Urban Peter (Northbrook IL) Engel Dusan J. (Des Plaines IL)
출원인 / 주소
UOP Inc. (Des Plaines IL 02)
인용정보
피인용 횟수 :
10인용 특허 :
0
초록▼
Liquefaction of lignin by hydrogenolysis in the presence of a catalytic composition of metal sulfides which are prepared in situ and in the presence of a lower aliphatic alcohol affords substantially increased yields of monophenols. When methanol is used in the presence of a catalyst which is a mixt
Liquefaction of lignin by hydrogenolysis in the presence of a catalytic composition of metal sulfides which are prepared in situ and in the presence of a lower aliphatic alcohol affords substantially increased yields of monophenols. When methanol is used in the presence of a catalyst which is a mixture of the sulfides of divalent iron, copper, and tin the total monophenols can be as high as 65% with the total cresols being about 45%. Phenol, which is used as a liquefying solvent, can itself be formed in good yield when lignin tar is used as the liquefying solvent. This affords the opportunity of conducting the liquefaction in a continuous fashion using two stages of reaction.
대표청구항▼
A method of liquefying lignin from the Kraft process comprising forming in situ a catalystic composition resulting from the addition of a sulfide source to an aqueous solution of divalent iron, and at least one promoter metal selected from the group consisting of copper, tin, silver, chromium, cobal
A method of liquefying lignin from the Kraft process comprising forming in situ a catalystic composition resulting from the addition of a sulfide source to an aqueous solution of divalent iron, and at least one promoter metal selected from the group consisting of copper, tin, silver, chromium, cobalt, nickel, zinc, molybdenum, gallium, and germanium, and reacting a mixture of an aqueous solution of said lignin, phenol, and a lower aliphatic alcohol in the presence of said catalytic composition in a hydrogen atmosphere at a temperature from about 300°to about 450°C. and an initial pressure from about 50 to about 150 atmospheres. A method of making cresols from lignin from the Kraft process comprising: (a) reacting a mixture of an aqueous solution of the lignin, phenol, and a lower aliphatic alcohol in the presence of a catalytic composition prepared in situ of sulfides of divalent iron and at least one promoter metal selected from the group consisting of copper, tin, silver, chromium, cobalt, nickel, zinc, molybdenum, gallium, and germanium, in a hydrogen atmosphere at a temperature from about 300°to about 450°C. and an initial hydrogen pressure from about 50 to about 150 atmospheres to afford a first product mixture; (b) recovering from the first product mixture substantially all material of boiling point less than about 235°C.; (c) reacting the remainder fo the first product mixture with an aqueous solution of a lignin salt in the presence of said catalyst compositon in a hydrogen atmosphere at a temperature of 300°to about 450°C. and an initial hydrogen pressure of about 50 to 150 atmospheres to afford a second product mixture; (d) recovering fromthe second product mixture substantially all material of boiling point less than about 235°C.; and (e) recycling the material of step (d) to step (a) as replacement therein, in whole or in part, for phenol.
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이 특허를 인용한 특허 (10)
Naae Douglas Gene ; Whittington Lawrence Edward ; Kieke Dan Edward, Catalytic method for the preparation of lignin phenol surfactants in organic solvents.
Naae Douglas Gene ; Whittington Lawrence Edward ; Kieke Dan Edward, Catalytic method for the preparation of lignin phenol surfactants in organic solvents.
Jung, Min Ho; Moon, Sun Joo; Park, Jeung Yil; Lee, Sang Mok; Kim, Da Eun; Kim, Young Ran; Kim, Jung Min; Chang, Jin Hwa, Method for preparing low-molecular lignin derivative.
Li, Yongdan; Ma, Rui; Ma, Xiaolei; Hao, Wenyue, Use of catalyst prepared with a subgroup VI element for the production of organic chemicals and fuels from lignin.
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