초록 ▼

When obtaining microcapsules by covering a hydrophobic material with an aminoaldehyde polycondensation product as a wall-forming material in an acidic aqueous medium containing an anionic water-soluble polymer, a microcapsule slurry having a high solid content and low viscosity can be obtained by us

When obtaining microcapsules by covering a hydrophobic material with an aminoaldehyde polycondensation product as a wall-forming material in an acidic aqueous medium containing an anionic water-soluble polymer, a microcapsule slurry having a high solid content and low viscosity can be obtained by using as the anionic water-soluble polymer a multi-component copolymer consisting as essential monomer components thereof of at least three types of acrylic monomers selected respectively from (A) acrylic acid and/or methacrylic acid, (B) acrylonitrile and/or methacrylonitrile and (C) an acrylamidoalkylsulfonic acid and/or sulfoalkyl acrylate. Over a wide pH range, the microcapsule slurry obtained in accordance with this invention undergoes little viscosity changes and exhibits neither destruction of its dispersed state nor coagulating tendency. Resulting microcapsules have a sharp particle size distribution and are equipped with dense wall films.

대표청구항 ▼

Process for producing microcapsules by covering a hydrophobic material with an aminoaldehyde polycondensation product as a wall-forming material in an acidic aqueous medium containing an anionic water-soluble polymer, characterized in that a multi-component copolymer containing as essential monomer

Process for producing microcapsules by covering a hydrophobic material with an aminoaldehyde polycondensation product as a wall-forming material in an acidic aqueous medium containing an anionic water-soluble polymer, characterized in that a multi-component copolymer containing as essential monomer components thereof at least three types of acrylic monomers, which are selected respectively from (A) acrylic acid and/or methacrylic acid, (B) acrylonitrile and/or methacrylonitrile and (C) an acrylamidoalkylsulfonic acid and/or a sulfoalkyl acrylate, is used as the anionic water-soluble polymer, the proportions of said three types of monomers being from 20 to 70 mole percent of monomer (A), from 20 to 70 mole percent of monomer (B) and from 0.5 to 30 mole percent of monomer (C), respectively, and the amount of the anionic water-soluble polymer used being 0.5 to 10 weight percent of the microcapsule-producing system. Microcapsule slurry obtained by covering a hydrophobic material with an aminoaldehyde polycondensation Product as a wall-forming material in an acidic aqueous medium containing an anionic water-soluble polymer, characterized in that the anionic water-soluble polymer is a multi-component copolymer containing as essential monomer components thereof at least three types of acrylic monomers selected respectively from (A) acrylic acid and/or methacrylic acid, (B) acrylonitrile and/or methacrylonitrile and (C) an acrylamidoalkylsulfonic acid and/or sulfoalkyl acrylate, the proportions of said three types of monomers being from 20 to 70 mole percent of monomer (A), from 20 to 70 mole percent of monomer (B) and from 0.5 to 30 mole percent of monomer (C), respectively, and the amount of the anionic water-soluble polymer used in the microcapsule-producing system being 0.5 to 10 weight percent.