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특허 상세정보

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Intercalates and exfoliates formed with monomeric amines and amides: composite materials containing same and methods of

특허상세정보
국가/구분 United States(US) Patent 등록
국제특허분류(IPC7판) C06K-009/06   
미국특허분류(USC) 524/445 ; 524/446 ; 524/447 ; 523/207 ; 523/209 ; 523/216 ; 428/297 ; 428/331 ; 428/446 ; 428/454 ; 428/474.4
출원번호 US-0577558 (1995-12-22)
발명자 / 주소
  • Beall Gary W.
  • Tsipursky Semeon
  • Sorokin Anatoliy
  • Goldman Anatoliy
출원인 / 주소
  • AMCOL International Corporation
대리인 / 주소
    Marshall, O'Toole, Gerstein, Murray & Borun
인용정보 피인용 횟수 : 56  인용 특허 : 44
초록
▼

Intercalates formed by contacting a layered material, e.g., a phyllosilicate, with an intercalant monomer amine and/or amide to sorb or intercalate the intercalant monomer between adjacent platelets of the layered material. Sufficient intercalant monomer is sorbed between adjacent platelets to expand the adjacent platelets to a spacing of at least about 5 .ANG. (as measured after water removal to a maximum of 5% by weight water), up to about 100 .ANG. and preferably in the range of about 10-45 .ANG., so that the intercalate easily can be exfoliated into ...

대표
청구항
▼

[ What is claimed is:] [1.] An intercalate formed by contacting a layered material, having adjacent platelets of said layered material, having a moisture content of at least about 4% by weight, with an intercalating composition comprising said layered material, water and an intercalant monomer having a functionality selected from the group consisting of an amine; an amide; and mixtures thereof, said intercalate having a weight ratio of intercalant monomer to layered material of at least about 1:20, to achieve sorption and complexing of the intercalant mo...

인용문헌 (44)

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  21. Alexander William (Naperville IL), Method of temporarily inhibiting the swellability of water swellable clays and compositions.
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  25. Deguchi Ryuichi (Ube JPX) Nishio Takeyoshi (Okazaki JPX) Okada Akane (Obu JPX), Polyamide composite material and method for preparing the same.
  26. Yano Kazuhisa (Aichi JPX) Usuki Arimitsu (Aichi JPX) Okada Akane (Aichi JPX) Kurauchi Toshio (Aichi JPX), Polyimide composite material and process for producing the same.
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  37. Rice Camilla A. (Sandersville GA), Surface modified clays and process of manufacture.
  38. Rice Camilla A. (Sandersville GA), Surface modified layered lattice silicate pigments.
  39. Fukui Osamu (Kamakura JPX) Tsutsui Kiyoshi (Sakai JPX) Akagawa Tomohiko (Sakai JPX) Sakai Ikunori (Sakai JPX) Nomura Takao (Toyota JPX) Nishio Takeyoshi (Okazaki JPX) Yokoi Toshio (Toyota JPX) Kawamu, Thermoplastic resin composition.
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  3. Rao,Yuan Q.; Wang,Jin Shan; Blanton,Thomas N.; Chen,Samuel; Kress,Robert J.; Majumdar,Debasis, Article utilizing highly branched polymers to splay layered materials.
  4. Majumdar, Debasis; Shukla, Deepak, Azinium salts as splayant for layered materials.
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  12. Slay, Jeremy Buc; Ray, Thomas Wayne, Downhole seal element formed from a nanocomposite material.
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  15. Dontula, Narasimharao; Blanton, Thomas N.; Majumdar, Debasis, Ethoxylated alcohol intercalated smectite materials and method.
  16. Beall Gary W. ; Serrano Fernando ; Cruz Hannah, Exfoliated layered materials and nanocomposites comprising said exfoliated layered materials having water-insoluble oligomers or polymers adhered thereto.
  17. Ballard, Robert L.; George, Eric R., Fluoropolymer extrusions based on novel combinations of process parameters and clay minerals.
  18. Reddy, B. Raghava; Eoff, Larry; Pascarella, Natalie, Gellable treatment fluids with clay-based gel retarders and related methods.
  19. Tie Lan ; Vasiliki Psihogios ; Sam Richard Turner ; Gary Wayne Connell ; James Christopher Matayabas, Jr. ; John Walker Gilmer, High barrier amorphous polyamide-clay intercalates, exfoliates, and nanocomposite and a process for preparing same.
  20. Landon, Shayne J.; Williams, David A.; Kumar, Vikram; Shelukar, Sachin A.; Nesakumar, Edward J.; Ramakrishnan, Indumathi, Insulated glass unit possessing room temperature-cured siloxane sealant composition of reduced gas permeability.
  21. C. Edward Bishop ; Suhas G. Niyogi, Intercalated clay useful for making an .alpha.-olefin polymer material nanocomposite.
  22. Grah, Michael D.; Becraft, Michael L.; Speer, Drew V.; Beall, Gary W.; Bartels, Jeremy, Intercalated layered silicate.
  23. Gary W. Beall ; Semeon Tsipursky ; Anatoliy Sorokin ; Anatoliy Goldman, Intercalates and exfoliates formed with hydroxyl-functional; polyhydroxyl-functional; and aromatic compounds; composite materials containing same and methods of modifying rheology therewith.
  24. Lan Tie ; Liang Ying ; Tsipursky Semeon ; Beal Gary W., Intercalates and exfoliates formed with long chain (C6+) or aromatic matrix polymer-compatible monomeric, oligomeric or polymeric intercalant compounds, and composite materials containing same.
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  26. Lan Tie ; Beal Gary W. ; Tsipursky Semeon, Intercalates formed by co-intercalation of monomer, oligomer or polymer intercalants and surface modifier intercalants and layered materials and nonocomposites prepared with the intercalates.
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  28. Guoqiang Qian ; Tie Lan ; Aaron M. Fay ; Anthony S. Tomlin GB, Intercalates formed via coupling agent-reaction and onium ion-intercalation pre-treatment of layered material for polymer intercalation.
  29. Guoqiang Qian ; Tie Lan ; Aaron M. Fay ; Anthony S. Tomlin GB, Intercalates formed with polypropylene/maleic anhydride-modified polypropylene intercalants.
  30. Qian, Guoqiang; Cho, Jae Whan; Lan, Tie, Intercalates formed with polypropylene/maleic anhydride-modified polypropylene intercalants.
  31. Liang, Ying; Lan, Tie; Omachinski, Scott; Whan Cho, Jae, Intercalates, exfoliates and concentrates thereof formed with low molecular weight; nylon intercalants polymerized in-situ via ring-opening polymerization.
  32. Liang,Ying; Lan,Tie; Omachinski,Scott, Intercalates, exfoliates and concentrates thereof formed with protonated, non-carboxylic swelling agent and nylon intercalants polymerized in-situ via ring-opening polymerization.
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  35. Lan Tie ; Westphal Erin K. ; Psihogios Vasiliki ; Liang Ying, Layered compositions with multi-charged onium ions as exchange cations, and their application to prepare monomer, oligomer, and polymer intercalates and nanocomposites prepared with the layered compo.
  36. Majumdar,Debasis; Shukla,Deepak, Light curable articles containing azinium salts.
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  38. Rosenthal, Jay S.; Wolkowicz, Michael D., Method for making polyolefin nanocomposites.
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  45. Yadav,Tapesh, Polymer nanotechnology.
  46. Tie Lan ; Vasiliki Psihogios ; Robert Boyd Barbee ; James Christopher Matayabas, Jr. ; John Walker Gilmer, Polymer/clay intercalates, exfoliates, and nanocomposites comprising a clay mixture and a process for making same.
  47. Liao Chien-Shiun,TWX ; Lin Li Kuei,TWX, Preparation of conductive polymeric nanocomposite.
  48. Zhou, Zhihong; Payzant, John Donald; Van Woudenberg, Walter, Reinforced networked polymer/clay alloy composite.
  49. Zhou, Zhihong; Payzant, John Donald; Woudenberg, Walter Van, Reinforced networked polymer/clay alloy composite.
  50. Majumdar,Debasis; Dontula,Narasimharao; Blanton,Thomas N.; Freedman,Gary S., Smectite clay intercalated with polyether block polyamide copolymer.
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