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Additive for the hydroconversion of a heavy hydrocarbon oil

국가/구분 United States(US) Patent 등록
국제특허분류(IPC7판) B01J-031/34    B01J-027/051    B01J-021/18    C10G-047/26   
미국특허분류(USC) 502/150 ; 208/108 ; 208/110 ; 208/112
출원번호 US-0131437 (1987-12-11)
우선권정보 JP-0294980 (1986-12-12)
발명자 / 주소
출원인 / 주소
인용정보 피인용 횟수 : 32  인용 특허 : 18
초록

There is provided an additive for the hydroconversion of a heavy hydrocarbon oil, which is obtained by suspending a fine powder of a carbonaceous substance and a solution of a heteropolymolybdic acid and/or transition metal salts thereof in a hydrocarbon oil. By the use of the additive of the present invention, the hydroconversion of a heavy hydrocarbon oil can be effectively performed at high conversion without occurrence of coking.

대표
청구항
▼

An additive for the hydroconversion of a heavy hydrocarbon oil, which is obtained by a process comprising suspending in a hydrocarbon oil: (i) a carbon black having an average particle size of from about 1 to 200 nm, and (ii) a solution comprising at least one molybdenum compound selected from the group consisting of a heteropolyacid containing a molybdenum atom as a polyatom and a transition metal salt thereof, dissolved in an oxygen-containing polar solvent, thereby obtaining a suspension, wherein the weight amount of said molybdenum compound calculate...

이 특허에 인용된 특허 (18)

  1. Bearden ; Jr. Roby (Baton Rouge LA) Aldridge Clyde L. (Baton Rouge LA). Catalysts and hydrocarbon treating processes utilizing the same. USP1982114357229.
  2. Metrailer William J. (Baton Rouge LA) Bearden ; Jr. Roby (Baton Rouge LA) Aldridge Clyde L. (Baton Rouge LA). Combination hydroconversion, fluid coking and gasification. USP1979094169038.
  3. Sasaki Yoshiyuki (Yatabe JPX) Nakamura Etsuro (Ushiku JPX) Ojima Yoshimoto (Nagareyama JPX) Kondo Teruo (Tsuchiura JPX) Ukegawa Koji (Sakura JPX) Matsumura Akimitsu (Noda JPX). Hydroconversion of heavy hydrocarbon oils. USP1983094406772.
  4. Bearden ; Jr. Roby (Baton Rouge LA) Aldridge Clyde L. (Baton Rouge LA). Hydroconversion of heavy hydrocarbons. USP1979014134825.
  5. Bearden, Jr., Roby; Aldridge, Clyde L.. Hydroconversion process. USP1985124557822.
  6. Bearden, Jr., Roby; Aldridge, Clyde L.. Hydroconversion process. USP1985104548700.
  7. Ranganathan Ramaswami (Ottawa CAX) Denis Jean-Marie D. (Munster CAX) Pruden Barry B. (Ottawa CAX). Hydrocracking of heavy oils using iron coal catalyst. USP1980074214977.
  8. Khulbe Chandra P. (700 Bathgate Dr. ; #195 Ottawa ; Ontario CAX) Ranganathan Ramaswami (309-210 Woodridge Crescent Ottawa ; Ontario CAX) Pruden Barry B. (32 Dalcastle Way ; N.W. Calgary ; Alberta CAX. Hydrocracking of heavy oils/fly ash slurries. USP1981114299685.
  9. Bearden ; Jr. Roby (Baton Rouge LA) Aldridge Clyde L. (Baton Rouge LA). Hydrocracking with aqueous phosphomolybdic acid. USP1987014637871.
  10. Bearden ; Jr. Roby (Baton Rouge LA) Aldridge Clyde L. (Baton Rouge LA). Hydrocracking with phosphomolybdic acid and phosphoric acid. USP1987014637870.
  11. Dahlberg Arthur J. (Rodeo CA) Shinn John H. (Richmond CA) Rosenthal Joel W. (El Cerrito CA) Chu Tim T. (Oakland CA). Hydroprocessing of heavy hydrocarbonaceous oils. USP1983034376037.
  12. Helmer John C. (Menlo Park CA). Magnetron sputter device having planar and curved targets. USP1986084606806.
  13. Bearden ; Jr. Roby (Baton Rouge LA) Aldridge Clyde L. (Baton Rouge LA) Mayer Francis X. (Baton Rouge LA) Taylor James H. (Baton Rouge LA) Lewis William E. (Baton Rouge LA). Method of preparing a hydroconversion sulfided molybdenum catalyst concentrate. USP1988044740489.
  14. Budahn Peter (Ellerhoop DEX) Ehlers Jrn (Uetersen DEX). Preparation of catalysts by the precipitation of a hydroxide or sulfide from an emulsion in the presence of carbonaceous. USP1985014495306.
  15. Ohtake Nobumitsu (Setagaya JPX) Kuri Koji (Fuji JPX). Process for converting heavy hydrocarbon into more valuable product. USP1988094770764.
  16. Jacquin Yves (Sevres FRX) Davidson Michel (Levesinet FRX) Le Page Jean-Francois (Rueil Malmaison FRX). Process for hydrotreating heavy hydrocarbons in liquid phase in the presence of a dispersed catalyst. USP1981084285804.
  17. Giuliani Pierre (Grenoble FRX) Jacquin Yves (Sevres FRX) Busson Christian (Tassin la Demi-Lune FRX) Josserand Jean-Francois (Grenoble FRX). Process for the catalytic hydroconversion of heavy hydrocarbons in liquid phase in the presence of a dispersed catalyst. USP1984024431520.
  18. Dahlberg Arthur J. (Rodeo CA) Shinn John H. (Richmond CA) Rosenthal Joel W. (El Cerrito CA) Chu Tim T. (Oakland CA). Two-step hydroprocessing of heavy hydrocarbonaceous oils. USP1983064389301.

이 특허를 인용한 특허 피인용횟수: 32

  1. Canelon, Carlos; Rivas, Angel; Delgado, Omayra; Paiva, Miguel; Di Sarli, Giuseppe; Zacarias, Luis. Additive for hydroconversion process and method for making and using same. USP2015109168506.
  2. Canelon, Carlos; Rivas, Angel; Delgado, Omayra; Paiva, Miguel; Di Sarli, Giuseppe; Zacaris, Luis. Additive for hydroconversion process and method for making and using same. USP2014098835351.
  3. Harris, Everette; Gendler, Jeffrey. Apparatus and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking. USP2018059969946.
  4. Wu, Zhihua; Zhou, Zhenhua; Zhou, Bing. Catalyst and method for hydrodesulfurization of hydrocarbons. USP2012018097149.
  5. Harle,Virginie; Martin,Catherine; Payen,Edmond; Lamonier,Carole; Blanchard,Pascal. Catalyst based on a group VI metal and a group VIII metal at least partially present in the form of heteropolyanions in the oxide precursor. USP2007027179366.
  6. Vanderspurt, Thomas; Cordatos, Harry. Catalytic treatment of fuel to impart coking resistance. USP2010067744827.
  7. Johnson, Axel R.; Brown, Elmo C.. Combination process for the pretreatment and hydroconversion of heavy residual oils. USP1994065320741.
  8. Cayton Roger H. ; Fisher Ronald B. ; Miller Jeffrey T. ; Waynick John A.. Fluid hydrocracking catalyst precursor and method. USP1999095954945.
  9. Cayton Roger H. ; Fisher Ronald B. ; Miller Jeffrey T. ; Waynick John A.. Fluid hydrocracking catalyst precursor and method. USP2001086274530.
  10. Lopez Jaime (Benicia CA) Pasek Eugene A. (Export PA). Heavy oil hydroprocessing with group VI metal slurry catalyst. USP1990114970190.
  11. Qiu, He; Zhou, Bing. Highly stable hydrocarbon-soluble molybdenum catalyst precursors and methods for making same. USP2016089403153.
  12. Wu, Zhihua; Zhou, Zhenhua; Zhou, Bing. Hydrocarbon-soluble molybdenum catalyst precursors and methods for making same. USP2010037670984.
  13. Wu, Zhihua; Zhou, Zhenhua; Zhou, Bing. Hydrocarbon-soluble molybdenum catalyst precursors and methods for making same. USP2013058445399.
  14. Zhou, Bing; Zhou, Zhenhua; Wu, Zhihua. Hydrocarbon-soluble, bimetallic catalyst precursors and methods for making same. USP2010117842635.
  15. Marzin, Roger; Solari, Bruno; Zacarias, Luis. Hydroconversion process for heavy and extra heavy oils and residuals. USP2014038679322.
  16. Gupta Ramesh ; Ellis Edward S. ; Lewis William Ernest. Hydroprocessing of petroleum fractions with a dual catalyst system. USP1999025871635.
  17. Lott, Roger K.; Lee, Lap-Keung. Method for efficiently operating an ebbulated bed reactor and an efficient ebbulated bed reactor. USP2014038673130.
  18. Lott, Roger K.; Lee, Lap Keung. Method for upgrading ebullated bed reactor and upgraded ebullated bed reactor. USP2018039920261.
  19. Lott, Roger K.; Lee, Lap Keung. Methods and systems for hydrocracking a heavy oil feedstock using an in situ colloidal or molecular catalyst. USP2013058440071.
  20. Harris, Everette; Gendler, Jeffrey. Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking. USP2017059644157.
  21. Lott, Roger K.; Lee, Lap-Keung. Methods for hydrocracking a heavy oil feedstock using an in situ colloidal or molecular catalyst and recycling the colloidal or molecular catalyst. USP2012118303802.
  22. Lott, Roger K.; Lee, Lap-Keung. Methods for hydrocracking a heavy oil feedstock using an in situ colloidal or molecular catalyst and recycling the colloidal or molecular catalyst. USP2013048431016.
  23. Chang, Yu-Hwa. Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker. USP2017109790440.
  24. Lott, Roger K.; Chang, Yu-Hwa. Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker. USP2013108557105.
  25. Lott, Roger K.; Chang, Yu-Hwa. Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker. USP2011108034232.
  26. Pedro Pereira VE; Jose Guitian VE; Jose Cordova VE; Ramon Salazar VE; Monsaris Pimentel VE; Alice Dupatrocinio VE. Oil soluble coking additive, and method for making and using same. USP2002026344429.
  27. Zhou, Bing; Zhou, Zhenhua; Wu, Zhihua. Process for increasing the mono-aromatic content of polynuclear-aromatic-containing feedstocks. USP2012038142645.
  28. Miller Jeffrey T. ; Fisher Ronald B. ; Marshbanks Tracy L.. Resid hydroprocessing method utilizing a metal-impregnated, carbonaceous particle catalyst. USP1999095951849.
  29. Wittenbrink, Robert Jay; Bauman, Richard Frank; Berlowitz, Paul Joseph; Cook, Bruce Randall. Synthetic diesel fuel and process for its production (law3 1 1). USP2003086607568.
  30. Wittenbrink, Robert J.; Berlowitz, Paul J; Cook, Bruce R.. Synthetic jet fuel and process for its production (law724). USP2003126669743.
  31. Lott, Roger K.; Lee, Lap-Keung. Systems and methods for hydroprocessing heavy oil. USP20181110118146.
  32. Lott, Roger K.; Lee, Lap Keung. Systems for hydroprocessing heavy oil. USP2017039605215.

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