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Supported catalysts and a process for their preparation 원문보기

IPC분류정보
국가/구분 United States(US) Patent 등록
국제특허분류(IPC7판)
  • B01J-021/14
  • B01J-023/74
  • B01J-037/02
출원번호 US-0743193 (1991-08-09)
우선권정보 DE-4025525 (1990-08-11)
발명자 / 주소
  • Horn Gerhardt (Oberhausen DEX) Frohning Carl D. (Wesel DEX)
출원인 / 주소
  • Hoechst Aktiengesellschaft (DEX 03)
인용정보 피인용 횟수 : 73  인용 특허 : 0

초록 ▼

Supported catalysts containing nickel, magnesium oxide and, if desired, further additives, which contain reduced Mg and Ni in a molar ratio of (0.0075 to 0.075):1. The catalyst also have an active nickel metal surface area of 110 to 180 m2/g of Ni, and a BET total surface area of 160 to 450 m2/g. Th

대표청구항 ▼

A catalyst in reduced form containing Mg and Ni in a molar ratio of (0.0075 to 0.075): 1, and a water-insoluble support in an amount of 17.0 to 60.0 grams of support per mol of Ni, wherein active nickel metal surface area is 110 to 180 m2/g of Ni, and 65 to 97% of a BET total surface area is formed

이 특허를 인용한 특허 (73)

  1. Zhou, Zhenhua; Johnston, Victor J.; Weiner, Heiko, Acetic acid hydrogenation over a group VIII metal calcined catalyst having a secondary promoter.
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  2. Jevtic, Radmila; Johnston, Victor J.; Pan, Tianshu; Scates, Mark O.; Shaver, Ronald David; Warner, R. Jay; Weiner, Heiko; Chapman, Josefina T., Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process.
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  3. Zhou, Zhenhua; Johnston, Victor J.; Weiner, Heiko, Bismuth catalyst composition and process for manufacturing ethanol mixture.
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  4. Weiner, Heiko; Zhou, Zhenhua; Johnston, Victor J., Calcination of modified support to prepare hydrogenation catalysts.
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  5. Weiner, Heiko; Zhou, Zhenhua; Jevtic, Radmila; Johnston, Victor J., Catalyst having support containing tin and process for manufacturing ethanol.
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  6. Weiner, Heiko; Johnston, Victor J., Catalyst supports having crystalline support modifiers.
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  7. Johnston, Victor J.; Chen, Laiyuan; Kimmich, Barbara F.; Chapman, Josefina T.; Zink, James H.; Weiner, Heiko; Potts, John L.; Jevtic, Radmila, Catalysts for making ethanol from acetic acid.
    상세보기
  8. Johnston, Victor J.; Kimmich, Barbara F.; Potts, John L.; Weiner, Heiko; Wollrab, Radmila; Zink, James H.; Chapman, Josefina T.; Chen, Laiyuan, Catalysts for making ethanol from acetic acid.
    상세보기
  9. Zhou, Zhenhua; Johnston, Victor; Weiner, Heiko; Wollrab, Radmila, Catalysts having promoter metals and process for producing ethanol.
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  10. Zhou, Zhenhua; Weiner, Heiko; Kumar, Dheeraj; Tu, Xiaoyan; Johnston, Victor J.; Jevtic, Radmila, Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol.
    상세보기
  11. Zhou, Zhenhua; Johnston, Victor; Weiner, Heiko, Cobalt and tin catalysts for producing ethanol.
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  12. Zhou, Zhenhua; Weiner, Heiko, Cobalt and tin hydrogenation catalysts.
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  13. Weiner, Heiko; Zhou, Zhenhua; Jevtic, Radmila; Johnston, Victor J., Cobalt/tin catalyst for producing ethanol.
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  14. Johnston, Victor; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko; Gruesendorf, Gerald; Horton, Trinity; Jevtic, Radmila, Denatured fuel ethanol compositions for blending with gasoline or diesel fuel for use as motor fuels.
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  15. Johnston, Victor J.; Chen, Laiyuan; Kimmich, Barbara F.; Chapman, Josefina T.; Zink, James H., Direct and selective production of ethanol from acetic acid utilizing a platinum/ tin catalyst.
    상세보기
  16. Johnston, Victor J.; Chen, Laiyuan; Kimmich, Barbara F.; Chapman, Josefina T.; Zink, James H., Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst.
    상세보기
  17. Johnston, Victor J.; Zink, James H.; Repman, Deborah R.; Chen, Laiyuan; Kimmich, Barbara F.; Chapman, Josefina T.; van der Waal, Jan Cornelis; Zuzaniuk, Virginie, Direct and selective production of ethyl acetate from acetic acid utilizing a bimetal supported catalyst.
    상세보기
  18. Horton, Trinity; Jevtic, Radmila; Johnston, Victor J.; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko, Ethanol compositions.
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  19. Johnston, Victor; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko; Horton, Trinity; Jevtic, Radmila, Ethanol compositions.
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  20. Zhou, Zhenhua; Duff, Emily; Kumar, Dheeraj; Weiner, Heiko, Ethanol manufacturing process over catalyst having improved radial crush strength.
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  21. Zhou, Zhenhua; Duff, Emily; Kumar, Dheeraj; Weiner, Heiko, Ethanol manufacturing process over catalyst having improved radial crush strength.
    상세보기
  22. Johnston, Victor J.; Kimmich, Barbara F.; van der Waal, Jan Cornelis; Zink, James H.; Zuzaniuk, Virginie; Chapman, Josefina T.; Chen, Laiyuan, Ethanol production from acetic acid utilizing a cobalt catalyst.
    상세보기
  23. Johnston, Victor J.; Kimmich, Barbara F.; van der Waal, Jan Cornelis; Zink, James H.; Zuzaniuk, Virginie; Chapman, Josefina T.; Chen, Laiyuan, Ethanol production from acetic acid utilizing a cobalt catalyst.
    상세보기
  24. Johnston, Victor J.; Kimmich, Barbara F.; van der Waal, Jan Cornelis; Zink, James H.; Zuzaniuk, Virginie; Chapman, Josefina T.; Chen, Laiyuan, Ethanol production from acetic acid utilizing a cobalt catalyst.
    상세보기
  25. Johnston, Victor J.; Kimmich, Barbara F.; van der Waal, Jan Cornelis; Zink, James H.; Zuzaniuk, Virginie; Chapman, Josefina T.; Chen, Laiyuan, Ethanol production from acetic acid utilizing a molybdenum carbide catalyst.
    상세보기
  26. Horton, Trinity; Jevtic, Radmila; Johnston, Victor J.; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko; Grusendorf, Gerald, Ethanol/fuel blends for use as motor fuels.
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  27. Dath,Jean Pierre; Vermeiren,Walter, Hydrogenation and dehydrogenation processes and catalysts therefor.
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  28. Zhou, Zhenhua; Johnston, Victor; Kumar, Dheeraj; Tu, Xiaoyan; Weiner, Heiko; Wollrab, Radmila, Hydrogenation catalysts.
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  29. Weiner, Heiko; Zhou, Zhenhua; Johnston, Victor J., Hydrogenation catalysts having an amorphous support.
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  30. Weiner, Heiko; Zhou, Zhenhua, Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol while minimizing diethyl ether formation.
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  31. Wollrab, Radmila; Johnston, Victor J.; Weiner, Heiko, Hydrogenation reaction conditions for producing ethanol.
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  32. Johnston, Victor; Sarager, Lincoln; Scates, Mark; Shaver, Ronald David; Torrence, G. Paull; Warner, R. Jay; Weiner, Heiko; Horton, Trinity; Jevtic, Radmila; Zink, James; Lee, David, Integrated process for producing alcohols from a mixed acid feed.
    상세보기
  33. Scates, Mark O., Integrated process for producing polyvinyl alcohol or a copolymer thereof and ethanol.
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  34. Johnston, Victor J.; Zink, James H.; Chen, Laiyuan; Kimmich, Barbara F.; Chapman, Josefina T., Integrated process for the production of vinyl acetate from acetic acid via acetaldehyde.
    상세보기
  35. Johnston, Victor J.; Zink, James H.; Repman, Deborah R.; Kimmich, Barbara F.; Chapman, Josefina T.; Chen, Laiyuan, Integrated process for the production of vinyl acetate from acetic acid via ethyl acetate.
    상세보기
  36. Johnston, Victor J.; Kimmich, Barbara; Potts, John; Weiner, Heiko; Zink, James H.; Chapman, Josefina T.; Chen, Laiyuan; Jevtic, Radmila, Palladium catalysts for making ethanol from acetic acid.
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  37. Dath,Jean Pierre; Vermeiren,Walter, Polymer hydrogenation process.
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  38. Weiner, Heiko; Jevtic, Radmila; Johnston, Victor J., Process for making diethyl ether from acetic acid.
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  39. Jevtic, Radmila; Johnston, Victor J.; Warner, R. Jay; Weiner, Heiko, Process for making ethanol from acetic acid using acidic catalysts.
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  40. Wollrab, Radmila; Johnston, Victor J.; Warner, R. Jay; Weiner, Heiko, Process for making ethanol from acetic acid using acidic catalysts.
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  41. Horton, Trinity; Jevtic, Radmila; Johnston, Victor J.; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko, Process for producing a water stream from ethanol production.
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  42. Horton, Trinity; Jevtic, Radmila; Johnston, Victor J.; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko, Process for producing a water stream from ethanol production.
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  43. Zhou, Zhenhua; Jevtic, Radmila; Johnston, Victor J.; Weiner, Heiko, Process for producing ethanol over catalysts containing platinum and palladium.
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  44. Zhou, Zhenhua; Johnston, Victor J.; Kumar, Dheeraj; Tu, Xiaoyan; Weiner, Heiko; Wollrab, Radmila, Process for producing ethanol using hydrogenation catalysts.
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  45. Wollrab, Radmila; Zhou, Zhenhua; Johnston, Victor J.; Lee, David; Weiner, Heiko, Process for promoting catalyst activity for ethyl acetate conversion.
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  46. Jevtic, Radmila; Johnston, Victor J.; Warner, R. Jay; Weiner, Heiko; Bower, Nathan; Chapman, Josefina T.; Grusendorf, Gerald, Process for purifying ethanol.
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  47. Johnston, Victor J.; Pan, Tianshu; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko; Chapman, Josefina; Cunningham, Robert; Grusendorf, Gerald; Horton, Trinity; Jevtic, Radmila, Process for purifying ethanol.
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  48. Wollrab, Radmila; Bower, Nathan; Chapman, Josefina T.; Grusendorf, Gerald; Johnston, Victor J.; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko, Process for purifying ethanol.
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  49. Jevtic, Radmila; Johnston, Victor J.; Pan, Tianshu; Warner, R. Jay; Weiner, Heiko; Chapman, Josefina T., Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water.
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  50. Jevtic, Radmila; Johnston, Victor J.; Pan, Tianshu; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko; Chapman, Josefina; Cunningham, Robert; Grusendorf, Gerald; Horton, Trinity, Process for recovering ethanol.
    상세보기
  51. Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko; Wollrab, Radmila; Chapman, Josefina T.; Cunningham, Robert; Grusendorf, Gerald; Hale, Trinity Horton; Johnston, Victor J.; Pan, Tianshu, Process for recovering ethanol.
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  52. Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko; Wollrab, Radmila; Chapman, Josefina T.; Cunningham, Robert; Grusendorf, Gerald; Hale, Trinity Horton; Johnston, Victor J.; Pan, Tianshu, Process for recovering ethanol.
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  53. Sarager, Lincoln; Warner, R. Jay; Chapman, Josefina T.; Cunningham, Robert; Horton, Trinity; Jevtic, Radmila; Johnston, Victor J.; Pan, Tianshu, Process for recovering ethanol with vapor separation.
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  54. Warner, R. Jay; Weiner, Heiko; Bower, Nathan; Chapman, Josefina T.; Grusendorf, Gerald; Jevtic, Radmila; Johnston, Victor J., Process for separating acetaldehyde from ethanol-containing mixtures.
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  55. Hale, Trinity Horton; Wollrab, Radmila; Johnston, Victor J.; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko, Process for utilizing a water stream in a hydrolysis reaction to form ethanol.
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  56. Weiner, Heiko; Wollrab, Radmila; Johnston, Victor J.; Potts, John L., Process for vapor phase hydrogenation.
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  57. Weiner, Heiko; Wollrab, Radmila; Johnston, Victor J.; Potts, John L., Process for vapor phase hydrogenation.
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  58. Jevtic, Radmila; Johnston, Victor; Weiner, Heiko; Zhou, Zhenhua, Processes for hydrogenating alkanoic acids using catalyst comprising tungsten.
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  59. Johnston, Victor J.; Chen, Laiyuan; Kimmich, Barbara F.; Chapman, Josefina T.; Zink, James H.; Weiner, Heiko; Potts, John L.; Jevtic, Radmila, Processes for making ethanol from acetic acid.
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  60. Johnston, Victor J.; Chen, Laiyuan; Kimmich, Barbara F.; Chapman, Josefina T.; Zink, James H.; Weiner, Heiko; Potts, John L.; Wollrab, Radmilla, Processes for making ethanol from acetic acid.
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  61. Johnston, Victor J.; Chen, Laiyuan; Kimmich, Barbara F.; Chapman, Josefina T.; Zink, James H.; Weiner, Heiko; Potts, John L.; Jevtic, Radmila, Processes for making ethanol from acetic acid using bimetallic catalysts.
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  62. Johnston, Victor J.; Chen, Laiyuan; Kimmich, Barbara F.; Chapman, Josefina T.; Zink, James H.; Weiner, Heiko; Potts, John L.; Jevtic, Radmila, Processes for making ethyl acetate from acetic acid.
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  63. Weiner, Heiko; Jevtic, Radmila; Johnston, Victor, Processes for making tin-containing catalysts.
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  64. Weiner, Heiko; Johnston, Victor J.; Jevtic, Radmila, Processes for making tin-containing catalysts.
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  65. Hale, Trinity Horton; Wollrab, Radmila; Johnston, Victor J.; Sarager, Lincoln; Warner, R. Jay; Grusendorf, Gerald, Processes for producing anhydrous ethanol compositions.
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  66. Horton, Trinity; Jevtic, Radmila; Johnston, Victor J.; Sarager, Lincoln; Warner, R. Jay; Grusendorf, Gerald, Processes for producing anhydrous ethanol compositions.
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  67. Johnston, Victor J.; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko; Horton, Trinity; Jevtic, Radmila, Processes for producing denatured ethanol.
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  68. Jevtic, Radmila; Johnston, Victor J.; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko; Hale, Trinity Horton, Processes for producing ethanol from acetaldehyde.
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  69. Jevtic, Radmila; Johnston, Victor J.; Sarager, Lincoln; Warner, R. Jay; Weiner, Heiko; Horton, Trinity, Processes for producing ethanol from acetaldehyde.
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  70. Weiner, Heiko; Zhou, Zhenhua; Jevtic, Radmila; Johnston, Victor J., Promoters for cobalt-tin catalysts for reducing alkanoic acids.
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  71. Zhou, Zhenhua; Johnston, Victor J.; Weiner, Heiko, Rhodium/tin catalysts and processes for producing ethanol.
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  72. Johnston, Victor J.; Kimmich, Barbara F.; van der Waal, Jan Cornelis; Zink, James H.; Zuzaniuk, Virginie; Chapman, Josefina T.; Chen, Laiyuan, Synthesis of ethanol from biomass.
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  73. Weiner, Heiko; Johnston, Victor J.; Potts, John L.; Jevtic, Radmila, Tunable catalyst gas phase hydrogenation of carboxylic acids.
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