국가/구분 |
United States(US) Patent
등록
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국제특허분류(IPC7판) |
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출원번호 |
US-0734407
(1991-07-23)
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발명자
/ 주소 |
- Rao V. N. M. (Wilmington DE)
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출원인 / 주소 |
- E. I. Du Pont de Nemours and Company (Wilmington DE 02)
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인용정보 |
피인용 횟수 :
43 인용 특허 :
0 |
초록
▼
Catalytic hydrogenolysis of fluorohalocarbons (e.g., CFCs) and fluorohalohydrocarbons (e.g., HCFCs), using catalysts of Re, Co, Ni, Ru, Rh, Pd, Os, Ir, and/or Pt on a carbon having low ash content. Preferred catalysts use carbon which is acid-washed, first with an acid other than hydrofluoric acid a
Catalytic hydrogenolysis of fluorohalocarbons (e.g., CFCs) and fluorohalohydrocarbons (e.g., HCFCs), using catalysts of Re, Co, Ni, Ru, Rh, Pd, Os, Ir, and/or Pt on a carbon having low ash content. Preferred catalysts use carbon which is acid-washed, first with an acid other than hydrofluoric acid and then with hydrofluoric acid; and also have a low content of phosphorus, sulfur, potassium, sodium and iron.
대표청구항
▼
A process for the catalytic hydrogenolysis of a cyclic or acyclic compound having the formula CnHmFpXq wherein n is an integer from 1 to 6, m is an integer from 0 to 12, p is an integer from 1 to 13, q is an integer from 1 to 13 and each X is independently selected from Cl and Br, provided that m+p+
A process for the catalytic hydrogenolysis of a cyclic or acyclic compound having the formula CnHmFpXq wherein n is an integer from 1 to 6, m is an integer from 0 to 12, p is an integer from 1 to 13, q is an integer from 1 to 13 and each X is independently selected from Cl and Br, provided that m+p+q equals 2n+2 when the compound is saturated and acyclic, equals 2n when the compound is saturated and cyclic or is olefinic and acyclic, and equals 2n-2 when the compound is olefinic and cyclic, using a catalyst of at least one metal selected from the group consisting of rhenium, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium and platinum supported on carbon which is characterized by the carbon support having an ash content of less than about 0.1 percent by weight.
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