초록 ▼

Processes are disclosed for the conversion of propylene to methylmercaptopropanal by converting propylene to acrolein and converting acrolein to methylmercaptopropanal. The processes utilize oxygen and recycle propane to the acrolein reactor. Process feeds can comprise, propane, propylene or mixture

Processes are disclosed for the conversion of propylene to methylmercaptopropanal by converting propylene to acrolein and converting acrolein to methylmercaptopropanal. The processes utilize oxygen and recycle propane to the acrolein reactor. Process feeds can comprise, propane, propylene or mixtures thereof. The presence of propane in the propylene-to-acrolein reaction can enhance the efficiency of the processes.

대표청구항 ▼

[ We claim:] [1.] A process for producing methylmercaptopropanal ("MMP") comprising:(i) passing a propane feedstream comprising propane, oxygen and a recycle gas comprising propane, oxygen and at least one of carbon monoxide or carbon dioxide to a propylene reaction zone at conditions to promote the

[ We claim:] [1.] A process for producing methylmercaptopropanal ("MMP") comprising:(i) passing a propane feedstream comprising propane, oxygen and a recycle gas comprising propane, oxygen and at least one of carbon monoxide or carbon dioxide to a propylene reaction zone at conditions to promote the formation of propylene to provide a preliminary oxidation effluent stream comprising propylene, propane, oxygen and at least one of carbon monoxide or carbon dioxide;(ii) passing the preliminary oxidation effluent stream to an acrolein reaction zone wherein the preliminary oxidation effluent stream is contacted with an acrolein reaction catalyst at conditions effective to promote the formation of acrolein to provide an acrolein effluent stream comprising acrolein, propane, acetaldehyde and water;(iii) passing the acrolein effluent stream to an acrolein separation zone wherein the acrolein effluent stream is partially condensed to provide a liquid acrolein product stream, comprising acrolein, acetaldehyde and water and a recycle gas stream comprising the recycle gas;(iv) passing the acrolein product stream and methyl mercaptan to a MMP reaction zone and contacting the acrolein and methyl mercaptan with a MMP reaction catalyst at conditions effective to promote the conversion of acrolein and methyl mercaptan to MMP; and(v) recycling at least a portion of the recycle gas stream to the acrolein reaction zone;wherein the preliminary oxidation effluent stream comprises an effective amount of propane to enhance the efficiency of acrolein formation in the acrolein reaction zone.