초록 ▼

A process employing two- and three-compartment electrodialytic water splitting for conversion of basic sodium material such as dry-mined or subterranean deposits of trona or nahcolite into a liquid comprising aqueous sodium base such as NaOH and/or Na2CO3. The basic sodium material is contacted with

A process employing two- and three-compartment electrodialytic water splitting for conversion of basic sodium material such as dry-mined or subterranean deposits of trona or nahcolite into a liquid comprising aqueous sodium base such as NaOH and/or Na2CO3. The basic sodium material is contacted with a liquid comprising aqueous hydrogen ions for a time sufficient to produce a liquid comprising aqueous sodium ions. A liquid comprising water is introduced into each base compartment and the liquid comprising aqueous sodium ions is introduced into each remaining compartment of a two- or three-compartment water splitter. Direct current is passed through said water splitter to produce, a liquid comprising an aqueous sodium base in the base compartment and a liquid comprising aqueous hydrogen ions in an acid compartment of said water splitter. At least a portion of the liquid comprising aqueous hydrogen ions is used in the initial contacting step. In preferred embodiments, a subterranean deposit of trona is solution mined with a Na2SO4/H2SO4 solution thereby converting the trona into CO2 and an aqueous solution (reaction liquid) of Na2SO4, optionally containing NaHCO3, which is pumped to the surface and supplied to a water splitter to wherein a Na2SO4/H2SO4 solution is regenerated and aqueous NaOH is produced. The regenerated Na2SO4/H2SO4 may be reinjected into the trona deposit and the NaOH may be concentrated or optionally used to convert trona into soda ash.

대표청구항 ▼

A process for converting basic sodium material into a liquid comprising aqueous hydrogen ions and a liquid comprising aqueous sodium base which comprises: (a) contacting basic sodium material with a liquid comprising aqueous hydrogen ions for a time sufficient to produce a reaction liquid comprising

A process for converting basic sodium material into a liquid comprising aqueous hydrogen ions and a liquid comprising aqueous sodium base which comprises: (a) contacting basic sodium material with a liquid comprising aqueous hydrogen ions for a time sufficient to produce a reaction liquid comprising aqueous sodium ions and being substantially free of CO3〓values; (b) introducing the reaction liquid and a liquid comprising water into separate compartments of an electrodialytic water splitter; (c) passing direct current through said electrodialytic water splitter to produce a reaction liquid product comprising aqueous hydrogen ions and a liquid product comprising an aqueous sodium base; (d) withdrawing reaction liquid product from the electrodialytic water splitter; and (e) supplying at least a portion of the withdrawn reaction liquid product for contact with the basic sodium material.