초록 ▼

A catalyst which exhibits superior activity maintenance in dehydrocyclization reactions are defined as a type L zeolite having exchangeable cations of which at least 75% are selected from Group IA and calcium and barium cations and containing well dispersed particles of at least one Group VII noble

A catalyst which exhibits superior activity maintenance in dehydrocyclization reactions are defined as a type L zeolite having exchangeable cations of which at least 75% are selected from Group IA and calcium and barium cations and containing well dispersed particles of at least one Group VII noble metal the preparation of which involves contacting the zeolite substantially free of moisture with a solution of the noble metal.

대표청구항 ▼

1. A process for preparing a catalyst which comprises substantially eliminating moisture from a zeolite L by heating the zeolite, contacting the heated zeolite L with a solution containing at least one Group VIII noble metal, separating a noble metal loaded zeolite from the solution and, calcining t

1. A process for preparing a catalyst which comprises substantially eliminating moisture from a zeolite L by heating the zeolite, contacting the heated zeolite L with a solution containing at least one Group VIII noble metal, separating a noble metal loaded zeolite from the solution and, calcining the loaded zeolite L at a temperature less than about 400° C. 2. The process of claim 1 wherein the zeolite L is immersed in the noble metal solution for less than about 2 minutes. 3. The process of claim 2 wherein the noble metal is platinum. 4. The process of claim 2 wherein the zeolite has an average crystal size of no greater than about 0.2 microns. 5. The process of claim 2 wherein the solution concentration ranges from about 7 to 20 mg equivalent of noble metal per cc of solution. 6. A process for preparing a reforming catalyst which comprises substantially eliminating the moisture from a zeolite L by heating the zeolite from about 70° to 200° C., contacting the heated zeolite with a solution containing from about 7 to 20 mg equivalent per ml. of at least one Group VIII noble metal for a period of less than about 2 minutes, separating a metal loaded zeolite from the solution and, calcining the loaded zeolite at a temperature less than about 400° C. 7. The process of claim 6 wherein the noble metal is platinum. 8. The process of claim 7 wherein the average crystal size of the zeolite is no greater than about 0.2 microns.