초록

This invention relates to N-aryl-3-aryl-4,5-dihydro-1H-pyrazole-1-carboxamide compounds which are useful as pesticides, compositions containing those compounds, methods of controlling pests and processes for preparing these compounds.

대표청구항 ▼

A compound of the formula [Figure] wherein A is unsubstituted or substituted aryl; B is unsubstituted or substituted aryl; U is O, S or N－Q; V is hydrogen, (C3-C6)cycloalkyl, unsubstituted or substituted aryl or R4－Q; Y is a group having the formula [Figure] where X is O or S; Z is hydrogen, (C3-C6)

A compound of the formula [Figure] wherein A is unsubstituted or substituted aryl; B is unsubstituted or substituted aryl; U is O, S or N－Q; V is hydrogen, (C3-C6)cycloalkyl, unsubstituted or substituted aryl or R4－Q; Y is a group having the formula [Figure] where X is O or S; Z is hydrogen, (C3-C6)cycloalkyl, unsubstituted or substituted aryl or R4－Q; Q is hydrogen, halogen, cyano, nitro, OR1, R4OR1, CO2R1, OR4OR1, CR1R2R3, CONR1R2, NR1R2, NR1COR2, N(COR1)COR2, CSR1, SR1, SOR1, SO2R1, NR1SOR2, R4SR1, OR4SR1, SR4SR1, SNHSR1, SNHSO2R1, CONHSR1, OCOR1, R1, C(〓NR1)R2, COR1, N3, OSO2R1, NR1SO2R2, NR1CSR2, alkenyl (CR1=CR2R3), alkynyl (C≡CR1), or aryl; R1, R2 and R3 are, independently, hydrogen, halogen, cyano, nitro, hydroxy, an alkoxy group (OR) having up to four carbon atoms, an amino group (NH2), an alkylamino group (NHR) having up to six carbon atoms, a dialkylamino group (NR2) having, independently, up to six carbon atoms in each alkyl moiety, a carboxy group (CO2H), a carbalkoxy group (CO2R) having up to six carbon atoms, an alkylcarbonyl group (COR) having up to six carbon atoms, an alkanoyloxy group (OCOR) having up to six carbon atoms, a carboxamido group (CONH2), an N-alkylcarboxamido group (CONHR) having up to six carbon atoms in the alkyl moiety, an N,N-dialkylcarboxamido group (CONR2) having, independently, up to six carbon atoms in each alkyl moiety, carbamoyloxy group (OCONH2), an N-alkylcarbamoyloxy group (OCONHR) having up to six carbon atoms in the alkyl moiety, an N,N-dialkylcarbamoyloxy group (OCONR2) having, independently, up to six carbon atoms in each alkyl moiety, a sulfhydril, an alkylsulfinyl group (－SOR) having up to six carbon atoms, an alkylsulfonyl group (－SO2R) having up to six carbon atoms, an alkylsulfonato group (－OSO2R) having up to six carbon atoms, an alkylthio group (SR) having up to six carbon atoms, a sulfonamido (SO2NH2), an N-alkylsulfonamido group (SO2NHR) having up to six carbon atoms in the alkyl moiety, an N,N-dialkylsulfonamido group (SO2NR2) having, independently, up to six carbon atoms in each alkyl moiety, an N-alkyl-N-acylamino group (NRCOR) having, independently, up to six carbon atoms in each alkyl moiety, an N-alkyl-N-alkylsulfonylamino group (NRSO2R) having, independently, up to six carbon atoms in each alkyl moiety, an alkylthiocarbonyl group (CSR) having up to six carbon atoms, an N-alkyl-N-thioacylamino group (NRCSR) having, independently, up to six carbon atoms in each alkyl moiety, an N-alkyl-N-alkylsulfinylamino group (NRSOR) having, independently, up to six carbon atoms in each alkyl moiety, an N,N-diacylamino group (N(COR)COR) having, independently, up to six carbon atoms in each alkyl moiety, an unsubstituted or substituted straight or branched chain (C1-C6)alkyl, (C3-C 6)cycloalkyl or unsubstituted or substituted aryl where the substituent on the alkyl moiety can be one or more of the same or different hydroxy, halogen, cyano, nitro, alkoxy group (OR) having up to four carbon atoms, an amino group (NH2), an alkylamino group (NHR) having up to six carbon atoms, a dialkylamino group (NR2) having, independently, up to six carbon atoms in each alkyl moiety, a carboxy group (CO2H), a carbalkoxy group (CO2R) having up to six carbon atoms, an alkylcarbonyl group (COR) having up to six carbon atoms, an alkanoyloxy group (OCOR) having up to six carbon atoms, a carboxamido group (CONH2), an N-alkylcarboxamido group (CONHR) having up to six carbon atoms in the alkyl moiety, an N,N-dialkylcarboxamido group (CONR2) having, independently, up to six carbon atoms in each alkyl moiety, a carbamoyloxy group (OCONH2), an N-alkylcarbamoyloxy group (OCONHR) having up to six carbon atoms in the alkyl moiety, an N,N-dialkylcarbamoyloxy group (OCONR2) having, independently, up to six carbon atoms in each alkyl moiety, a sulfhydril, an alkylsulfinyl group (－SOR) having up to six carbon atoms, an alkylsulfonyl group (－SO2R) having up to six carbon atoms, an alkylsulfonato group (－OSO2R) having up to six carbon atoms, an alkylthio group (SR) having up to six carbon atoms, a sulfonamido (SO2NH2), an N-alkylsulfonamido group (SO2NHR) having up to six carbon atoms in the alkyl moiety, an N,N-dialkylsulfonamido group (SO2NR2) having, independently, up to six carbon atoms in each alkyl moiety, an N-alkyl-N-acylamido group (NRCOR) having, independently, up to six carbon atoms in each alkyl moiety, an N-alkyl-N-alkylsulfonylamino (NRSO2R) having, independently, up to six carbon atoms in each alkyl moiety, an alkylthiocarbonyl group (CSR) having up to six carbon atoms, an N-alkyl-N-thioacylamino group (NRCSR) having, independently, up to six carbon atoms in each alkyl moiety, an N-alkyl-N-alkylsulfinylamino (NRSOR) having, independently, up to six carbon atoms in each alkyl moiety, an N,N-diacylamino group (N(COR)COR) having, independently, up to six carbon atoms in each alkyl moiety, or an unsubstituted or substituted aryl group, where R is an alkyl group having the stated number of carbon atoms; R4 is [Figure] G is (C3-C6)cycloalkyl, unsubstituted or substituted aryl or R4－Q; and n is an integer from 0 to 10; or an agronomically acceptable salt thereof; wherein unsubstituted or substituted aryl is phenyl, optionally substituted with 1-5 substituents independently chosen from W; naphthyl, optionally substituted with 1-7 substituents independently chosen from W; a pyrryl; furyl; thienyl; imidazolyl; oxazolyl; thiazolyl; pyrazolyl; pyridyl or pyrimidyl optionally substituted with 1-4 substituents independently chosen from W; where W is halogen, cyano, nitro, R1, CO2R1, CONR1R2, CR1〓CR2R3, C≡CR1, SR1, OR1, NR1R2, SOR1, SO2R1, OSO2R1, NR1COR2, SF5, CF3, OCF3, OCF2H, SCF3, OCF2Br, SCF2Br, SCF2Cl, SCF2H, NR1SO2R2 or N(COR1)COR2. A method of controlling insects which comprises applying to the insects or to the loci to be freed or protected from attack by insects an insecticidally effective amount of a compound according to claim 1.