first hydrolysis zone having an inlet and an outlet and under relatively mild hydrolytic conditions to hydrolyze primarily the more readily hydrolyzable polysaccharides and resulting in an aqueous solution of lower saccharides commingled with biomass solids, the latter comprising more difficulty polymerizable polysaccharide material, and then subjecting such biomass solids to a second, more severe hydrolytic treatment to depolymerize cellulose and such other difficultly depolymerizable polysaccharides as may be present, the improvement which comprises subjecting the product of second stage hydrolysis to phase separation resulting in separate streams of liquid separated from solids including first, second and third streams, the first stream being most concentrated, the second stream being less concentrated and the third stream being the least concentrated in soluble sugars. 2. The method of claim 1 wherein the first and second streams are introduced into the first hydrolysis zone, the first stream being introduced more remotely from the outlet and closer to the inlet of the first hydrolysis zone than the second stream, and causing the combined streams to flow through the first hydrolysis zone countercurrently to the biomass material. 3. The method of claim 1 wherein the first stream is withdrawn as product and the second stream is introduced into the first hydrolysis zone at or near its inlet and is caused to flow co-currently through the first hydrolysis zone with the biomass material. 4. The method of claim 1 or 2 wherein the third stream is used to wash solids leaving the first hydrolysis zone. 5. The method of claim 1 wherein effluent from the first hydrolysis zone is subjected to a dewatering step to express liquid which is withdrawn as product and to produce partially dewatered solids, and such third stream is divided into two parts one of which is used to add water to the partially dewatered solids, the other part being used to wash solids undergoing partial dewatering. 6. In the hydrolytic treatment of biomass material to produce a liquid hydrolysate containing one or more monosaccharides and wherein a first hydrolysis zone and a second hydrolysis zone are provided each having an inlet and an outlet spaced from one another and wherein the biomass material is introduced to the first hydrolysis zone through its inlet, is passed therethrough under hydrolytic conditions adapted to depolymerize principally only the more easily depolymerized polysaccharides, and wherein the resultant solid biomass material together with liquid aqueous phase is withdrawn through the outlet of the first zone and is caused to pass through the second hydrolysis zone from its inlet to its outlet and is subjected during such transit to more severe hydrolytic conditions to depolymerize cellulose and to produce an aqueous solution of glucose, and a mixture of the remaining solids together with a solution of one or more monosaccharides is withdrawn through the outlet of the second hydrolysis zone, the improvement which comprises: (a) withdrawing from the outlet of the second hydrolysis zone a mixture of biomass solids and a solution of one or more monosaccharides and subjecting such mixture to a plurality of successive separation steps resulting in a plurality of streams of solutions substantially free of solids, each successive stream being less concentrated than the preceeding stream with respect to monosaccharides. 7. The improvement of claim 6 wherein at least one of the more concentrated streams is recycled to the first hydrolysis zone and one of the less concentrated streams is used to wash biomass solids effluent from the outlet of the first hydrolysis zone and also to dilute the washed solids.