초록 ▼

The present disclosure describes flame-retardant, high-temperature resistant polyimide fibers, nonwovens made from said fibers, as well as the fibers and molded articles obtained after a heat treatment. A composite of such fibers is heated to a temperature in the glass transition range of the fiber,

The present disclosure describes flame-retardant, high-temperature resistant polyimide fibers, nonwovens made from said fibers, as well as the fibers and molded articles obtained after a heat treatment. A composite of such fibers is heated to a temperature in the glass transition range of the fiber, i.e., between 280°and 350°C. This heat treatment develops a contraction force of 0.3 to 1.1 cN in the fibers which results in a fiber shrinkage of between 20 and 60% and the formation of cohesive bonds. The fibers of the invention enable the manufacture of molded articles that are particularly strong, have a high temperature resistance and flame-retardant properties, while having a relatively low density.

대표청구항 ▼

A process for making a machineable, molded article which is flame retardant and high temperature stable comprising: a) preparing a first composition of heat-shrinkable fibers comprising i) a quantity of polyimide fibers corresponding to the formula: [Figure] in which R is selected form the group con

A process for making a machineable, molded article which is flame retardant and high temperature stable comprising: a) preparing a first composition of heat-shrinkable fibers comprising i) a quantity of polyimide fibers corresponding to the formula: [Figure] in which R is selected form the group consisting of [Figure] [Figure] and combinations thereof, said quantity of polyimide fibers being sufficient to impart flame retardant and high temperature stability properties to said composition; and ii) a solvent of said polyimide fiber and an oligomer of said polyimide fibers; b) aligning said polyimide fibers in more than one dimension; c) placing said heat-shrinkable fiber composition with aligned fibers on a shaping surface; d) preparing a second heat-shrinkable fiber composition; e) placing said second heat-shrinkable fiber composition on said first heat-shrinkable fiber composition on said shaping surface in a manner effective to abut said first and said second heat-shrinkable fiber compositions; f) applying a quantity of heat energy to said compositions on said shaping surface effective to maintain to the temperature of said polyimide fibers at about the glass transition temperature of said polyimide fibers for between 1 and 30 minutes; and g) removing the material from said shaping surface after said application of heat energy.