초록 ▼

A liquid containing radioactive ions is purified (decontaminated) by contacting the same with an inorganic ion exchange composition having ion exchange sites which can be occupied by the radioactive ions from the liquid. The ion exchange composition is a mixture of an ion exchange medium and an addi

A liquid containing radioactive ions is purified (decontaminated) by contacting the same with an inorganic ion exchange composition having ion exchange sites which can be occupied by the radioactive ions from the liquid. The ion exchange composition is a mixture of an ion exchange medium and an additive which is relatively inert to the ion exchange process and which is a sintering aid for the ion exchange medium designed to lower the sintering temperature of the ion exchange composition. The ion exchange composition may be disposed within a suitable container (e.g., cannister), e.g., made of 304L stainless steel or Inconel 601 and the ion exchange process may be carried out in such container. Alternatively, the ion exchange medium can be employed without being previously admixed with the additive. The additive, if desired, can be admixed at a later stage with the contaminated medium. Thereafter, the mixture may be sintered and disposed of in any desirable manner as by underground burial of the spent mixture within the container. Also, the container may be placed within a suitably designed furnace for carrying out the ion exchange process, sintering of the ion exchange composition and its safe disposal. Methods are also described for making a homogeneous mixture of the ion exchange medium and the additive which, for example, have a certain defined density and particle size relationship.

대표청구항 ▼

A method of removing radioactive ions from a liquid containing such ions with an ion exchange medium and sintering the ion exchange medium to form a monolith, comprising: (1) providing an ion exchange medium for radioactive ions, said ion exchange medium being selected from the group consisting of:

A method of removing radioactive ions from a liquid containing such ions with an ion exchange medium and sintering the ion exchange medium to form a monolith, comprising: (1) providing an ion exchange medium for radioactive ions, said ion exchange medium being selected from the group consisting of: (i) porous silicate glass or porous silica gel, (ii) natural or syntheitc clays, (iii) hydrated metal oxides, (iv) the alkali salts of said hydrated metal oxides, and (v) mixtures of (i)-(iv); (2) containing said ion exchange medium in a canister capable of withstanding the sintering temperature of said ion exchange composition; (3) contacting said ion exchange medium contained in said canister with said liquid to exchange cations or anions of said ion exchange medium with said radioactive ions; (4) mixing said ion exchange medium contained in said canister with an additive which is a sintering aid for said ion exchange medium and permits said composition to be sintered at a temperature below about 1200 degrees C., said additive being mixed with said ion exchange medium either before or after step (3); and (5) sintering said ion exchange medium contained in said canister to form a monolith.