초록 ▼

A solid composition of matter selected from the group consisting of: (a) a component comprising: (1) at least one material selected from the group consisting of Group IA metals and compounds containing said metals, a component comprising: (2) at least one material selected from the group consisting

A solid composition of matter selected from the group consisting of: (a) a component comprising: (1) at least one material selected from the group consisting of Group IA metals and compounds containing said metals, a component comprising: (2) at least one material selected from the group consisting of zinc and compounds containing zinc, and a component comprising: (3) at least one material selected from the group consisting of chloride ions, compounds containing chloride ions; tin and compounds containing tin; and (b) a component comprising: (1) at least one material selected from the group consisting of Group IA metals and compounds containing said metals, a component comprising: (2) zinc oxide, and, optionally, a component comprising: (3) at least one material selected from the group consisting of chloride ions, compounds containing chloride ions tin and compounds containing tin. The above composition of matter is useful as a solid contact material adapted to convert feed organic compounds to product organic compounds, particularly, in the presence of a free oxygen containing gas. A method for the conversion of feed organic materials to product organic materials, particularly methane to ethylene, in the presence of a free oxygen containing gas, utilizing combinations of Group IA metals, zinc and, optionally, chloride ions and/or tin, is also disclosed.

대표청구항 ▼

A method for the oxidative conversion of feed organic compounds comprising methane to product organic compounds comprising higher hydrocarbons, comprising: contacting said feed organic compounds and a free oxygen-containing gas with a solid contact material selected from the group consisting of: (a)

A method for the oxidative conversion of feed organic compounds comprising methane to product organic compounds comprising higher hydrocarbons, comprising: contacting said feed organic compounds and a free oxygen-containing gas with a solid contact material selected from the group consisting of: (a) a contact material consisting essentially of: (1) at least one material selected from the group consisting of Group IA metals and compounds containing said metals, and (2) zinc oxide; and (b) a contact material consisting essentially of: (1) at least one material selected from the group consisting of Group IA metals and compounds containing said metals, (2) zinc oxide and (3) at least one material selected from the group consisting of chloride ions, compounds containing chloride ions, tin and compounds containing tin, under oxidative conversion conditions sufficient to convert said feed organic compounds to said product organic compounds.