IPC분류정보
국가/구분 |
United States(US) Patent
등록
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국제특허분류(IPC7판) |
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출원번호 |
US-0653417
(1984-09-24)
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발명자
/ 주소 |
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출원인 / 주소 |
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대리인 / 주소 |
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인용정보 |
피인용 횟수 :
9 인용 특허 :
1 |
초록
A resinous hardener system comprising the reaction product of diethyl toluene diamine and an epoxide having a functionality of at least two, the hardener being capable of incorporation into a variety of epoxy and urethane resins.
대표청구항
▼
1. A hardener for epoxy resins comprising the adduct obtained from the reaction of diethyl toluene diamine and a polyepoxide having a functionality of at least two, said diamine being present in excess relative to said polyepoxide. 2. The hardener of claim 1, wherein said polyepoxide is selected fro
1. A hardener for epoxy resins comprising the adduct obtained from the reaction of diethyl toluene diamine and a polyepoxide having a functionality of at least two, said diamine being present in excess relative to said polyepoxide. 2. The hardener of claim 1, wherein said polyepoxide is selected from the group consisting of diglycidyl ether of bisphenol A, epoxy phenol novolacs, 1,4-butanediol diglycidyl ether, epoxy cresol novolacs, triglycidyl para-amino phenol, triglycidyl tris(p-hydroxyphenyl)methane, tetraglycidyl-1,1,2,2 tetrakis (p-hydroxyphenyl)ethane, vinyl cyclohexene dioxide, N,N,N 1,N 1 -tetraglycidyl-4,4 1 -methylene bis benzeneamine, N,N,N 1,N 1 -tetraglycidyl meta-xylene diamine, diglycidyl aniline, resorcinol diglycidyl ether, catechol diglycidyl ether, hydroquinone diglycidyl ether, diglycidyl orthotoluidine, diglycidyl isophthalate, bisphenol F and S epoxy resins, and N,N,N 1,N 1 -tetraglycidyl 1,3 bis-aminomethylcyclohexane. 3. The hardener of claim 1, wherein said polyepoxide corresponds to the formula ##STR## wherein R is hydrogen or methyl, and n is 0.2-3.4. 4. The hardener of claim 1, wherein said polyepoxide corresponds to the formula ##STR## wherein m is 0-50 and X is --CH 2 --, ##STR## 5. The hardener of claim 1, wherein said polyepoxide is 1,4-butanediol diglycidyl ether. 6. The hardener of claim 1, wherein from about 2 to 10 moles of diamine are present per mole of polyepoxide. 7. A curable mixture comprising (a) a polyepoxide compound and (b) a hardener according to claim 1. 8. The curable mixture of claim 7, wherein said polyepoxide compound is selected from the group consisting of epoxide resins based on polyhydric phenols, epoxidation products of cresol novolacs, epoxidation products of phenol novolacs, hydantoin epoxide resins, polyglycidyl esters, glycidylated aromatic amines, glycidylated aminophenols and cycloaliphatic epoxy resins. 9. The curable mixture of claim 7, wherein said hardener and said polyepoxide compound are present in stoichiometric amounts ±50%. 10. The curable mixture of claim 7 which also contains a maximum of 75%, by weight, of an aliphatic, cycloaliphatic or aromatic primary or secondary amine. 11. The curable mixture of claim 10, wherein said amine is selected from the group consisting of monoethanolamine, N-aminoethyl ethanolamine, ethylenediamine, hexamethylenediamine, trimethylhexamethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, N,N-dimethylpropylenediamine-1,3, N,N-diethylpropylenediamine-1,3, bis(4-amino-3-methylcyclohexly)methane, bis(p-aminocyclohexyl)methane, 2,2-bis(4-aminocyclohexyl)propane, 3,5,5-trimethyl-s-(aminomethyl)-cyclohexylamine, N-aminoethyl-piperazine, m-phenylene-diamine, p-phenylenediamine, bis(p-aminophenyl)methane, bis(p-aminophenyl)-sulfone, m-xylylenediamine, 1,2-diaminocyclohexane, 1,4-diaminocyclohexane, toluene diamine, 1,3-bis(aminomethyl)cyclohexane, 1-4-bis(aminomethyl)cyclohexane, isophorone diamine and 1-methyl-imidazole. 12. The curable mixture of claim 7, wherein in said hardener said polyepoxide corresponds to the formula ##STR## wherein R is hydrogen or methyl, and n is 0.2-3.4. 13. The curable mixture of claim 7, wherein in said hardener said polyepoxide corresponds to the formula ##STR## wherein m is 0-50 and X is --CH 2 --, ##STR## 14. The curable mixture of claim 7, wherein 1,4-butanediol diglycidyl ether is the polyepoxide in said hardener. 15. The curable mixture of claim 7, wherein in said hardener from about 2 to 10 moles of diamine are present per mole of polyepoxide. 16. The product obtained by curing the mixture of claim 7 at elevated temperatures. 17. The product obtained by curing the mixture of claim 10 at elevated temperatures. 18. A curable mixture comprising (a) a urethane resin and (b) a hardener according to claim 1. 19. The product obtained by curing the mixture of claim 18 at elevated temperatures.
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