초록 ▼

A NO.sub.x abatement composition comprises a NO.sub.x abatement catalyst and a NO.sub.x sorbent material which are dispersed in proximity to, but segregated from, each other on a common refractory carrier member (10). The NO.sub.x sorbent material comprises a basic oxygenated metal compound and opti

A NO.sub.x abatement composition comprises a NO.sub.x abatement catalyst and a NO.sub.x sorbent material which are dispersed in proximity to, but segregated from, each other on a common refractory carrier member (10). The NO.sub.x sorbent material comprises a basic oxygenated metal compound and optionally further comprises ceria. The NO.sub.x abatement catalyst contains a catalytic metal component including a platinum metal catalytic component. The catalytic metal component is segregated from the NO.sub.x sorbent material, which may be one or more of metal oxides, metal carbonates, metal hydroxides and mixed metal oxides. At least the catalytic metal component and the NO.sub.x sorbent material must be on, or comprise separate, particles; the particles may either be admixed or may be disposed in separate layers (20a, 20b) on the carrier member (10). A NO.sub.x abatement method employs the composition and includes periodically adjusting the gas being treated between lean and stoichiometric/rich operating cycles.

대표청구항 ▼

[ What is claimed is:] [1.] A method of NO.sub.x abatement comprising contacting a gas stream containing NO.sub.x with a NO.sub.x abatement composition, the composition comprising a NO.sub.x abatement catalyst and a NO.sub.x sorbent material disposed in proximity to each other on a common refractory

[ What is claimed is:] [1.] A method of NO.sub.x abatement comprising contacting a gas stream containing NO.sub.x with a NO.sub.x abatement composition, the composition comprising a NO.sub.x abatement catalyst and a NO.sub.x sorbent material disposed in proximity to each other on a common refractory carrier member,(i) the NO.sub.x abatement catalyst comprising a catalytic metal component comprised of platinum and, optionally, at least one other platinum group metal catalytic component, the catalytic metal component being dispersed on a first refractory metal oxide support,(ii) the NO.sub.x sorbent material optionally being a bulk material and comprising at least one material selected from the group consisting of basic oxygenated metal compounds and, optionally, further comprising ceria, and(iii) wherein the NO.sub.x sorbent material is segregated from the catalytic metal component, at least to the extent that (a) when the NO.sub.x sorbent material is dispersed on a refractory support material, the catalytic metal component and the NO.sub.x sorbent material are not dispersed on the same increment of refractory support material, and (b) when the NO.sub.x sorbent material comprises a bulk material, the catalytic metal component is not impregnated into the bulk NO.sub.x sorbent material and providing that when the catalytic material is disposed as a first discrete layer on the carrier member a second discrete layer of NO.sub.x sorbent material comprises an overlayer superimposed on the catalytic material layer;the method including periodically adjusting the composition of the gas stream between lean and stoichiometric/rich conditions to thereby provide alternating lean operating condition periods and stoichiometric/rich operating condition periods, and maintaining NO.sub.x abatement conditions during the stoichiometric/rich operating condition periods, whereby during the lean operating periods NO.sub.x is sorbed by the NO.sub.x sorption material and during the stoichiometric/rich operating periods the NO.sub.x abatement catalyst promotes the reduction of NO.sub.x.