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A method of forming high temperature resistant coatings from a quantity of composite particles, each comprising very small magnetic particles in a ceramic matrix by plasma spraying the composite particles onto a surface. Typically, the surface to be coated is pre-treated by a combination of solvent

A method of forming high temperature resistant coatings from a quantity of composite particles, each comprising very small magnetic particles in a ceramic matrix by plasma spraying the composite particles onto a surface. Typically, the surface to be coated is pre-treated by a combination of solvent cleaning and abrasion, such as by grit blasting. In some cases the surface is coated with a thin electrically conductive transition layer having a coefficient of thermal expansion intermediate those of the surface and the composite coating. A quantity of finely divided composite particles are then prepared, each of the particles comprising a ceramic matrix containing plural spaced very small magnetic metal particles. In some cases, a small quantity of smaller pure matrix particles or lower melting particles are mixed with the composite particles to improve bonding. The composite particles are plasma sprayed onto the surface to be coated at temperatures such that only the surfaces of the composite particles are melted, thereby permitting higher magnetic material loadings without forming an excessively electrically conductive coating. The resulting coating is durable, has high temperature resistance and absorbs incident microwave energy.

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1. The method for forming a magnetic-cermet dielectric coating on substrate surfaces which comprises the steps of: cleaning the surface to be coated; preparing a quantity of finely divided composite particles having diameters from about 60 to 75 micrometers, each composite particle comprising an

1. The method for forming a magnetic-cermet dielectric coating on substrate surfaces which comprises the steps of: cleaning the surface to be coated; preparing a quantity of finely divided composite particles having diameters from about 60 to 75 micrometers, each composite particle comprising an electrically insulating ceramic matrix having a plurality of magnetic metal particles, having average diameters of from about 1 to 5 micrometers, spaced throughout the matrix, the metal particles making up from about 50 to 75 vol % of said composite particles; and plasma spraying said composite particles onto the surface to be coated at temperatures such that the composite particles are melted on their surfaces only; whereby a magnetic-ceramic dielectric layer is formed. 2. The method according to claim 1 further including the step of plasma spraying particles having substantially the same composition as said composite particles at a temperature sufficient to substantially fully melt the particles, to form a transition layer on said surface prior to spraying said dielectric layer, said transition layer having a thickness of from about 5 to 7 mils, whereby a conductive layer having a coefficient of thermal expansion intermediate those of the substrate and the dielectric coating is formed. 3. The method according to claim 1 wherein said particles used to form said transition layer have diameters of from about 10 to 45 micrometers. 4. The method according to claim 1 wherein said surface is metallic and said cleaning is accomplished by applying a degreaser to the surface, abrading the surface by directing alumina particles having diameters of from about 20 to 80 micrometers against the surface and washing the surface with a solvent that does not leave a residue. 5. The method according to claim 1 wherein said metal particles are formed from metal selected from the group consisting of iron, iron-aluminum, iron-silicon, cobalt and mixtures thereof. 6. The method according to claim 1 wherein said ceramic matrix material is selected from the group consisting of oxides of silicon, barium, aluminum, boron, calcium, strontium, potassium and mixtures thereof. 7. The method according to claim 1 wherein said ceramic matrix material consists essentially of about 45 wt % silicon dioxide, about 46 wt % barium oxide and about 9 wt % boron oxide. 8. The method according to claim 1 including the step of plasma spraying said composite particles onto the surface to form a coating having maximum microwave absorption at any frequency within the range from about 5 to 16 GHz. 9. The method according to claim 1 including the step of plasma spraying said composite particles onto the surface to form a coating having a thickness of from about 35 to 55 mils. 10. The method for forming a magnetic-ceramic dielectric coating on substrate surfaces which comprises the steps of: cleaning the surface to be coated; preparing a quantity of first finely divided composite particles having diameters from about 10 to 45 micrometers, each first composite particle comprising a first electrically insulating ceramic matrix having a plurality of first magnetic metal particles, having average diameters of from about 1 to 5 micrometers, spaced throughout the matrix, the first metal particles making up from about 50 to 75 vol % of said composite particles; plasma spraying said composite particles onto the surface to be coated at temperatures such that the composite particles are substantially completely melted to form an electrically conductive transition layer; preparing a quantity of second composite particles having diameters of from about 60 to 75 micrometers each second composite particle comprising a second electrically insulating ceramic matrix having a plurality of second magnetic metal particles, having average diameters of from about 1 to 5 micrometers, spaced throughout the matrix, the second metal particles making up from about 50 to 75 vol % of said composite particles; and plasma spraying said second composite particles onto the surface to be coated at temperatures such that the composite particles are melted on their surfaces only; whereby a magnetic-ceramic dielectric layer is formed. 11. The method according to claim 10 wherein the composition and physical characteristics, other than diameter, of said first and second composite particles are substantially the same. 12. The method according to claim 10 wherein said first and second metals are selected from the group consisting of iron, iron-aluminum, iron-silicon, cobalt and mixtures thereof. 13. The method according to claim 10 wherein said first and second ceramic matrix materials are selected from the group consisting of oxides of silicon, barium, aluminum, boron, calcium, strontium, potassium and mixtures thereof. 14. The method according to claim 10 wherein said first and second ceramic matrix materials consists essentially of about 45 wt % silicon dioxide, about 46 wt % barium oxide and about 9 wt % boron oxide. 15. The method according to claim 8 including the step of plasma spraying said second composite particles onto the surface to form a dielectric coating having maximum microwave absorption at any frequency within the range from about 5 to 16 GHz. 16. The method according to claim 10 wherein said first plasma spraying step forms a transition layer having a thickness of from about 5 and 7 micrometers and said second plasma spraying step forms a dielectric coating having a thickness of from about 35 to 55 mils.