초록 ▼

This invention relates to membrane gas separation of carbon dioxide and methane containing gas mixtures. More particularly the invention relates to apparatus and processes for recovering a methane-enriched non-permeate gas of natural gas pipe line quality from mixtures of carbon dioxide and methane

This invention relates to membrane gas separation of carbon dioxide and methane containing gas mixtures. More particularly the invention relates to apparatus and processes for recovering a methane-enriched non-permeate gas of natural gas pipe line quality from mixtures of carbon dioxide and methane where membrane permeate gases contain substantially all of the carbon dioxide of the feed gas mixture. An aspect of the process of this invention is that a significant portion of the carbon dioxide containing permeate gas can be utilized as combustion engine fuel to drive feed gas compressors utilized in the process.

대표청구항 ▼

A membrane gas separator apparatus for recovering a methane-enriched non-permeate gas from a mixture comprising methane and carbon dioxide, said appartaus comprising at least one first separator having a membrane exhibiting selectivity to the permeation of carbon dioxide; at least one subsequent sep

A membrane gas separator apparatus for recovering a methane-enriched non-permeate gas from a mixture comprising methane and carbon dioxide, said appartaus comprising at least one first separator having a membrane exhibiting selectivity to the permeation of carbon dioxide; at least one subsequent separator having a membrane exhibiting selectivity to the permeation of carbon dioxide; a combustion engine for generating power; means for providing said mixture at a permeating pressure to said at least one first separator; means for conducting a non-permeate gas from said at least one first separator to said at least one subsequent separator; means for withdrawing carbon dioxide-enriched permeate gas from said at least one first separator; means for withdrawing a methane-enriched non-permeate gas from said at least one subsequent separator; means for conducting a combustible permeate gas from said at least one subsequent separator to a fuel inlet of said combustion engine; and means for transmitting power from said combustion engine to said means for providing said mixture at a permeating pressure. A membrane gas separation process for recovering from a mixture comprising from 30 to 70 mole percent methane and from 30 to 60 mole percent carbon dioxide a methane-enriched non-permeate gas said process comprising (a) passing said mixture to means for providing said mixture at a permeating pressure; (b) passing said mixture at a permeating pressure to at least one first separator having a membrane exhibiting selectivity to the permeation of carbon dioxide, wherein the separation factor, a2/CH4, is at least about 9; (c) allowing the non-permeate gas from said at least one first separator to pass at a permeating pressure to at least one subsequent separator having a membrane exhibiting selectivity to the permeation of carbon dioxide, wherein the separation factor, a2/CH4, is at least about 9; (d) withdrawing a carbon dioxide-enriched permeate gas from said at least one first separator; (e) withdrawing a methane-enriched non-permeate gas comprising at least about 90 mole percent methane from said at least one subsequent separator; and (f) allowing a combustible permeate gas comprising at least about 40 mole percent methane to flow from said at least one subsequent separator to a combustion engine having means to transmit power to said means for providing said mixture at a permeating pressure.