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Preparation of ethanol and higher alcohols from lower carbon number alcohols 원문보기

IPC분류정보
국가/구분 United States(US) Patent 등록
국제특허분류(IPC7판)
  • C07C-029/00
  • C07C-027/00
  • C07C-031/08
  • C07C-031/10
출원번호 US-0154536 (1988-02-16)
발명자 / 주소
  • Quarderer George J. (Midland MI) Stevens Rex R. (Midland MI) Cochran Gene A. (Midland MI) Murchison Craig B. (Midland MI)
출원인 / 주소
  • The Dow Chemical Company (Midland MI 02)
인용정보 피인용 횟수 : 34  인용 특허 : 8

초록

A process for forming an alcohol fraction boiling in the range of motor gasoline that is enriched in higher alcohols, comprises contacting a mixture of hydrogen, carbon monoxide and a lower alkanol with a catalyst comprising: (1) a first component comprising molybdenum, tungsten or a mixture thereof

대표청구항

A process comprising contacting a mixture of hydrogen, carbon monoxide and one or more lower alcohols with a heterogeneous catalyst consisting of: (1) a molybdenum metal, sulfide, oxide, carbide or a mixture thereof; (2) an alkali or alkaline earth element or a mixture thereof in free or combined fo

이 특허에 인용된 특허 (8)

  1. Current Steven P. (Novato CA), Alcohol carbonylation process using a bimetallic cobalt catalyst.
  2. Current Steven P. (Novato CA), Alcohol carbonylation process using a bimetallic nickel catalyst.
  3. Hargis Duane C. (Pleasant Ridge MI) Dubeck Michael (Birmingham MI), Catalytic composition for the selective formation of ethanol and methyl acetate from methanol and synthesis gas.
  4. Chen Michael J. (Darien IL) Rathke Jerome W. (Bolingbrook IL), Methanol production method and system.
  5. Isogai Nobuo (Niigata JPX) Okawa Takashi (Niigata JPX) Wakui Natuko (Niigata JPX), Process for producing ethanol.
  6. Ellgen ; Paul Clifford ; Bhasin ; Madan Mohan, Process for producing ethanol, acetic acid and/or acetaldehyde, from synthesis gas.
  7. Keim Karl-Heinz (Heimerzheim DEX) Korff Joachim (Bornheim-Sechtem DEX), Process for the production of acetaldehyde and ethanol.
  8. Walker Robert H. (Chicago IL) Palmer David A. (Naperville IL) Salvatore Donna M. (Chicago IL) Bernier Edward J. (Naperville IL), Syn gas conversion.

이 특허를 인용한 특허 (34)

  1. Ding, Yunjie; Zhu, Hejun; Wang, Tao; Jiao, Guiping; Lv, Yuan, Activated carbon supported cobalt based catalyst for directly converting of synthesis gas to mixed linear alpha-alcohols and paraffins.
  2. Manikandan, Palanichamy; Barton, David G.; Millar, Dean M., Anderson-type heteropoly compound-based catalyst compositions and their use conversion of synthesis gas to oxygenates.
  3. Jones, Christopher W.; Agrawal, Pradeep K.; Nguyen, Tien Thao, Carbon-supported catalysts for production of higher alcohols from syngas.
  4. Caram, Hugo S.; Sahoo, Ranjan K.; Herman, Richard G.; Acharya, Divyanshu R., Catalyst composition formulated for synthesis of alcohols and method of preparing the same.
  5. Jones, Christopher W.; Agrawal, Pradeep K.; Nguyen, Tien Thao, Catalyst compositions for converting syngas to produce higher alcohols.
  6. Menne, Andreas; Kraft, Axel, Catalytic conversion of alcohols and aldehydes.
  7. Sher,Jaimes; Van Egmond,Cornelis F.; Martens,Luc R. M.; Janssen,Mechilium Johannes; Lattner,James R.; Xu,Teng, Controlling the ratio of ethylene to propylene produced in an oxygenate to olefin conversion process.
  8. Gadewar, Sagar B.; Stoimenov, Peter K., Ethyl acetate production.
  9. Gadewar, Sagar B.; Vicente, Brian Christopher; Norton, Robert Elliot; Doherty, Michael Francis, Ethyl acetate production.
  10. Jimeson, Robert M.; Radosevich, Mark C.; Stevens, Rex R., Fuels for internal combustion engines.
  11. Manikandan, Palanichamy; Rao, Sreenivasa; Barton, David G., Keggin-type structure heteropoly compound-based catalyst compositions and their use in conversion of synthesis gas to oxygenates.
  12. Van Egmond,Cornelis F.; Argo,Andrew; Xu,Teng; Janssen,Marcel Johannes; Sher,Jaimes, Methanol and ethanol production for an oxygenate to olefin reaction system.
  13. Janssen,Marcel Johannes; Van Egmond,Cornelis F.; Martens,Luc R. M.; Sher,Jaimes, Methanol and fuel alcohol production for an oxygenate to olefin reaction system.
  14. Chunshan Song ; Yoshiharu Yoneyama JP; Madhusudan Reddy Kondam, Method for preparing a highly active, unsupported high surface-area MoS2 catalyst.
  15. Song Chunshan ; Yoneyama Yoshiharu,JPX ; Kondam Madhusudan Reddy, Method for preparing a highly active, unsupported high-surface-area ub . MoS.s2 catalyst.
  16. Tirmizi, Shakeel H.; Klepper, Robert E.; Ferraro, Francis M., Methods and apparatus for producing alcohols from syngas.
  17. Klepper, Robert E.; Geertsema, Arie; Tirmizi, Shakeel H.; Robota, Heinz Juergen; Ferraro, Francis M.; Stites, Ronald C., Methods and apparatus for producing syngas and alcohols.
  18. Tijm, Peter J.; Baksh, Faisal, Methods for improving higher alcohol yields from syngas by altering flow regimes within a reactor.
  19. Klepper, Robert E.; Geertsema, Arie; Tirmizi, Shakeel H.; Ferraro, Francis M., Methods for producing syngas.
  20. Kharas, Karl; Durand, Jason P.; May, William A., Methods of making improved cobalt-molybdenum-sulfide catalyst compositions for higher alcohol synthesis.
  21. Jimeson, Robert M.; Radosevich, Mark C.; Stevens, Rex R., Mixed alcohol fuels for internal combustion engines, furnaces, boilers, kilns and gasifiers.
  22. Jimeson, Robert M.; Radosevich, Mark C.; Stevens, Rex R.; Giardino-Radosevich, Geradelte, Mixed alcohol fuels for internal combustion engines, furnaces, boilers, kilns and gasifiers.
  23. Giardino, Geradette; Jimeson, Robert M.; Radosevich, Mark C.; Stevens, Rex R., Mixed alcohol fuels for internal combustion engines, furnaces, boilers, kilns and gasifiers and slurry transportation.
  24. Tirtowidjojo, Max M.; Fish, Barry B.; Pelt, Hendrik L.; Jewell, Dennis W.; Bearden, Mark D.; Pendergast, Jr., John G.; Siddall, Jon H.; Stears, Brien A.; Tran, Haivan D.; Verwijs, Jan W.; Verwijs-van den Brink, legal representative, Aaltje; Verwijs, legal representative, Lena; Verwijs, legal representative, Hendrika Gerrita; Wehmeyer, Richard M., Mixed alcohol synthesis with enhanced carbon value use.
  25. Pearson, Stanley R., Process and apparatus for the production of useful products from carbonaceous feedstock.
  26. Pearson, Stanley R., Process and apparatus for the production of useful products from carbonaceous feedstock.
  27. Aiken, John E., Process for integrated co-production of hydrogen peroxide and epoxidized esters.
  28. Gulotty, Jr., Robert J.; Millar, Dean M.; Schweizer, Jr., Albert E.; Collins, Raymond M., Process for synthesis of molybdenum sulfide-based catalysts.
  29. Nielsen, Poul Erik Højlund; Temel, Burcin; Beato, Pablo, Process for the preparation of ethanol and higher alcohols.
  30. Gadewar, Sagar B.; Vicente, Brian Christopher; Stoimenov, Peter K., Production of butyl acetate from ethanol.
  31. Gadewar, Sagar B.; Vicente, Brian Christopher; Stoimenov, Peter K.; Julka, Vivek, Production of higher alcohols.
  32. Tijm, Peter J.; Stevens, Rex R., Production of mixed alcohols from synthesis gas.
  33. Lattner,James R., Reactor and process for producing methanol.
  34. Jin Yun,CNX ; Yu Qiquan,CNX ; Chang Shih-Ger, Sulfide catalysts for reducing SO2 to elemental sulfur.
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