초록 ▼

Cured cement matrices are exposed to dense-phase or supercritical CO2 which enters the matrix through passages therein to neutralize the natural alkalinity of the cement so that alkali-intolerant materials can be incorporated in the cement. The CO2 converts calcium hydroxide in the cement to calcium

Cured cement matrices are exposed to dense-phase or supercritical CO2 which enters the matrix through passages therein to neutralize the natural alkalinity of the cement so that alkali-intolerant materials can be incorporated in the cement. The CO2 converts calcium hydroxide in the cement to calcium carbonate and water, and the high pressure of the dense-phase or supercritical CO2 forms rounded, closely packed and aligned crystals with few or no visible pores or capillaries to enhance the homogeneity and strength of the cured cement and its bonding with, for example, uncoated reinforcing glass fibers. The supercritical CO2 can be used to transport other organic or inorganic materials, including pulverized metal, in solution or suspension into the interior of the cement matrix to alter its chemical and/or physical characteristics. The supercritical CO2 can further be used to quickly determine if a particular cement specimen comes from a wet cement mix to which a material has been added which prevents or hinders cement carbonation.

대표청구항 ▼

A method of ascertaining the permeability of a cured cement product formed from a cement mix with one or more additives therein by a highly pressurized fluid comprising the steps of subjecting the product to supercritical CO2 in a combined gaseous liquid phase of fluid by an infusion, diffusion or i

A method of ascertaining the permeability of a cured cement product formed from a cement mix with one or more additives therein by a highly pressurized fluid comprising the steps of subjecting the product to supercritical CO2 in a combined gaseous liquid phase of fluid by an infusion, diffusion or injection process, thereafter analyzing a cross-section of the product to determine an extent to which the supercritical CO2 penetrated into the product and caused carbonation therein, and from the extent of supercritical CO2 penetration determining if the mix from which the cement product was cured included an additive which prevented the supercritical CO2 from penetrating the product and causing carbonation of said cement product down to said extent of supercritical CO2 penetration.