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In a laminated material comprising a polyolefin-based film bonded to a metal sheet (M), the polyolefin-based film is a multi-layer co-extruded film comprising an inner layer (B2) of a bonding resin which is an acid-modified polyolefin resin containing carboxyl or anhydride groups and an outer layer

In a laminated material comprising a polyolefin-based film bonded to a metal sheet (M), the polyolefin-based film is a multi-layer co-extruded film comprising an inner layer (B2) of a bonding resin which is an acid-modified polyolefin resin containing carboxyl or anhydride groups and an outer layer (B1) of a polyolefin or polyamide containing 0.15% to 0.5% by weight of a finely divided non-reactive low-opacity synthetic silica having an average particle size on the range 0.5 to 5 microns. Another thermoplastic film (A1,A2), such as a biaxially oriented polyester film, may be simultaneously laminated to the other surface of the metal sheet. The lamination process involves heating the laminated material to effect bonding and then quenching the laminated material rapidly and uniformly from above the melting point of the polyolefin to below its softening point. The laminated material may be used in the formation of can ends and can bodies, which can be double seamed together without fibrillation of the polyolefin-based coating.

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A laminated material comprising a polyolefin based film bonded to one major surface of a metal sheet, characterised in that the polyolefin-based film is a multi-layer co-extruded film comprising an inner layer of a bonding resin which is an acid-modified polyolefin resin containing carboxyl or anhyd

A laminated material comprising a polyolefin based film bonded to one major surface of a metal sheet, characterised in that the polyolefin-based film is a multi-layer co-extruded film comprising an inner layer of a bonding resin which is an acid-modified polyolefin resin containing carboxyl or anhydride groups and an outer layer of a polyolefin or a polyamide containing 0.15% to 0.5% by weight of a finely divided non-reactive low-opacity synthetic silica having an average particle size in the range of 0.5 to 5 microns.