초록 ▼

Thermoplastic foams are provided by a process in which a gaseous blowing agent of nitrogen, air, carbon dioxide, argon or mixtures thereof is injected into a melted thermoplastic polymer and the pressure is used to form a solution of the blowing agent and the melted polymer. The solution is cooled t

Thermoplastic foams are provided by a process in which a gaseous blowing agent of nitrogen, air, carbon dioxide, argon or mixtures thereof is injected into a melted thermoplastic polymer and the pressure is used to form a solution of the blowing agent and the melted polymer. The solution is cooled to a temperature which is within 10.degree. C. of the polymer freezing point while the pressure is held to a point within which both of the following conditions exist: A) the pressure must be high enough to keep the gas blowing agent in the solution with the melt, and B) the pressure must be low enough to avoid adding more heat to the solution. Just before the cooled solution is extruded, it is important to have the solution at a temperature which is sufficiently uniform to make: A) the thermoplastic foam at least about 65% by volume in closed cells, and B) a substantially uniform cell size in the product. The cooled solution is then extruded out of an extruder die to where the pressure drop across the die is in the range of from about 70 to about 90% of the pressure in the extruder so that a cellular product is formed.

대표청구항 ▼

[ We claim:] [1.] A process for making a cellular thermoplastic structure comprising the steps of:feeding a polymer into an extruder;melting the polymer in the extruder to form a melt;feeding a gaseous blowing agent into the extruder at a pressure which is low enough to maintain the blowing agent as

[ We claim:] [1.] A process for making a cellular thermoplastic structure comprising the steps of:feeding a polymer into an extruder;melting the polymer in the extruder to form a melt;feeding a gaseous blowing agent into the extruder at a pressure which is low enough to maintain the blowing agent as a gas, but which is high enough to at least begin to force the blowing agent to form a solution with the melt, further providing that the gaseous blowing agent is nitrogen, air, argon, carbon dioxide or mixtures thereof;increasing pressure by means of the extruder wherein the pressure is increased to at least the value thermodynamically required to force the rest of the gas blowing agent into solution with the melt;cooling the solution to form a cooled solution at a temperature which is within 10.degree. C. of the polymer solidification point while the pressure is held to a point within which both of the following conditions exist: A) the pressure must be high enough to keep the gas blowing agent in the solution with the melt, and B) the pressure must be low enough to avoid adding more heat to the solution;moving the cooled solution in a first direction along the extruder to a die where, in a second direction which is perpendicular to the first direction and is across the cooled solution, the temperature of the cooled solution in a direction transverse to the flow of the solution inside the extruder is in a temperature gradient so that before extruding, the cooled solution at a wall of the extruder is at a temperature which is within 5.degree. C. of the temperature of the polymer inside the solution: A) to allow extrusion to make a cellular product which is at least about 50% by volume in closed cells and B) to allow extrusion to make a substantially uniform cell size in the product; andextruding the cooled solution across and out of the die so that a pressure drop occurs across the die wherein said pressure drop is in the range of from about 70 to about 90% so that the cellular product is formed.