초록 ▼

Pigmented thermosetting organic solvent solution coating compositions are disclosed which cure to provide improved weather resistance. These coating compositions contain three resin components, as follows: (1) an essentially nonfunctional organic solvent-soluble silicone resin reaction product of a

Pigmented thermosetting organic solvent solution coating compositions are disclosed which cure to provide improved weather resistance. These coating compositions contain three resin components, as follows: (1) an essentially nonfunctional organic solvent-soluble silicone resin reaction product of a low molecular weight hydroxy functional polyether with an hydroxy or alkoxy-functional organic polysiloxane, said polyether having an average molecular weight in the range of 300 to 4000 and an hydroxy functionality of at least about 3, said polysiloxane being present in an amount of from 8% to 20% of the weight of the three resin components, and said polyether and said polysiloxane being combined in approximately stoichiometric proportions; (2) a reactive organic solvent-soluble essentially linear high molecular weight hydroxy functional polyester constituting the balance of the three resin components; and (3) from 3% to 15% of the three resin components of a heterocyclic aminoplast resin for curing the reactive polyester. Components 1 and 2 are compatible in the solution and at least partially incompatible in a film as the solvent evaporates, so that component 1 can concentrate at the surface to enhance the weather resistance.

대표청구항 ▼

An organic solvent solution coating composition adapted to deposit a thermosetting weather-resistant coating comprising three essential resin components, as follows: (1) an essentially nonfunctional organic solvent-soluble silicone resin reaction product of a low molecular weight hydroxy functional

An organic solvent solution coating composition adapted to deposit a thermosetting weather-resistant coating comprising three essential resin components, as follows: (1) an essentially nonfunctional organic solvent-soluble silicone resin reaction product of a low molecular weight hydroxy functional polyether with an hydroxy or alkoxy-functional organic polysiloxane, said polyether having an average molecular weight in the range of 300 to 4000 and an hydroxy functionality of at least about 3, said polysiloxane being present in an amount of from 8% to 20% of the weight of the three resin components, and said polyether and said polysiloxane being combined in approximately stoichiometric proportions; (2) a reactive organic solvent-soluble essentially linear high molecular weight hydroxy functional polyester, said hydroxy functionality being present in an amount to provide a thermoset film by reaction with aminoplast resin, said reactive polyester constituting the balance of the three resin components; and (3) from 3% to 15%, based on the weight of the three resin components, of a heterocyclic aminoplast resin for curing said reactive polyester, said components 1 and 2 being compatible in the solution and at least partially incompatible in a film as the solvent evaporates, so that components 2 and 3 can cure in a deposited film and adhere the coating to a metal substrate, and component 1 can concentrate at the surface to enhance the weather resistance which is obtained when a deposited coating is baked.