초록

A promoted multi-metal oxide catalyst is useful for the vapor phase oxidation of an alkane, or a mixture of an alkane and an alkene, to an unsaturated carboxylic acid and for the vapor phase ammoxidation of an alkane, or a mixture of an alkane and an alkene, to an unsaturated nitrile.

대표청구항 ▼

1. A catalyst comprising a mixed metal oxide having the empirical formulaMoaVbNcXdZeOf whereinN is at least one element selected from the group consisting of Te, Sb, Sn, Ge and Bi, X is at least one element selected from the group consisting of Nb, Ta, Ti, Al, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ni, Pt, B,

1. A catalyst comprising a mixed metal oxide having the empirical formulaMoaVbNcXdZeOf whereinN is at least one element selected from the group consisting of Te, Sb, Sn, Ge and Bi, X is at least one element selected from the group consisting of Nb, Ta, Ti, Al, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ni, Pt, B, In, As, Li, Na, K, Rb, Cs, Fr, Be, Mg, Ca, Sr, Ba, Hf, Pb, P, Pm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, La, Sc, Au, Ag, Pd, Ga, Pr, Re, Ir, Nd, Y, Sm, Tb, W, Ce, Cu and Zn, and Z is selected from the group consisting of Se and Bi; and wherein, when a=1, b=0.01 to 1.0, c=0.01 to 1.0, d=0.01 to 1.0, e=0.01 to 0.1 and f is dependent on the oxidation state of the other elements;with the proviso that, when Z is Se, Sb and Ga are not simultaneously present in the mixed metal oxide.