초록 ▼

Adjusted gas compositions having two or more components in desired proportions for particular industrial uses are obtained from available feed gas mixtures accompanied by recovery of one or more valuable individual gases of high purity, by a novel selective adsorption-desorption scheme carried out i

Adjusted gas compositions having two or more components in desired proportions for particular industrial uses are obtained from available feed gas mixtures accompanied by recovery of one or more valuable individual gases of high purity, by a novel selective adsorption-desorption scheme carried out in a multi-column PSA system. Following initial adsorption of one or more components from the feed gas mixture at high pressure the sorbate-laden column is subjected to a high pressure rinse using as rinse gas the previously recovered more strongly adsorbed species. After the rinsing step, the column is depressured to a selected level and purged with part of the unsorbed gas effluent discharged during the initial adsorption step until a preset amount of the earlier sorbed gas is recovered in the purge effluent as the readjusted binary gas mixture of desired proportions. As an example, there is disclosed the production from a starting gas mixture rich in hydrogen and carbon monoxide, such as that obtained from steam-methane reforming, an industrially useful gas mixture having a desired H2/CO ratio with the accompanying individual recovery of high purity hydrogen and carbon monoxide as by-products.

대표청구항 ▼

In the production of a binary gas mixture of desired fixed proportions of components from a starting feed gas containing such components, the method which comprisees the steps of (a) passing the feed gas at superatmospheric pressure into a bed of solid adsorbent preferentially selective in retention

In the production of a binary gas mixture of desired fixed proportions of components from a starting feed gas containing such components, the method which comprisees the steps of (a) passing the feed gas at superatmospheric pressure into a bed of solid adsorbent preferentially selective in retention of a first of said components, while discharging from said bed as primary effluent a stream consisting essentially of the unadsorbed or less selectively adsorbed second component; (b) while said bed is at about the aforesaid superatmospheric pressure, discontinuing said feed gas introduction and rinsing the bed, in a direction co-current to that of the feed gas introduction, with a gas stream rich in said preferentially retained first component; (c) withdrawing contained gas from said bed until said bed is depressurized to about a pressure level P and compressing at least a part of the gas so withdrawn to about superatmospheric level for use as rinsing gas in step (b); (d) while at about said pressure level of P, purging the bed with a controlled amount of the gas discharged as primary effluent during step (a), thereby producing a purge effluent as the binary gas mixture of desired fixed proportions of components; and thereafter (e) repressuring the bed to the initial superatmospheric pressure level of step (a) for repetition of the recited sequence of steps, said repressuring being effected with part of the primary effluent from step (a).