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Polymer electrolyte membranes for use in fuel cells 원문보기

IPC분류정보
국가/구분 United States(US) Patent 등록
국제특허분류(IPC7판)
  • H01M-008/10
출원번호 US-0846972 (1997-04-30)
발명자 / 주소
  • G. K. Surya Prakash
  • George A. Olah
  • Marshall C. Smart
  • Sekharipuram R. Narayanan
  • Qungie J. Wang
  • Subbarao Surumpudi
  • Gerald Halpert
출원인 / 주소
  • University of Southern California
대리인 / 주소
    Fish & Richardson P.C.
인용정보 피인용 횟수 : 54  인용 특허 : 16

초록

A polymer electrolyte membrane composed of polystyrene sulfonic acid (PSSA) crosslinked within a poly(vinylidene fluoride) (PVDF) matrix is provided. This membrane exhibits low methanol crossover which translates to higher fuel and fuel cell efficiencies. A fuel cell comprising a PSSA-PVDF membrane

대표청구항

1. A fuel cell element which is intended for use in an electrochemical reaction in a fuel cell comprising a polymer electrolyte membrane said membrane being in the form of an interpenetrating network composed of polystyrene sulfonic acid crosslinked within a poly(vinylidene fluoride) matrix, prepare

이 특허에 인용된 특허 (16)

  1. Lee Jai Y. (Taejeon KRX) Lee Han H. (Seoul KRX) Lee Jon H. (Taejeon KRX) Kim Dong M. (Taejeon KRX), Alkaline fuel cell.
  2. Surampudi Subbarao (Glendora CA) Narayanan Sekharipuram R. (Altadena CA) Vamos Eugene (La Canada CA) Frank Harvey A. (Encino CA) Halpert Gerald (Pasadena CA) Olah George A. (Beverly Hills CA) Prakash, Aqueous liquid feed organic fuel cell using solid polymer electrolyte membrane.
  3. Beal Daniel W. (East Hartford CT) Scheffler Glenn W. (Tolland CT), Augmented air supply for fuel cell power plant during transient load increases.
  4. Takada Noriyuki (Hokkaido JPX) Shimizu Junko (Hokkaido JPX), Fuel cell.
  5. Ehrenberg Scott G. (Fishkill NY) Serpico Joseph M. (Troy NY) Wnek Gary E. (Latham NY) Rider Jeffrey N. (Troy NY), Fuel cell incorporating novel ion-conducting membrane.
  6. Tsukui, Tsutomu; Shimizu, Toshio; Doi, Ryota; Tsutsumi, Yasuyuki, Fuel cell using organic, high-molecular weight electrolyte.
  7. Kosek John A. (Danvers MA) Cropley Cecelia C. (Acton MA) Laconti Anthony B. (Lynnfield MA), Membrane-electrode assembly for a direct methanol fuel cell.
  8. Grot Walther Gustav ; Rajendran Govindarajulu, Membranes containing inorganic fillers and membrane and electrode assemblies and electrochemical cells employing same.
  9. Voss Henry H. (North Vancouver CAX) Wilkinson David P. (North Vancouver CAX) Watkins David S. (Coquitlam CAX), Method and apparatus for removing water from electrochemical fuel cells.
  10. Momose Takashi (Urbana IL) Tomiie Kazuo (Tokyo JPX) Harada Hiroyuki (Yokohama JPX) Miyachi Hiroshi (Okayama JPX) Kato Hiroko (Tamano JPX), Method for preparation of graft polymeric membranes.
  11. Gillberg-LaForce Gunilla E. (Summit NJ) Gabriel Eric M. (Lebanon NJ), Modified microporous structures.
  12. Fleischer Niles A. (Rehovot ILX) Manassen Joost (Rehovot ILX) Daren Steve (Nes Ziona ILX), Non-liquid proton conductors for use in electrochemical systems under ambient conditions.
  13. Benz Uwe (Uhldingen DEX) Fleck Wolfram (Erbach DEX) Hornburg Gerald (Elchingen DEX), Process for supplying air to a fuel cell system.
  14. Klinkowski Peter R. (Norwalk CT), Solid polymeric electrolyte.
  15. Gregor Harry P. (410 Riverside Dr. New York NY 10025) Samuelsen Edgar (348-68 St. Brooklyn NY 11220) Dalven Paul I. (914 Montgomery St. Brooklyn NY 11213) Gregor Charles D. (530 W. 113 St. New York N, Solid state cross-linked polymer.
  16. Steck Alfred E.,CAX ; Stone Charles,CAX, Substituted .alpha.,.beta.,.beta.-trifluorostyrene-based composite membranes.

이 특허를 인용한 특허 (54)

  1. Nam, Kiehyun; Xu, Helen; Cao, Shuguang; Olmeijer, David; Servaites, Jon; Wang, Ying, Acid-base proton conducting polymer blend membrane.
  2. MacKinnon, Sean M; Fuller, Timothy J.; Schoeneweiss, Michael R., Blended PEM's with elastomers for improved mechanical durability.
  3. Fuller, Timothy J.; MacKinnon, Sean M; Schoeneweiss, Michael R.; Gittleman, Craig S., Blends of low equivalent molecular weight PFSA ionomers with Kynar 2751.
  4. Schoeneweiss, Michael R.; Fuller, Timothy J.; Coms, Frank; MacKinnon, Sean M, Co(II)tetramethoxyphenylporphyrin additive to PFSA PEMS for improved fuel cell durability.
  5. Schoeneweiss, Michael R.; Fuller, Timothy J.; Coms, Frank; MacKinnon, Sean M., Co(II)tetramethoxyphenylporphyrin additive to PFSA PEMs for improved fuel cell durability.
  6. Fuller, Timothy J.; Schoeneweiss, Michael R.; Zhang, Junliang, Cobalt(II) tetramethoxyphenylporphyrin (CoTMPP) ionomer stabilization to prevent electrode degradation.
  7. Zou, Lijun; MacKinnon, Sean M.; Fuller, Timothy J., Combination of main-chain and side-chain sulfonation of PFCB-6F high-temperature fuel cell membranes.
  8. MacKinnon, Sean M; Fuller, Timothy J., Composite membrane.
  9. Müller, Jens; Urban, Peter; Wezel, Regina; Colbow, Kevin M.; Zhang, Jiujun, Direct dimethyl ether fuel cells.
  10. Surampudi,Subbarao; Frank,Harvey A.; Narayanan,Sekharipuram R.; Chun,William; Jeffries Nakamura,Barbara; Kindler,Andrew; Halpert,Gerald, Direct methanol feed fuel cell and system.
  11. Surampudi,Subbarao; Frank,Harvey A.; Narayanan,Sekharipuram R.; Chun,William; Jeffries Nakamura,Barbara; Kindler,Andrew; Halpert,Gerald, Direct methanol feed fuel cell and system.
  12. Surampudi,Subbarao; Frank,Harvey A.; Narayanan,Sekharipuram R.; Chun,William; Jeffries Nakamura,Barbara; Kindler,Andrew; Halpert,Gerald, Direct methanol feed fuel cell and system.
  13. Ophir, Amos; Cohen, Eyal; Dishon, David; Colman, Joshua Lewis, Drying substances, preparation and use thereof.
  14. Ophir, Amos; Cohen, Eyal; Dishon, David; Colman, Joshua Lewis, Drying substances, preparation and use thereof.
  15. Ophir, Amos; Cohen, Eyal; Dishon, David; Colman, Joshua Lewis, Drying substances, preparation and use thereof.
  16. Ophir, Amos; Cohen, Eyal; Dishon, David; Colman, Joshua Lewis, Drying substances, preparation and use thereof.
  17. Rakhman, Moshe; Faiglin, Tehila; Ophir, Amos; Levitsky, Gershon; Colman, Joshua Lewis, Drying substances, preparation and use thereof.
  18. Rakhman, Moshe; Faiglin, Tehila; Ophir, Amos; Levitsky, Gershon; Colman, Joshua Lewis, Drying substances, preparation and use thereof.
  19. Markoski, Larry J.; Natarajan, Dilip; Primak, Alex, Electrochemical cells.
  20. MacKinnon, Sean M; Fuller, Timothy J.; Brenner, Annette M., Fuel cell with spatially non-homogeneous ionic membrane.
  21. MacKinnon, Sean M; Schoeneweiss, Michael R.; Fuller, Timothy J.; Gittleman, Craig S., Gradient reinforced proton exchange membrane.
  22. Markoski, Larry J.; Natarajan, Dilip, High efficiency fuel cell system.
  23. Jiang, Rongzhong; Rong, Charles; Chu, Deryn, High voltage methanol fuel cell assembly using proton exchange membranes and base/acid electrolytes.
  24. Markoski, Larry J.; Natarajan, Dilip; Primak, Alex, Hydrogel barrier for fuel cells.
  25. Morin, Arnaud; Ameduri, Bruno; Chikh, Linda; Fichet, Odile; Gebel, Gérard; Mercier, Régis, Interpenetrating polymer networks and uses thereof.
  26. Fuller, Timothy J.; MacKinnon, Sean M; Schoeneweiss, Michael R., Ion exchange membrane having lamellar morphology and process of making the same.
  27. Markoski, Larry J.; Simmons, Timothy C., Liquid containers and apparatus for use with power producing devices.
  28. Brack, Hans-Peter; Scherer, Günther; Gubler, Lorenz, Membrane electrode assembly (MEA), method for its manufacturing and a method for preparing a membrane to be assembled in a MEA.
  29. Prakash,Surya; Narayanan,Sekharipuram R.; Atti,Anthony; Olah,George; Smart,Marshall C., Membrane electrode assembly for a fuel cell.
  30. Markoski, Larry J.; Natarajan, Dilip, Method and apparatus for enhancing power density of direct liquid fuel cells.
  31. Vamos,Eugene; Surampudi,Subbarao; Narayanan,Sekharipuram R.; Frank,Harvey A.; Halpert,Gerald; Olah,George A.; Prakash,G. K. Surya, Organic fuel cell methods and apparatus.
  32. MacKinnon, Sean M; Fuller, Timothy J.; Brenner, Annette M., Perfluorocyclobutane based water vapor transfer membranes.
  33. MacKinnon, Sean M; Fuller, Timothy J.; Brenner, Annette M., Perfluorocyclobutane based water vapor transfer membranes with side chain perfluorosulfonic acid moieties.
  34. Markoski, Larry J.; Natarajan, Dilip; Primak, Alex, Permselective composite membrane for electrochemical cells.
  35. Zou, Lijun; Fuller, Timothy J.; Schoeneweiss, Michael R., Poly(perfluorocyclobutane) ionomer with phosphonic acid groups for high temperature fuel cells.
  36. Fuller, Timothy J.; MacKinnon, Sean M; Schoeneweiss, Michael R.; Gittleman, Craig S., Polyelectrolyte membranes comprised of blends of PFSA and sulfonated PFCB polymers.
  37. Fuller, Timothy J.; MacKinnon, Sean M; Schoeneweiss, Michael R., Polyelectrolyte membranes derived from soluble perfluorocyclobutane polymers with sulfonyl chloride groups.
  38. Fuller, Timothy J.; MacKinnon, Sean M; Schoeneweiss, Michael R., Polyelectrolyte membranes made of poly(perfluorocyclobutanes) with pendant perfluorosulfonic acid groups and blends with poly(vinylidene fluoride).
  39. Liu,Jin; Wang,Huanting; Cheng,Shao An; Chan,Kwong Yu, Polymer composite membrane and method of making the same.
  40. Koestner, Roland J.; Mackinnon, Sean M; Fuller, Timothy J.; Owejan, Jeanette E., Polymer dispersant addition to fuel cell electrode inks for improved manufacturability.
  41. Nakamura, Masataka; Shimoyama, Naoki; Izuhara, Daisuke; Kono, Shunji; Kidai, Masayuki, Polymer electrolyte as well as polymer electrolyte membrane, membrane electrode assembly and polymer electrolyte fuel cell using the same.
  42. Cho, Myung-dong; Sun, Hee-young; Lee, Myung-jin, Polymer electrolyte membrane and fuel cell employing the same.
  43. Cho, Myung-dong; Sun, Hee-Young; Lee, Myung-jin, Polymer electrolyte membrane and fuel cell using the polymer electrolyte membrane.
  44. Adachi, Shinya; Izuhara, Daisuke; Nakamura, Masataka; Ito, Nobuaki, Polymer electrolytic material, polymer electrolytic part, membrane electrode assembly, and polymer electrolyte fuel cell.
  45. Wang, Chuanfu; Dong, Junqing, Polymers for proton exchange membranes, proton exchange membranes, and their fabrication methods.
  46. MacKinnon, Sean M; Fuller, Timothy J., Proton conductive polymer electrolytes and fuel cells.
  47. MacKinnon, Sean M; Fuller, Timothy J.; Coms, Frank; Schoeneweiss, Michael R., Proton exchange membranes for fuel cell applications.
  48. Kim, Yo Jin; Choi, Seung Don; Lee, Han Ho, Secondary battery with improved storage characteristics and method for manufacturing the same.
  49. Kim, Yo Jin; Choi, Seung Don; Lee, Han Ho, Secondary battery with improved storage characteristics and method for manufacturing the same.
  50. Fuller, Timothy J.; Schoeneweiss, Michael R.; Mackinnon, Sean M; Coms, Frank, Sodium stannate additive to improve the durability of PEMS for H2/air fuel cells.
  51. Chen, Jong Pyng; Chen, Jen Luan; Shih, Chih Jer; Chen, Chih Yuan, Structures of the proton exchange membranes with different molecular permeabilities.
  52. Mackinnon, Sean M; Fuller, Timothy J.; Coms, Frank, Sulfonated perfluorocyclobutane block copolymers and proton conductive polymer membranes.
  53. Fuller, Timothy J.; Mackinnon, Sean M; Schoeneweiss, Michael R., Sulfonated-polyperfluoro-cyclobutane-polyphenylene polymers for PEM fuel cell applications.
  54. Narayanan,Sekharipuram R.; Yen,Shiao Pin S., Water free proton conducting membranes based on poly-4-vinylpyridinebisulfate for fuel cells.
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