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A continuous, cyclic, vapor-phase adsorption process for the separation of normal paraffins from a hydrocarbon feed mixture, providing improved efficiency of separation and continuity in product flows. For purposes of this process, a continuous flow of the feed mixture and a continuous flow of an el

A continuous, cyclic, vapor-phase adsorption process for the separation of normal paraffins from a hydrocarbon feed mixture, providing improved efficiency of separation and continuity in product flows. For purposes of this process, a continuous flow of the feed mixture and a continuous flow of an eluent are passed in repetitions of a particular sequence of nine process steps to at least three molecular sieve adsorbent beds.

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A improved process for using at least three molecular sieve adsorbent beds and a continuous flow of a vapor-phase eluent to effect the resolution of a continuous flow of a vapor-phase hydrocarbon feed mixture containing normal paraffins and non-normal paraffin hydrocarbons into an adsorbate product

A improved process for using at least three molecular sieve adsorbent beds and a continuous flow of a vapor-phase eluent to effect the resolution of a continuous flow of a vapor-phase hydrocarbon feed mixture containing normal paraffins and non-normal paraffin hydrocarbons into an adsorbate product fraction comprising normal paraffins and a raffinate product fraction comprising non-normal paraffin hydrocarbons, which process comprises repeated sequential performance of the following steps: step one, in which the feed mixture is passed through a first adsorbent bed, effluent is withdrawn from the first bed and passed through a second adsorbent bed, the eluent flow is passed through a third adsorbent bed, adsorbate product is withdrawn as an effluent from the third bed, and raffinate product is withdrawn as an effluent from the second bed; step two, in which the feed mixture is passed through the second bed, the eluent flow is passed through the first bed, effluent from the first bed is withdrawn and is passed through the third bed, and raffinate product is withdrawn as effluent from the second bed and from the third bed; step three, in which the feed mixture is passed through the second bed, the eluent flow is passed through the first bed, adsorbate product is withdrawn as effluent from the first bed, effluent from the second bed is withdrawn and is divided into a major fraction containing between about 50 and 95 volume percent and a minor fraction containing between about 5 and 50 volume percent, said minor fraction is passed through the third bed, and raffinate product is withdrawn as said major fraction of effluent from the second bed and as effluent from the third bed; step four, in which the feed mixture is passed through the second bed, effluent is withdrawn from the second bed and passed through the third bed, the eluent flow is passed through the first bed, adsorbate product is withdrawn as effluent from the first bed, and raffinate product is withdrawn as effluent from the third bed, step five, in which the feed mixture is passed through the third bed, the eluent flow is passed through the second bed, effluent from the second bed is withdrawn and is passed through the first bed, and raffinate product is withdrawn as effluent from the first bed and from the third bed; step six, in which the feed mixture is passed through the third bed, the eluent flow is passed through the second bed, adsorbate product is withdrawn as effluent from the second bed, effluent from the third bed is withdrawn and is divided into a major fraction containing between about 50 and 95 volume percent and a minor fraction containing between about 5 and 50 volume percent, said minor fraction is passed through the first bed, and raffinate product is withdrawn as said major fraction of effluent from the third bed and as effluent from the first bed; step seven, in which the feed mixture is passed through the third bed, effluent is withdrawn from the third bed and passed through the first bed, the eluent flow is passed through the second bed, adsorbate product is withdrawn as effluent from the second bed, and raffinate product is withdrawn as effluent from the first bed; and step eight, in which the feed mixture is passed through the first bed, the eluent flow is passed through the third bed, effluent from the third bed is withdrawn and is passed through the second bed, and raffinate product is withdrawn as effluent from the first bed and from the second bed; and step nine, in which the feed mixture is passed through the first bed, the eluent flow is passed through the third bed, adsorbate product is withdrawn as effluent from the third bed, effluent from the first bed is withdrawn and is divided into a major fraction containing between about 50 and 95 volume percent and a minor fraction containing between about 5 and 50 volume percent, said minor fraction is passed through the second bed, and raffinate product is withdrawn as said major fraction of effluent from the first bed and as effluent from the second bed.