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Kafe 바로가기국가/구분 | United States(US) Patent 등록 |
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국제특허분류(IPC7판) |
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출원번호 | US-0496378 (1990-03-20) |
발명자 / 주소 |
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출원인 / 주소 |
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인용정보 | 피인용 횟수 : 436 인용 특허 : 0 |
This invention relates to catalyst systems, and a method for using such system, for the enhanced production of homo and copolymer products of olefin, diolefin and/or acetylenically unsaturated monomers. This invention catalyst system comprises a Group III-A element compound for improving the product
This invention relates to catalyst systems, and a method for using such system, for the enhanced production of homo and copolymer products of olefin, diolefin and/or acetylenically unsaturated monomers. This invention catalyst system comprises a Group III-A element compound for improving the productivity of an olefin polymerization catalyst which is the reaction product of a metallocene of a Group IV-B transition metal and an ionic activator compound comprising a cation capable of donating a proton or which will irreversibly react with at least one ligand contained in the Group IV-B metal compound and an anion which is bulky, labile and noncoordinateable with the Group IV transition metal cation produced upon reaction of the metallocene and activator compound to form the catalyst component of the catalyst system.
A catalyst system comprising (a) a reaction product of (i) a bis(cyclopentadienyl) Group IV B metal compound; and (ii) a activator compound comprising (1) a cation, which will irreversibly react with at least one ligand contained in said Group IV B metal compound, and (2) a labile, bulky anion which
A catalyst system comprising (a) a reaction product of (i) a bis(cyclopentadienyl) Group IV B metal compound; and (ii) a activator compound comprising (1) a cation, which will irreversibly react with at least one ligand contained in said Group IV B metal compound, and (2) a labile, bulky anion which is a single coordination complex having a plurality of lipophilic radicals covalently coordinated to and shielding a central charge-bearing metal or metalloid atom, or an anion comprising a plurality of boron atoms the bulk of said anion being such that upon reaction of the cation with a ligand of said bis(cyclopentadienyl) Group IV B metal compound whereby a Group IV-B metal cation is formed said anion is sterically hindered from covalently coordinating o the Group IV-B metal cation, and the lability of said anion being such that it is displaceable from said group IV-B metal cation by an unsaturated hydrocarbon having a Lewis base strength equal to or greater than ethylene; and (b) an organometallic additive compound.
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