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Catalyst for the production of an alcohol and/or a carboxylic acid ester by hydrogenation of a carboxylic acid 원문보기

IPC분류정보
국가/구분 United States(US) Patent 등록
국제특허분류(IPC7판)
  • B01J-021/18
  • B01J-023/28
  • B01J-023/30
  • B01J-023/40
출원번호 US-0197579 (1988-05-05)
우선권정보 GB-0009530 (1985-04-13)
발명자 / 주소
  • Kitson Melanie (Staines GB2) Williams Peter S. (Hull GB2)
출원인 / 주소
  • BP Chemicals Limited (London GB2 03)
인용정보 피인용 횟수 : 126  인용 특허 : 3

초록

An alcohol and/or a carboxylic acid ester is (are) produced from a C2 to C12 carboxylic acid by contacting the carboxylic acid at elevated temperature and pressure with hydrogen in the presence of a heterogeneous catalyst characterized in that the catalyst comprises a first component which is either

대표청구항

A catalyst for use in the hydrogenation of a C2 to C12 carboxylic acid to produce an alcohol and/or a carboxylic acid ester which catalyst comprises from 1 to 10% by weight of a first component which is molybdenum or tungsten from 1 to 10% by weight of a second component which is a noble metal of Gr

이 특허에 인용된 특허 (3)

  1. Travers Christine (Rueil-Malmaison FRX) Trinh Dinh Chan (Le Vesinet FRX) Snappe Roger (Sevres FRX) Bournonville Jean-Paul (Chatou FRX), Catalytic process for manufacturing alcohols by hydrogenolysis of carboxylic acid esters.
  2. Grey Roger A. (Denville NJ) Pez Guido P. (Boonton NJ), Hydrogenation of esters using alkali doped heterogeneous Group VIII transition metal catalysts.
  3. Wyatt Michael (Wallingford GB2) Leach Gary M. (Reading GB2) Gould Ashley M. (Reading GB2), Three-way catalysts for purification of exhaust gas and method for the preparation of the catalysts.

이 특허를 인용한 특허 (126)

  1. Zhou, Zhenhua; Johnston, Victor J.; Weiner, Heiko, Acetic acid hydrogenation over a group VIII metal calcined catalyst having a secondary promoter.
  2. Kalakkunnath, Sumod; Truitt, Matthew J.; Bae, Jaehoon; Phillips, Cory B., Advanced cellulosic renewable fuels.
  3. Jevtic, Radmila; Johnston, Victor J.; Pan, Tianshu; Scates, Mark O.; Shaver, Ronald David; Warner, R. Jay; Weiner, Heiko; Chapman, Josefina T., Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process.
  4. Horton, Trinity; Jevtic, Radmila; Johnston, Victor J.; Pan, Tianshu; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko; Chapman, Josefina T., Alcohol production process with impurity removal.
  5. Zhou, Zhenhua; Johnston, Victor J.; Weiner, Heiko, Bismuth catalyst composition and process for manufacturing ethanol mixture.
  6. Weiner, Heiko; Zhou, Zhenhua; Johnston, Victor J., Calcination of modified support to prepare hydrogenation catalysts.
  7. Weiner, Heiko; Zhou, Zhenhua; Jevtic, Radmila; Johnston, Victor J., Catalyst having support containing tin and process for manufacturing ethanol.
  8. Weiner, Heiko; Johnston, Victor J., Catalyst supports having crystalline support modifiers.
  9. Johnston, Victor J.; Chen, Laiyuan; Kimmich, Barbara F.; Chapman, Josefina T.; Zink, James H.; Weiner, Heiko; Potts, John L.; Jevtic, Radmila, Catalysts for making ethanol from acetic acid.
  10. Johnston, Victor J.; Kimmich, Barbara F.; Potts, John L.; Weiner, Heiko; Wollrab, Radmila; Zink, James H.; Chapman, Josefina T.; Chen, Laiyuan, Catalysts for making ethanol from acetic acid.
  11. Zhou, Zhenhua; Johnston, Victor; Weiner, Heiko; Wollrab, Radmila, Catalysts having promoter metals and process for producing ethanol.
  12. Zhou, Zhenhua; Weiner, Heiko; Kumar, Dheeraj; Tu, Xiaoyan; Johnston, Victor J.; Jevtic, Radmila, Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol.
  13. Zhou, Zhenhua; Johnston, Victor; Weiner, Heiko, Cobalt and tin catalysts for producing ethanol.
  14. Zhou, Zhenhua; Weiner, Heiko, Cobalt and tin hydrogenation catalysts.
  15. Weiner, Heiko; Zhou, Zhenhua; Jevtic, Radmila; Johnston, Victor J., Cobalt/tin catalyst for producing ethanol.
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  17. Johnston, Victor J.; Chen, Laiyuan; Kimmich, Barbara F.; Chapman, Josefina T.; Zink, James H., Direct and selective production of ethanol from acetic acid utilizing a platinum/ tin catalyst.
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  20. Rueter,Michael, Direct hydrogen peroxide production using staged hydrogen addition.
  21. Rueter,Michael, Direct hydrogen peroxide production using staged hydrogen addition.
  22. Jevtic, Radmila; Johnston, Victor; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko; Horton, Trinity, Esterification of vapor crude product in the production of alcohols.
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  27. Johnston, Victor J.; Kimmich, Barbara F.; van der Waal, Jan Cornelis; Zink, James H.; Zuzaniuk, Virginie; Chapman, Josefina T.; Chen, Laiyuan, Ethanol production from acetic acid utilizing a cobalt catalyst.
  28. Johnston, Victor J.; Kimmich, Barbara F.; van der Waal, Jan Cornelis; Zink, James H.; Zuzaniuk, Virginie; Chapman, Josefina T.; Chen, Laiyuan, Ethanol production from acetic acid utilizing a cobalt catalyst.
  29. Johnston, Victor J.; Kimmich, Barbara F.; van der Waal, Jan Cornelis; Zink, James H.; Zuzaniuk, Virginie; Chapman, Josefina T.; Chen, Laiyuan, Ethanol production from acetic acid utilizing a cobalt catalyst.
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  37. Zhou, Zhenhua; Weiner, Heiko, Hydrogenation catalysts with acidic sites.
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  45. Johnston, Victor; Sarager, Lincoln; Scates, Mark; Shaver, Ronald David; Torrence, G. Paull; Warner, R. Jay; Weiner, Heiko; Horton, Trinity; Jevtic, Radmila; Zink, James; Lee, David, Integrated process for producing alcohols from a mixed acid feed.
  46. Scates, Mark O., Integrated process for producing polyvinyl alcohol or a copolymer thereof and ethanol.
  47. Johnston, Victor J.; Zink, James H.; Repman, Deborah R.; Kimmich, Barbara F.; Chapman, Josefina T.; Chen, Laiyuan, Integrated process for the production of vinyl acetate from acetic acid via ethyl acetate.
  48. Zhou,Bing; Rueter,Michael, Intermediate precursor compositions used to make supported catalysts having a controlled coordination structure and methods for preparing such compositions.
  49. Jevtic, Radmila; Johnston, Victor; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko; Horton, Trinity, Liquid esterification for the production of alcohols.
  50. Reyes,Clementine; Zhou,Bing, Low temperature preparation of supported nanoparticle catalysts having increased dispersion.
  51. Rueter, Michael A.; Parasher, Sukesh; Zhang, Cheng; Zhou, Bing, Method for manufacturing supported nanocatalysts having an acid-functionalized support.
  52. Zhou, Bing; Parasher, Sukesh; Rueter, Michael, Method of manufacturing multicomponent nanoparticles.
  53. Zhou, Zhenhua; Wu, Zhihua; Zhang, Cheng; Zhou, Bing, Methods for manufacturing bi-metallic catalysts having a controlled crystal face exposure.
  54. Zhou, Bing; Parasher, Sukesh; Rueter, Michael, Multicomponent nanoparticles formed using a dispersing agent.
  55. Zhou, Zhenhua; Weiner, Heiko; Wollrab, Radmila, Multifunctional hydrogenation catalysts.
  56. Wollrab, Radmila; Johnston, Victor, Multiple vapor feeds for hydrogenation process to produce alcohol.
  57. Parasher,Sukesh; Rueter,Michael; Zhou,Bing, Nanocatalyst anchored onto acid functionalized solid support and methods of making and using same.
  58. Johnston, Victor J.; Kimmich, Barbara; Potts, John; Weiner, Heiko; Zink, James H.; Chapman, Josefina T.; Chen, Laiyuan; Jevtic, Radmila, Palladium catalysts for making ethanol from acetic acid.
  59. He, Ting; Kreidler, Eric Rolland; Nomura, Tadashi; Minor, Lara, Platinum and tungsten containing electrocatalysts.
  60. He, Ting; Kreidler, Eric Rolland, Platinum, tungsten and nickel containing electrocatalysts.
  61. He,Ting; Kreidler,Eric Rolland, Platinum, tungsten, and nickel or zirconium containing electrocatalysts.
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  65. Weiner, Heiko; Jevtic, Radmila; Johnston, Victor J., Process for making diethyl ether from acetic acid.
  66. Jevtic, Radmila; Johnston, Victor J.; Warner, R. Jay; Weiner, Heiko, Process for making ethanol from acetic acid using acidic catalysts.
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  68. Horton, Trinity; Jevtic, Radmila; Johnston, Victor J.; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko, Process for producing a water stream from ethanol production.
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  73. Jevtic, Radmila; Johnston, Victor J.; Lee, David; Weiner, Heiko; Zhou, Zhenhua, Process for producing ethanol using a molar excess of hydrogen.
  74. Weiner, Heiko; Zhou, Zhenhua; Jevtic, Radmila; Johnston, Victor J., Process for producing ethanol using a stacked bed reactor.
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  76. Warner, R. Jay; Wollrab, Radmila; Amleh, Wael; Grusendorf, Gerald; Hale, Trinity Horton; Johnston, Victor J.; Olsson, Fred Ronaold; Powell, Nathan Kirk; Salado, Manuel; Sarager, Lincoln, Process for producing ethanol using an extractive distillation column.
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  78. Weiner, Heiko; Zhou, Zhenhua; Jevtic, Radmila; Johnston, Victor J., Process for producing ethanol using multiple beds each having different catalysts.
  79. Weiner, Heiko; Zhou, Zhenhua; Jevtic, Radmila; Johnston, Victor J., Process for production of ethanol using a mixed feed using copper containing catalyst.
  80. Wollrab, Radmila; Zhou, Zhenhua; Johnston, Victor J.; Lee, David; Weiner, Heiko, Process for promoting catalyst activity for ethyl acetate conversion.
  81. Jevtic, Radmila; Johnston, Victor J.; Warner, R. Jay; Weiner, Heiko; Bower, Nathan; Chapman, Josefina T.; Grusendorf, Gerald, Process for purifying ethanol.
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  84. Jevtic, Radmila; Johnston, Victor J.; Pan, Tianshu; Warner, R. Jay; Weiner, Heiko; Chapman, Josefina T., Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water.
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  89. Jevtic, Radmila; Johnston, Victor J.; Warner, R. Jay; Potts, John; Kerlegon, Stephen, Process for recycling gas from acetic acid hydrogenation.
  90. Lee, David; Orosco, Adam; Powell, Nathan; Salado, Manuel; Sarager, Lincoln; Warner, R. Jay; Horton, Trinity; Jevtic, Radmila; Johnston, Victor J., Process for removing water from alcohol mixtures.
  91. Warner, R. Jay; Weiner, Heiko; Bower, Nathan; Chapman, Josefina T.; Grusendorf, Gerald; Jevtic, Radmila; Johnston, Victor J., Process for separating acetaldehyde from ethanol-containing mixtures.
  92. Zhou, Zhenhua; Franjkic, Iva; Jevtic, Radmila; Johnston, Victor J.; Lee, David; Weiner, Heiko, Process for the production of ethanol from an acetic acid feed and a recycled ethyl acetate feed.
  93. Hale, Trinity Horton; Wollrab, Radmila; Johnston, Victor J.; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko, Process for utilizing a water stream in a hydrolysis reaction to form ethanol.
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  95. Weiner, Heiko; Wollrab, Radmila; Johnston, Victor J.; Potts, John L., Process for vapor phase hydrogenation.
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