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Membranes containing inorganic fillers and membrane and electrode assemblies and electrochemical cells employing same 원문보기

IPC분류정보
국가/구분 United States(US) Patent 등록
국제특허분류(IPC7판)
  • H01M-008/10
출원번호 US-0920982 (1997-08-29)
발명자 / 주소
  • Grot Walther Gustav
  • Rajendran Govindarajulu
출원인 / 주소
  • E. I. du Pont de Nemours and Company
인용정보 피인용 횟수 : 67  인용 특허 : 8

초록

Cation exchange membranes, made from polymer having cation exchange groups and containing inorganic filler, exhibit reduced fuel crossover for fuel cells employing direct feed organic fuels such as methanol and, when inorganic proton conductor is employed, enhanced proton conductivity.

대표청구항

[ What is claimed is:] [1.] A fuel cell for operation with a direct feed organic fuel, said fuel cell comprising an anode compartment containing an anode, a cathode compartment containing a cathode and a membrane serving as a separator and electrolyte between said anode and cathode compartment, and

이 특허에 인용된 특허 (8)

  1. Surampudi Subbarao (Glendora CA) Narayanan Sekharipuram R. (Altadena CA) Vamos Eugene (La Canada CA) Frank Harvey A. (Encino CA) Halpert Gerald (Pasadena CA) Olah George A. (Beverly Hills CA) Prakash, Aqueous liquid feed organic fuel cell using solid polymer electrolyte membrane.
  2. Ezzell Bobby R. (Lake Jackson TX) Carl William P. (Angleton TX), Low equivalent weight sulfonic fluoropolymers.
  3. Gore Robert W. (Newark DE), Porous products and process therefor.
  4. Gore Robert W. (Newark DE), Process for producing porous products.
  5. Watanabe Masahiro,JPX ; Uchida Hiroyuki,JPX, Solid polymer electrolyte composition.
  6. Ezzell Bobby R. (Lake Jackson TX) Carl William P. (Angleton TX) Mod William A. (Lake Jackson TX), Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000.
  7. Wei Jinzhu (Burnaby CAX) Stone Charles (Vancouver CAX) Steck Alfred E. (West Vancouver CAX), Trifluorostyrene and substituted trifluorostyrene copolymeric compositions and ion-exchange membranes formed therefrom.
  8. Gore Robert Walton (Newark DE), Very highly stretched polytetrafluoroethylene and process therefor.

이 특허를 인용한 특허 (67)

  1. Marsh, Stephen A.; Hill, Lawrence W., Apparatus for cleaning catalyst of a power cell.
  2. Ishida, Junya; Negishi, Mitsuaki; Morioka, Yuzo; Kawakita, Mika; Iwase, Katsunori; Maeda, Manabu; Minemura, Masahiko; Hagiwara, Mamoru, Asymmetric membrane and air-conditioning system using the same.
  3. Roelofs, Mark Gerrit, Chemically stabilized ionomers containing inorganic fillers.
  4. Wang,Da Ming; Lai,Juin Yig; Lee,Kueir Rarn; Kuo,Pei Yun; Su,Yu Huei, Chitosan membrane containing nano-inorganic particles and the method for forming the same.
  5. Cho,Ju hee; Pak,Chan ho, Composite electrolyte membrane and fuel cell containing the same.
  6. Rhee,Hee Woo; Song,Min Kyu; Kim,Young Taek; Park,Seung Bae; Park,Jin Ho, Composite ion-exchange membrane, fabrication method of the same, and membrane-electrode assembly, and polymer electrolyte fuel cell having the same.
  7. Pintauro, Peter N.; Park, Andrew; Ballengee, Jason, Composite membranes, methods of making same, and applications of same.
  8. Xie, Tao; Fuller, Timothy J., Composite proton exchange membrane.
  9. Krusic, Paul J.; Lu, Helen S. M.; Yang, Zhen-Yu, Compositions containing modified fullerenes.
  10. Mueller, Jens Thomas; Schnetzler, Sven; Waitkat, Peter, Device for treating a fuel/coolant mixture.
  11. Minteer, Shelley D.; Treu, Becky L.; Duma, Rodica, Direct electron transfer using enzymes in bioanodes, biocathodes, and biofuel cells.
  12. Peled,Emanuel; Duvdevani,Tair; Melman,Avi; Aharon,Adi, Direct oxidation fuel cell with a divided fuel tank having a movable barrier pressurized by anode effluent gas.
  13. Zimmerman William H. ; Trainham ; III James Arthur ; Law ; Jr. Clarence Garlan ; Newman John Scott, Electrochemical conversion of anhydrous hydrogen halide to halogen gas using a membrane-electrode assembly or gas diffusion electrodes.
  14. Minteer, Shelley D.; Akers, Niki L.; Moore, Christine M., Enzyme immobilization for use in biofuel cells and sensors.
  15. Marsh, Stephen A., Fuel cell and power chip technology.
  16. Marsh,Stephen A., Fuel cell and power chip technology.
  17. Marsh,Stephen A., Fuel cell and power chip technology.
  18. Dohle Hendrik,DEX ; Peinecke Volker,DEX ; Busenbender Ilona,DEX ; Kels Thorsten,DEX, Fuel cell electrode-electrolyte unit.
  19. Peled, Emanuel; Duvdevani, Tair; Melman, Avi; Aharon, Adi, Fuel cell having fuel tank directly attached to anode allowing pump-free fuel delivery.
  20. Acker,William P.; Beckmann,Gerhard, Fuel cell membrane and fuel cell system with integrated gas separation.
  21. Blankenship George D., Fuel cell operated welder.
  22. Blankenship, George D., Fuel cell operated welder.
  23. Blankenship, George D., Fuel cell operated welder.
  24. Okoye, Kenneth Ejike; Ejiogu, Emenike Chinedozi; Matsui, Sachio, Fuel cell unit, fuel cell unit array, fuel cell module and fuel cell system.
  25. Emanuel Peled IL; Tair Duvdevani IL; Avi Melman IL; Adi Aharon IL, Fuel cell with proton conducting membrane.
  26. Emanuel Peled IL; Tair Duvdevani IL; Avi Melman IL; Adi Aharon IL, Fuel cell with proton conducting membrane with a pore size less than 30 nm.
  27. Ohlsen, Leroy J.; Cooke, Aaron M.; Mallari, Jonathan C.; Chan, Chung M.; Rice, Gordon L.; Nelson, Craig E., Fuel cells having silicon substrates and/or sol-gel derived support structures.
  28. Krusic, Paul J.; Law, Clarence G.; Lu, Helen S. M.; Yang, Zhen-Yu; Garner, Jocelyn Hicks, Functionalized carbon materials.
  29. Chapples,John; Jones,Martin Geoffrey, Gas sensors.
  30. Park, Yong-il; Kim, Eun Hyung; Park, Sung Bum, High molecular nanocomposite membrane for direct methanol fuel cell, and membrane-electrode assembly and methanol fuel cell including the same.
  31. McGrath, James E.; Hickner, Michael; Wang, Feng; Kim, Yu-Seung, ION-conducting sulfonated polymeric materials.
  32. Minteer, Shelley D.; Akers, Niki L.; Moore, Christine M., Immobilized enzymes and uses thereof.
  33. Minteer, Shelley D.; Topcagic, Sabina; Treu, Becky, Immobilized enzymes in biocathodes.
  34. Alberti, Giulio; Casciola, Mario; Pica, Monica, Innovative method for the preparation of proton conducting nanopolymeric membranes for use in fuel cells or in catalytic membrane reactors.
  35. Bauer,Bernd; Roziere,Jacques; Jones,Deborah; Alberti,Giulio; Casciola,Mario; Pica,Monica, Ion conducting composite membrane materials containing an optionally modified zirconium phosphate dispersed in a polymeric matrix, method for preparation of the membrane material and its use.
  36. Chang, Hyuk; Kim, Hae-kyoung; Kim, Hasuck; Lee, Jin-Kyu; Park, Sangook; Ha, Shin Woo, Ion conductive composite membrane using inorganic conductor.
  37. Chang, Hyuk; Kim, Hae-kyoung; Kim, Hasuck; Lee, Jin-Kyu; Park, Sangook; Ha, Shin Woo, Ion conductive composite membrane using inorganic conductor and method of manufacturing the same.
  38. McGrath, James E.; Hickner, Michael; Wang, Feng; Kim, Yu-Seung, Ion-conducting sulfonated polymeric materials.
  39. Gopal, Ramanathan, Membrane electrode assemblies for electrochemical cells.
  40. Fenton, James M.; Kunz, H. Russell; Lin, Jung-Chou, Membrane electrode assemblies using ionic composite membranes.
  41. Prakash,Surya; Narayanan,Sekharipuram R.; Atti,Anthony; Olah,George; Smart,Marshall C., Membrane electrode assembly for a fuel cell.
  42. James M. Fenton ; H. Russell Kunz ; Michael B. Cutlip ; Jung-Chou Lin, Membranes, membrane electrode assemblies and fuel cells employing same, and process for preparing.
  43. Chu Dervn ; Jiang Rongzbong, Methanol tolerant catalyst material.
  44. Marsh, Stephen A.; Hill, Lawrence W., Method and apparatus for cleaning catalyst of a power cell.
  45. Marsh, Stephen A.; Hill, Lawrence W., Method and apparatus for controlling an array of power generators.
  46. Marsh, Stephen A., Method and apparatus for electro-chemical reaction.
  47. Marsh, Stephen A., Methods of operating fuel cells.
  48. Marsh, Stephen A., Methods of operating fuel cells.
  49. Minteer, Shelley D.; Martin, Robert S.; Moore, Christine M., Microfluidic biofuel cell.
  50. Kim, Hae-kyoung; Lee, Jae-sung; Lee, Hyun-chul; Chang, Hyuk; Rhee, Chang-houn, Modified inorganic material with ion exchange capacity, composite electolyte membrane comprising the same, and fuel cell comprising the composite electrolyte membrane.
  51. Kim,Hae kyoung, Nanocomposite electrolyte membrane and fuel cell employing the same.
  52. Briehn, Christoph; Ball, Peter; Baumann, Martina; Gottschalk-Gaudig, Torsten; Hoelzl, Manfred, Particles comprising zwitterionic structural elements.
  53. Kim, Hae kyoung; Cho, Ju hee, Polymer electrolyte comprising inorganic conductive nano-particles and fuel cell employing the polymer electrolyte.
  54. G. K. Surya Prakash ; George A. Olah ; Marshall C. Smart ; Sekharipuram R. Narayanan ; Qungie J. Wang ; Subbarao Surumpudi ; Gerald Halpert, Polymer electrolyte membranes for use in fuel cells.
  55. Song, Min-Kyu; Yoon, Hae-Kwon; Park, Young-Mi, Polymer membrane for a fuel cell, a method of preparing the same, and a membrane-electrode assembly fuel cell system comprising the same.
  56. Kim,Hae kyoung; Lee,Jae sung; Rhee,Chang houn; Chang,Hyuk, Polymer nanocomposite membrane and fuel cell using the same.
  57. Marsh, Stephen A., Power cell and power chip architecture.
  58. Marsh, Stephen A., Power cell and power chip architecture.
  59. Sahu, Akhila Kumar; Selvarani, Ganesh; Pitchumani, Sethuraman; Sridhar, Parthasarathi; Shukla, Ashok Kumar, Process for the preparation of sol-gel modified alternative Nafion-Silica composite membrane useful for polymer electrolyte fuel cell.
  60. Hamrock, Steven J.; Schaberg, Mark S.; Sharma, Neeraj; Abulu, John E., Proton conducting materials.
  61. Hamrock, Steven J.; Schaberg, Mark S.; Sharma, Neeraj; Abulu, John E., Proton conducting materials.
  62. Hamrock, Steven J.; Schaberg, Mark S.; Sharma, Neeraj; Abulu, John E., Proton conducting materials.
  63. Savinell Robert F. ; Litt Morton H., Proton conducting solid polymer electrolytes prepared by direct acid casting.
  64. Yamaguchi, Takeo; Lee, Ju Myeung; Anilkumar, Gopinathan Madhavikutty, Proton conductive hybrid material, and catalyst layer for fuel cell using the same.
  65. Won,Jongok; Kang,Yong Soo; Oh,In Hwan; Ha,Heung Yong; Choi,Sangwook; Choun,Jee Won; Jung,Bum Suk, Proton exchange composite membranes, composite solutions, and method for manufacturing and fuel cell using the same.
  66. Chen, Jong Pyng; Chen, Jen Luan; Shih, Chih Jer; Chen, Chih Yuan, Structures of the proton exchange membranes with different molecular permeabilities.
  67. Narayanan,Sekharipuram R.; Yen,Shiao Pin S., Water free proton conducting membranes based on poly-4-vinylpyridinebisulfate for fuel cells.
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