IPC분류정보
국가/구분 |
United States(US) Patent
등록
|
국제특허분류(IPC7판) |
|
출원번호 |
US-0640858
(1984-08-14)
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우선권정보 |
IL-63630 (1981-08-21) |
발명자
/ 주소 |
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출원인 / 주소 |
- Technion Research and Development Foundation, Inc.
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대리인 / 주소 |
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인용정보 |
피인용 횟수 :
15 인용 특허 :
0 |
초록
▼
The present invention relates to an improved process for the manufacture of ammonia from a gaseous mixture containing hydrogen and nitrogen. According to the invention, the process comprises the steps of: (a) feeding a gaseous mixture of hydrogen and nitrogen, in the proportions of about 3 moles hyd
The present invention relates to an improved process for the manufacture of ammonia from a gaseous mixture containing hydrogen and nitrogen. According to the invention, the process comprises the steps of: (a) feeding a gaseous mixture of hydrogen and nitrogen, in the proportions of about 3 moles hydrogen to 1 mole nitrogen, together with inert gases, into a converter containing catalyst(s) for ammonia synthesis; (b) conveying the reaction mixture from said converter through a water-free adsorbent to effect adsorption of the formed ammonia together with some inert gases, whereby the adsorbed gases are separated from the unreacted mixture of gases, the latter being recycled to the converter; (c) effecting desorption of ammonia from the water-free ammonia-loaded adsorbent by direct contact of said adsorbent with a concentrated hot stream of ammonia-containing gases, and (d) condensing the ammonia eliberated from the adsorbent to liquid ammonia. The process has several advantages such as: reduced investments in equipment, substantial savings in mechanical energy, high yields of ammonia conversion per pass and less energy requirements per unit of ammonia produced.
대표청구항
▼
1. A process for the manufacture of ammonia, comprising the steps of (a) feeding a gaseous mixture of hydrogen and nitrogen, or generators thereof in the proportions of about 3 moles hydrogen to 1 mole nitrogen, together with inert gases, into a converter containing catalyst(s) for ammonia synthe
1. A process for the manufacture of ammonia, comprising the steps of (a) feeding a gaseous mixture of hydrogen and nitrogen, or generators thereof in the proportions of about 3 moles hydrogen to 1 mole nitrogen, together with inert gases, into a converter containing catalyst(s) for ammonia synthesis and thereby producing ammonia; (b) conveying the reaction mixture from said converter through an adsorbent to effect adsorption of the formed ammonia together with some inert gases, whereby the adsorbed gases are separated from the unreacted mixture of gases, the latter being recycled to the converter; (c) effecting desorption of ammonia from the ammonia-loaded adsorbent by direct contact of said adsorbent with a concentrated hot stream of ammonia-containing gases comprising the hot effluent from the converter; (d) condensing the ammonia eliberated from the adsorbent to liquid ammonia; and wherein the adsorption and desorption steps are carried out in phased order, providing continuous streams of controlled compositions. 2. A process according to claim 1, wherein two or more adsorbent beds are utilized to carry out, in parallel, said adsorption and desorption steps in said phased order, providing said continuous streams of controlled compositions. 3. A process according to claim 1, wherein heat is transferred from the hot regenerant stream to the adsorbent bed to be regenerated and subsequently heat is transferred from the adsorbent bed to the unreacted mixture of gases recycled into the converter. 4. A process according to claim 1, wherein the adsorbent bed separates simultaneously the ammonia and methane from the gas recycled to the converter. 5. A process according to claim 4, wherein the gases going out from the adsorbent bed and entering into the converter, comprises substantially pure synthesis gas including argon. 6. A process according to claim 1, carried out in an existing ammonia plant wherein solid adsorption beds are incorporated therein. 7. A process according to claim 1 wherein said desorption is carried out at substantially the same pressure as said adsorption. 8. A process for the manufacture of ammonia, comprising the steps of (a) feeding a gaseous mixture of hydrogen and nitrogen, or generators thereof in the proportions of about 3 moles hydrogen to 1 mole nitrogen, together with inert gases, into a converter containing catalyst(s) for ammonia synthesis and thereby producing ammonia; (b) conveying the reaction mixture from said converter through an adsorbent to effect adsorption of the formed ammonia together with some inert gases, whereby the adsorbed gases are separated from the unreacted mixture of gases, the latter being recycled to the converter; (c) effecting desorption of ammonia from the ammonia-loaded adsorbent by direct contact of said adsorbent with a concentrated hot stream of ammonia-containing gases comprising hot compressed ammonia refrigerant which is at least as concentrated with ammonia as the hot effluent from the converter; (d) condensing the ammonia eliberated from the adsorbent to liquid ammonia; and wherein the adsorption and desorption steps are carried out in phased order, providing continuous streams of controlled compositions. 9. A process according to claim 8, wherein a liquid ammonia barrier is used to separate the circulated reactant mixture of gases from the ammonia refrigerant gas, thus substantially eliminating losses of unreacted gases into the refrigeration cycle. 10. A process according to claim 8, wherein two or more adsorbent beds are utilized to carry out, in parallel, said adsorption and desorption steps in said phased order, providing said continuous streams of controlled compositions. 11. A process according to claim 8, wherein heat is transferred from the hot regenerant stream to the adsorbent bed to be regenerated and subsequently heat is transferred from the adsorbent bed to the unreacted mixture of gases recycled into the converter. 12. A process according to claim 8, wherein the adsorbent bed separates simultaneously the ammonia and methane from the gas recycled to the converter. 13. A process according to claim 12, wherein the gases going out from the adsorbent bed and entering into the converter, comprises substantially pure synthesis gas including argon. 14. A process according to claim 8, carried out in an existing ammonia plant wherein solid adsorption beds are incorporated therein. 15. A process according to claim 8 wherein said desorption is carried out at substantially the same pressure as said adsorption.
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