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Reducing no emissions from an engine by on-demand generation of ammonia for selective catalytic reduction 원문보기

IPC분류정보
국가/구분 United States(US) Patent 등록
국제특허분류(IPC7판)
  • B01D-053/54
  • B01D-053/60
출원번호 US-0826165 (1997-03-27)
발명자 / 주소
  • Jeremy D. Peter-Hoblyn GB
  • Eric N. Balles
  • John E. Hofmann
출원인 / 주소
  • Clean Diesel Technologies, Inc.
대리인 / 주소
    Ware, Fressola, Van Der, Sluys & Adolphson LLP
인용정보 피인용 횟수 : 61  인용 특허 : 15

초록

A safe, reliable SCR system for reducing NOx emissions from an internal combustion engine hydrolyzes urea or like reagent under sufficient pressure to assure generation of ammonia, without production of solids that could foul injectors or catalysts. The heat for hydrolysis can be provided by the exh

대표청구항

1. A method for reducing the emissions of NOx from a lean-burn engine having associated therewith an exhaust system having an exhaust passage leading to an SCR reactor effective for selective catalytic NOx reduction, comprising:supplying an aqueous urea solution at a preset pressure of at least abou

이 특허에 인용된 특허 (15)

  1. Luftglass Bryan K. (South Salem NY) Sun William H. (Aurora IL) Hofmann John E. (Naperville IL), Catalytic/non-catalytic combination process for nitrogen oxides reduction.
  2. Hug Hans T. (Grabenwiese 87 CH-8484 Weisslingen CHX) Hartenstein Axel (Wolfzangenstrasse 42 CH-8413 Neftenbach CHX) Hug Michael (Hofweg 2 CH-9547 Heiterschen TG CHX), Cleaning exhaust gases from combustion installations.
  3. Bowers Wayne E. (Clearwater FL) Sprague Barry N. (West Haven CT), Diesel fuel additives and diesel fuels containing soluble platinum group metal compounds and use in diesel engines.
  4. Bowers Wayne E. (Clearwater FL) Sprague Barry N. (West Haven CT), Gasoline additives and gasoline containing soluble platinum group metal compounds and use in internal combustion engines.
  5. Schmelz Helmut (Prien DEX), Method and apparatus for controlled introduction of a reducing agent into a nitrogen oxide-containing exhaust gas.
  6. Epperly W. Robert (New Canaan CT) Sprague Barry N. (Bethlehem CT), Method for catalyzing fuel for powering internal combustion engines.
  7. Jones Dale G. (Visalia CA), Method for converting urea to ammonia.
  8. Peter-Hoblyn Jeremy D. (Bodmin CT GB3) Valentine James M. (Fairfield CT) Epperly W. Robert (New Canaan CT) Sprague Barry N. (Bethlehem CT), Method for reducing pollution emissions from a diesel engine.
  9. Dahlheim Christian (Berlin DEX) Fleischer Maximilian (Hoehenkirchen DEX) Meixner Hans (Haar DEX), Method for reducing the nitrogen oxide concentration in the exhaust of an internal combustion engine or of a firing syst.
  10. Epperly W. Robert (New Canaan CT) Sprague Barry N. (Bethlehem CT) Kelso Danny T. (Houston TX) Bowers Wayne E. (North Vassalboro ME), Method for regenerating, replacing or treating the catalyst in a hydroprocessing reactor.
  11. Hofmann John E. (Stamford CT) Sprague Barry N. (Bethlehem CT) Sun William H. (Wallingford CT), Process for reducing nitrogen oxides without generating nitrous oxide.
  12. Mori ; Toshikatsu ; Takeuchi ; Masato ; Hitomi ; Otane ; Uno ; Shigeo ; I mahashi ; Jinichi ; Nakajima ; Fumito, Process for removing nitrogen oxides using ammonia as a reductant and sulfated metallic catalysts.
  13. Ginger Edward A. (Northbrook IL), Process for the catalytic reduction of nitrogen oxides in gaseous mixtures.
  14. von Harpe Thure (Meerbusch DEX) Pachaly Reihard (Kerpen IL DEX) Holfmann John E. (Naperville IL), Process for the in-line hydrolysis of urea.
  15. Schoubye Peter ; Carl S. (Horsholm DKX), Process for the removal of nitrogen oxides from offgases from turbines.

이 특허를 인용한 특허 (61)

  1. Jambhekar, Rajaram; Lisauskas, Robert; Medeiros, William; Erickson, Clayton, Adaptive control system for reagent distribution control in SCR reactors.
  2. Shaikh, Furqan; Lawrence, Don; Cooper, Scott; Castleberry, Jr., Larry, Ammonia vapor management system and method.
  3. Hatfield, Randal L.; Golden, Stephen J.; Ngo, Johnny T., Base metal activated rhodium coatings for catalysts in three-way catalyst (TWC) applications.
  4. Launois, Maxime; Nazarpoor, Zahra; Golden, Stephen J., Calibration strategies to improve spinel mixed metal oxides catalytic converters.
  5. Sczomak, David P.; Narayanaswamy, Kushal; Keating, Edward J., Dedicated exhaust gas recirculation control systems and methods.
  6. Schaller,Johannes; Brinz,Thomas; Ullmann,Ilona, Device for exhaust gas treatment of a combustion system.
  7. Ayyappan, Ponnayan; Harris, Tom; Dou, Danan, Diesel exhaust fluid formulation having a high ammonium content and a low freezing point.
  8. Sprague, Barry; Beal, Steve, Diesel exhaust treatment systems and methods.
  9. Hudson, Dannie B., Dual homogenization system and process for fuel oil.
  10. Reba, Peter Joseph; Baccari, Gregory John; Eldredge, Thomas V.; Valentine, James M., Dual injector system for diesel emissions control.
  11. Guinther, Gregory H.; Roos, Joseph W.; Human, David M.; Schwab, Scott D., Emissions control system for diesel fuel combustion after treatment system.
  12. Guinther, Gregory H.; Roos, Joseph W.; Human, David M.; Schwab, Scott D., Emissions control system for diesel fuel combustion after treatment system.
  13. Sczomak, David P.; Gallon, Robert J.; McAlpine, Robert S.; Solomon, Arun S., Engine control systems and methods for nitrogen oxide reduction.
  14. Nazarpoor, Zahra; Golden, Stephen J., Enhanced catalytic activity at the stoichiometric condition of zero-PGM catalysts for TWC applications.
  15. Gundrum, Timothy Joseph, Exhaust aftertreatment supplying a reducing agent.
  16. Kapsos, David W.; Bremigan, Cary D.; Adams, Mark P.; Klein, Patrick M., Exhaust aftertreatment system with spiral mixer.
  17. Zheng, Guanyu; Zhang, Yongyue; Popovich, Jeremy D.; Yetken, Dervis A.; Kotrba, Adam J., Exhaust gas additive/treatment system and mixer for use therein.
  18. Kesse, Mary Lou; Wynkoop, Chris L.; Wei, Zhiyong; Lukich, Michael S.; Scrivner, Wade D.; Jayachandran, Amit, Exhaust system implementing feedforward and feedback control.
  19. Kesse, Mary Lou; Wei, Zhiyong; Zhu, Liangtao, Exhaust system implementing in situ calibration.
  20. Nazarpoor, Zahra, Firing (calcination) process and method related to metallic substrates coated with ZPGM catalyst.
  21. Deshpande, Hemant, Gaseous ammonia injection system.
  22. Gschwind, Thomas, Heating device and thermal reactor for the heating and gasification of urea.
  23. Verdegan, Barry M.; Liu, Z. Gerald, Impactor for selective catalytic reduction system.
  24. Kaemingk, Nathan J.; Gerty, Michael, Injector control for a selective catalytic reduction system.
  25. Kaemingk, Nathan J.; Gerty, Michael, Injector control for a selective catalytic reduction system.
  26. Jacob, Eberhard; K?fer, Sebastian; M?ller, Werner; Lacroix, Andreas; Herr, Andreas, Method and apparatus for producing ammonia (NH3).
  27. Cook, David; Shaikh, Furqan Zafar; Levin, Michael; Furedy, David; Dawson, Evan Kent; Kabat, Daniel; Keller, Jeremy, Method and apparatus for rapidly thawing frozen NOx reductant.
  28. Colucci,William J., Method and composition for suppressing coal dust.
  29. Brück, Rolf; Hirth, Peter; Härig, Thomas; Brugger, Marc, Method and device for providing a gas flow containing a reducing agent.
  30. Lambert, Christine Kay; Backes, Rolf, Method and system for freeze protecting liquid NOx reductants for vehicle application.
  31. Dougnier, Francois; Madoux, Dominique; Van Schaftingen, Jules Joseph; Wouters, Paul, Method and system for purifying the exhaust gases of a combustion engine.
  32. Maus, Wolfgang; Brück, Rolf, Method for feeding reducing agent into an exhaust gas system and corresponding exhaust gas system and motor vehicle.
  33. Brunengo, Paolo, Method for the treatment of combustion flue gas.
  34. Dudis, Douglas S.; Schmidt, Joel E.; Miller, Douglas J., Method for thermal management through use of ammonium carbamate.
  35. Guinther,Gregory H.; Devlin,Mark T.; Roos,Joseph W.; Human,David M., Method of enhancing the operation of diesel fuel combustion systems.
  36. Chiruta, Mihai; Liu, Z. Gerald; Dastoor, Varjavan, Mounting plate for mounting injectors and directing reductant flow in exhaust conduits.
  37. Wakasa,Satoshi; Takubo,Noboru; Isshiki,Yukihiro; Masuda,Kouichi; Ishizaki,Nobuyuki, NOx removal system for boilers.
  38. Wakasa,Satoshi; Takubo,Noboru; Isshiki,Yukihiro; Masuda,Kouichi; Ishizaki,Nobuyuki, NOx removal system for boilers.
  39. Valentine, James M.; Broderick, Jeffrey Michael; Lindemann, Scott H.; Broderick, R. Gifford; Schindler, Edmund S., On demand generation of ammonia for small industrial and commercial boilers.
  40. Nazarpoor, Zahra; Kitazumi, Sen; Ngo, Johnny T., Optimization of Zero-PGM washcoat and overcoat loadings on metallic substrate.
  41. Brinkman, Norman D.; Najt, Paul M.; Narayanaswamy, Kushal; Brown, David B.; Li, Wei; Perry, Kevin L.; Qi, Gongshin; Guralp, Orgun A., Passive ammonia-selective catalytic reduction for NOx control in internal combustion engines.
  42. Meessen, Jozef Hubert, Process for the preparation of a urea-comprising aqueous stream.
  43. Davidson, Debbie; Engeham, Duncan; Uban, Piotr; Elsey, David; Liu, Z. Gerald; Pawson, Kenneth; Smith, Paul; Capel, Ken; Critchley, Andrew; Sarcona, David; Goss, James, Reductant decomposition system.
  44. Davidson, Debbie; Engeham, Duncan; Urban, Piotr; Elsey, David; Liu, Z. Gerald; Pawson, Ken; Smith, Paul; Capel, Ken; Critchley, Andrew; Sarcona, David; Goss, James R, Reductant decomposition system.
  45. Li, Yongxiang; Sun, Jinhui, Reductant dosing system.
  46. Hatfield, Randal L.; Golden, Stephen J.; Ngo, Johnny T., Rhodium-iron catalysts.
  47. Nunez, Rafael; Abhyankar, Atul; Hummel, Ken; Kruer, Justin; Lorenz, Tyler; Farid, Farshad; Sundaravel, Arun Shori, Selective dosing module control system.
  48. Nunez, Rafael; Abhyankar, Atul; Hummel, Ken; Kruer, Justin; Lorenz, Tyler; Farid, Farshad; Sundaravel, Arun Shori, Selective dosing module control system.
  49. Nunez, Rafael; Abhyankar, Atul; Hummel, Ken; Kruer, Justin; Lorenz, Tyler; Farid, Farshad; Sundaravel, Arun Shori, Selective dosing module control system.
  50. Odermatt, Peter; Spiegel, Andreas; Dittrich, Jurgen, Sensor for detecting the instantaneous concentrations of a plurality of gas constituents in a gas.
  51. Nazarpoor, Zahra; Golden, Stephen J., Spinel compositions and applications thereof.
  52. Harris, Michael; Leyrer, Jurgen; Demel, Yvonne; Lox, Egbert; Kreuzer, Thomas, Structured catalysts for selective reduction of nitrogen oxides by ammonia using a compound that can be hydrolyzed to ammonia.
  53. Nazarpoor, Zahra; Golden, Stephen J., Synergized PGM catalyst systems including platinum for TWC application.
  54. Golden, Stephen J., Synergized PGM close-coupled catalysts for TWC applications.
  55. Ryan, William R.; Smith, Ernest W., System for modulating fuel supply to individual fuel nozzles in a can-annular gas turbine.
  56. Assalve, Daniel; Campbell, John; Fessler, Harald; Schlegel, Reto, System for preventing the urea crystal formation within an exhaust gas after treatment system.
  57. Dudis, Douglas S.; Schmidt, Joel E.; Miller, Douglas J., Systems and methods for thermal management through use of ammonium carbamate.
  58. Nazarpoor, Zahra; Abken, Anke Elizabeth; Golden, Stephen J., Thermal stability of copper-manganese spinel as Zero PGM catalyst for TWC application.
  59. Hatfield, Randal L.; Lee, Edward J.; Ngo, Johnny T.; Golden, Stephen J., Three-way catalyst systems including Fe-activated Rh and Ba-Pd material compositions.
  60. Broderick, R. Gifford; Broderick, Jeffrey Michael; O'Leary, Kathryn V.; Lindemann, Scott H.; Valentine, James M., Urea decomposition and improved SCR NOx reduction on industrial and small utility boilers.
  61. Nazarpoor, Zahra; Golden, Stephen J., ZPGM Diesel Oxidation Catalysts and methods of making and using same.
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